a. PTHH: 3NaOH + AlCl₃ ---> Al(OH)₃↓ + 3NaCl (1)

Ta có: \(C_{\%_{NaOH}}=\dfrac{m_{NaOH}}{100}.100\%=12\%\)

=> m_NaOH = 12(g)

=> \(n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\)

Ta lại có: \(C_{\%_{AlCl_3}}=\dfrac{m_{AlCl_3}}{200}.100\%=13,35\%\)

=> \(m_{AlCl_3}=26,7\left(g\right)\)

=> \(n_{AlCl_3}=\dfrac{26,7}{133,5}=0,2\left(mol\right)\)

Ta thấy: \(\dfrac{0,3}{3}< \dfrac{0,2}{1}\)

Vậy AlCl₃ dư

Theo PT₍₁₎: \(n_{Al\left(OH\right)_3}=\dfrac{1}{3}.n_{NaOH}=\dfrac{1}{3}.0,3=0,1\left(mol\right)\)

=> \(m_{Al\left(OH\right)_3}=0,1.78=7,8\left(g\right)\)

b. Ta có: \(m_{dd_{NaCl}}=12+200-7,8=204,2\left(g\right)\)

Theo PT₍₁₎: \(n_{NaCl}=n_{NaOH}=0,3\left(mol\right)\)

=> \(m_{NaCl}=0,3.58,5=17,55\left(g\right)\)

=> \(C_{\%_{NaCl}}=\dfrac{17,55}{204,2}.100\%=8,59\%\)

c. PTHH: 2Al(OH)₃ ---t^o---> Al₂O₃ + 3H₂O (2)

Theo PT₍₂₎: \(n_{Al_2O_3}=\dfrac{1}{2}.n_{Al\left(OH\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)

=> \(m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)

Bài 10:

PTHH: \(Na_2CO_3+BaCl_2\rightarrow2NaCl+BaCO_3\downarrow\)

a) Ta có: \(n_{Na_2CO_3}=\dfrac{200\cdot10,6\%}{106}=0,2\left(mol\right)=n_{BaCO_3}\)

\(\Rightarrow m_{BaCO_3}=0,2\cdot197=39,4\left(g\right)\)

b) Theo PTHH: \(n_{BaCl_2}=n_{BaCO_3}=0,2mol\)

\(\Rightarrow C\%_{BaCl_2}=\dfrac{0,2\cdot208}{120}\cdot100\%\approx34,67\%\)

c) Theo PTHH: \(n_{NaCl}=2n_{BaCl_2}=0,4mol\) \(\Rightarrow m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)

Mặt khác: \(m_{dd}=m_{ddNa_2CO_3}+m_{ddBaCl_2}-m_{BaCO_3}=280,6\left(g\right)\)

\(\Rightarrow C\%_{NaCl}=\dfrac{23,4}{280,6}\cdot100\%\approx8,34\%\)

Bài 11 và bài 12 tương tự bài 10

\(a)n_{BaCl_2}=\dfrac{240}{1,12}:1000\cdot1=\dfrac{3}{14}mol\\ n_{H_2SO_4}=\dfrac{122.20}{100}:98=\dfrac{61}{245}mol\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\\ \Rightarrow\dfrac{3:14}{1}< \dfrac{61:245}{1}\Rightarrow H_2SO_4.dư\\ n_{BaSO_4}=n_{BaCl_2}=n_{H_2SO_4}=\dfrac{3}{14}mol\\ m_{kt}=m_{BaSO_4}=\dfrac{3}{14}\cdot233=50g\\ c)C_{\%H_2SO_4\left(dư\right)}=\dfrac{\left(61:245-3:14\right)98}{240+122-50}\cdot100=1,2\%\)

a)H2SO4+BaCl2--->BaSO4+2HCl

m dd H2SO4=38,168.1,31=50(g)

m H2SO4=50.19,6/100=15,68(g)

n H2SO4=15,68/98=0,16(mol)

m baCl2=208.10/100=20,8(g)

n BaCl2=20,8/108=0,1(mol)

-->H2SO4 dư.

n BaSO4=n BaCl2=0,1(mol)

m baSO4=0,1.233=23,3(g)

Muối sau pư là baSO4 luôn rồi nha

b) m dd sau pư=50+208-23,3=234,7(g)

n H2SO4=n BaCl2=0,1(mol)

n H2SO4 dư=0,16-0,1=0,06(mol)

m H2SO4 dư=0,06.98=5,88(g)

C% H2SO4=5,88/234,7.100%=2,5%

n HCl=2n BaCl2=0,2(mol)

m HCl=0,2.36,5=73(g)

C% HCl=73/234,7.100%=31,1%

PTHH 3ZnCl₂+2H₃PO₄----->Zn₃(PO₄)₂+6HCl

\(n_{ZnCl_2}\)=0,3.2=0,6(mol)

Theo phương trình =>\(\dfrac{1}{3}n_{ZnCl_2}=n_{Zn_3\left(PO_4\right)_2}=0,2\left(mol\right)\)

=>\(m_{Zn_3\left(PO_4\right)_2}\)=0,2.385=77(g)

Theo phương trình =>\(2n_{ZnCl_2}=n_{HCl}=1,2\left(mol\right)\)

=>\(C_{M_{HCl}}\)=\(\dfrac{1,2}{0,2+0,3}=2,4M\)

a/

\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

0,15 0,3 (mol)

\(m_{NaOH}=0,3.40=12\left(g\right)\)

\(m_A=90,7+9,3=100\left(g\right)\)

\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)

b/

m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)

\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)

\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)

pư: 0,3 0,15 0,15 0,15 (mol)

dư: 0 \(\dfrac{23}{380}\) (mol)

\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)

\(m_C=100+200-13,5=286,5\left(g\right)\)

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)

\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)

\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)