\(n_{Na}=\dfrac{m}{M}=\dfrac{3,45}{23}=0,15\left(mol\right)\\ n_{Na_2O}=\dfrac{m}{M}=\dfrac{6,2}{62}=0,1\left(mol\right)\\ PTHH:2Na+2H_2O->2NaOH+H_2\left(1\right)\)

tỉ lệ             2    :      2      :         2         ;   1

n(mol)       0,15---->0,15------->0,15----->0,075

\(m_{NaOH\left(1\right)}=n\cdot M=0,15\cdot40=6\left(g\right)\)

\(PTHH:Na_2O+H_2O->2NaOH\left(2\right)\)

tỉ lệ           1       ;       1      ;     2

n(mol)       0,1----->0,1------->0,2

\(m_{NaOH\left(2\right)}=n\cdot M=0,2\cdot40=8\left(g\right)\\ =>m_{NaOH}=m_{NaOH\left(1\right)}+m_{NaOH\left(2\right)}=6+8=14\left(g\right)\)

Ca+ 2H2O -> Ca(OH)2+ H2 

nH2= nCa= 0,14 mol 

=> mCa= 5,6g 

=> mFe= 6,2-5,6= 0,6g 

H2 + O -> H2O 

=> Y có 0,14 mol O 

nFe2O3= 0,02 mol 

=> 0,02 mol Fe2O3 có 0,04 mol Fe và 0,06 mol O 

Tổng mol Fe sau phản ứng là = 0,1 mol 

=> FexOy có 0,06 mol Fe và 0,08 mol O 

nFe : nO= 0,06 : 0,08= 3 : 4 

=> FexOy là Fe3O4 

a= 0,06.56+ 0,08.16= 4,64g

\(n_{H_2}=\dfrac{3,136}{22,4}=0,14mol\)

Gọi \(\left\{{}\begin{matrix}n_{Ca}=x\\n_{Na}=y\end{matrix}\right.\)

\(Ca+2H_2O\rightarrow Ca\left(OH\right)_2+H_2\)

 x                                            x     ( mol )

\(2Na+2H_2O\rightarrow2NaOH+H_2\)

 y                                        1/2 y       ( mol )

Ta có:

\(\left\{{}\begin{matrix}40x+23y=6,2\\x+\dfrac{1}{2}y=0,14\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,04\\y=0,2mol\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}m_{Ca}=0,04.40=1,6g\\m_{Na}=0,2.23=4,6g\end{matrix}\right.\)

\(n_{Fe_2O_3}=\dfrac{3,2}{160}=0,02mol\)

\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)

0,02      0,06               0,04       0,06               ( mol )

\(m_{Fe}=0,04.56=2,24g\)

\(\rightarrow m_{H_2\left(tdFe_xO_y\right)}=0,14-0,06=0,08mol\)

\(n_{Fe\left(tdFe_xO_y\right)}=\dfrac{5,6-0,04.56}{56}=0,06mol\)

\(Fe_xO_y+yH_2\rightarrow\left(t^o\right)xFe+yH_2O\)

                0,08            0,06              ( mol )

\(\Rightarrow x:y=0,06:0,08=3:4\)

\(\Rightarrow CTHH:Fe_3O_4\)

a, \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)

\(Na_2O+H_2O\rightarrow2NaOH\)

Theo PT: \(n_{Na}=2n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Na}=0,1.23=2,3\left(g\right)\)

\(\Rightarrow m_{Na_2O}=8,5-2,3=6,2\left(g\right)\)

b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)

Theo PT: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=0,3\left(mol\right)\Rightarrow m_{NaOH}=0,3.40=12\left(g\right)\)

PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)

           \(Na_2O+H_2O\rightarrow2NaOH\)

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)

\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)

Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)

Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\) 

Các bạn giúp mình với

2Na + 2H2O ---> 2NaOH + H2   (1)

Na2O + H2O ---> 2NaOH           (2)

 a) nH2 = 0,3 (mol)

Theo pthh (1) : nNa = 2nH2 = 0,6 (mol)

=> mNa = 0,6.23 = 13,8 (g)

=> mNa2O = 26,2 - 13,8 = 12,4 (g)

=> nNa2O = 0,2 (mol)

BTNa : nNaOH = nNa + 2nNa2O = 0,6 + 2.0,2 = 1 (mol)

=> mNaOH = 1.40 = 40(g)

b) %mNa = 13,8.100%/26,2 = 52,67%

%mNa2O = 100% - 52,67% = 47,33%

PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)

            \(Na_2O+H_2O\rightarrow2NaOH\)

Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=n_{Na}+2n_{Na_2O}=\dfrac{4,6}{23}+2\cdot\dfrac{6,2}{62}=0,3\left(mol\right)\\n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,3\cdot40=12\left(g\right)\\m_{H_2}=0,05\cdot2=0,1\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Na}+m_{Na_2O}+m_{H_2O}-m_{H_2}=110,7\left(g\right)\)

\(\Rightarrow C\%_{NaOH}=\dfrac{12}{110,7}\cdot100\%\approx10,84\%\)

Theo gt ta có: $n_{Na}=0,2(mol);n_{Na_2O}=0,1(mol)$

$2Na+2H_2O\rightarrow 2NaOH+H_2$

$Na_2O+H_2O\rightarrow 2NaOH$

Ta có: $n_{NaOH}=0,4(mol);n_{H_2}=0,1(mol)$

Bảo toàn khối lượng ta có: $m_{dd}=110,6(g)$

$\Rightarrow \%C_{NaOH}=14,46\%$

\(n_{Na}=\dfrac{m}{M}=0,2mol\)

\(n_{Na2O}=\dfrac{m}{M}=0,1\left(mol\right)\)

\(BTNT\left(Na\right):n_{NaOH}=0,2+2.0,1=0,4\left(mol\right)\)

\(\Rightarrow m_{NaOH}=n.M=16g\)

\(PTHH:Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)

...............0,2...................................0,1.

\(\Rightarrow m_{dd}=m_{KL}+m_{H2O}-m_{H2}=110,6g\)

\(\Rightarrow C\%_{NaOH}=\dfrac{m}{m_{dd}}.100\%=14,46\%\)

\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)

Anh có làm rồi nha!

Đáp án C

Ta có: n O = 0 , 14   m o l

Quy đổi hỗn hợp về Na x mol, Ba y mol và O 0,14 mol

Mặt khác cho CuSO₄ dư vào X kết tủa thu được gồm BaSO₄ y mol và Cu(OH)₂ 0,5x+y mol

Giải được: x=0,32; y=0,06