C

 B

\(m_{SO_2}=\dfrac{6,72}{22,4}.80=24\left(g\right)\)

AD ĐLBTKL ta có : 
\(m_{SO_2}+m_{NaOH}=m_{NaHSO_3}\\ \Leftrightarrow m_{NaOH}=45,8-24=21,8\left(g\right)\) 
\(\Rightarrow n_{NaOH}=21,8:40=0,07\left(mol\right)\) 
\(V_{NaOH}=0,07:2=0,035\left(l\right)\)

Bài 1: 

Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\n_{NaOH}=\dfrac{164\cdot1,22\cdot20\%}{40}=1,0004\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo muối trung hòa

PTHH: \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)

Vì NaOH dư nên tính theo CO₂ \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2CO_3}=0,25\left(mol\right)\\n_{NaOH\left(dư\right)}=0,5004\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Na_2CO_3\left(rắn\right)}=0,25\cdot106=26,5\left(g\right)\\m_{NaOH\left(rắn\right)}=0,5004\cdot40=20,016\left(g\right)\end{matrix}\right.\)

*Các bài còn lại bạn làm theo gợi ý bên dưới 
PTHH: \(CO_2+NaOH\rightarrow NaHCO_3\)  (1)

            \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)  (2)

\(n_{KOH}=0,75.0,1=0,075\left(mol\right)\\ n_{NaOH}=1.0,1=0,1\left(mol\right)\\ n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo LT thì CO₂ sẽ phản ứng với dd KOH trước, sau đó mới phản ứng với dd NaOH

\(2KOH+CO_2\rightarrow K_2CO_3+H_2O\left(1\right)\\ Ta.có:n_{K_2CO_3}=n_{CO_2\left(1\right)}=\dfrac{n_{KOH}}{2}=\dfrac{0,075}{2}=0,0375\left(mol\right)\)

\(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\left(2\right)\\ n_{CO_2\left(còn.sau.1\right)}=0,1-0,0375=0,0625\left(mol\right)\\ Vì:\dfrac{0,1}{2}< \dfrac{0,0625}{1}\\ \Rightarrow CO_2dư\)

\(n_{CO_2\left(dư\right)}=0,0625-\dfrac{0,1}{2}=0,0125\left(mol\right)\\ CO_2+K_2CO_3+H_2O\rightarrow2KHCO_3\left(3\right)\\ Vì:\dfrac{0,0125}{1}< \dfrac{0,0375}{1}\\ \Rightarrow Rắn.X:\left\{{}\begin{matrix}n_{Na_2CO_3}=\dfrac{n_{NaOH}}{2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\n_{KHCO_3}=2.n_{CO_2\left(3\right)}=0,0125.2=0,025\left(mol\right)\\n_{K_2CO_3}=0,0375-n_{K_2CO_3\left(3\right)}=0,0375-0,0125=0,025\left(mol\right)\end{matrix}\right.\\ \Rightarrow m_X=m_{Na_2CO_3}+m_{KHCO_3}+m_{K_2CO_3}=106.0,05+100.0,025+138.0,025=11,25\left(g\right)\)

2M+2nH2SO4-->M2(SO4)n+nSO2+2nH2O 
0.6/n
Xét TH NaOH dư 
SO2+2NaOH-->Na2SO3+H2O 
a----->2a--------->a 
TA có: 126a+40(0.7-2a)=41.8 
< = > a=0.3 
M=19.2n/0.6=32n 
n=2, => M=64 : Cu

còn 2 TH nữa thì sao

Đáp án C

Þ m = 0,02.23 + 0,02.39 + 0,015.60 + 0,01.17 = 2,31 gam