\(a,\) Đặt \(\begin{cases} n_{Fe}=x(mol)\\ n_{Al}=y(mol) \end{cases}\Rightarrow 56x+27y=22(1)\)

\(n_{H_2}=\dfrac{17,92}{22,4}=0,8(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow x+1,5y=0,8(2)\\ (1)(2)\Rightarrow \begin{cases} x=0,2(mol)\\ y=0,4(mol) \end{cases} \Rightarrow \begin{cases} \%_{Fe}=\dfrac{0,2.56}{22}.100\%=50,91\%\\ \%_{Al}=100\%-50,91\%=49,09\% \end{cases} \)

\(b,\Sigma n_{HCl}=2n_{Fe}+3n_{Al}=0,4+1,2=1,6(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{1,6.36,5}{3,7\%}=1578,38\%\)

Đáp án B.

Định hướng tư duy giải

Đáp án B

Bài 1:

\(n_{HCl}=2.0,16=0,32\left(mol\right);n_{H_2}=\dfrac{3,584}{22,4}=0,16\left(mol\right)\)

PTHH: Mg + 2HCl → MgCl₂ + H₂

PTHH: Fe + 2HCl → FeCl₂ + H₂

\(m_{H_2}=0,16.2=0,32\left(g\right)\)

\(m_{HCl}=0,32.36,5=11,68\left(g\right)\)

Theo ĐLBTKL ta có: \(m_{MgCl_2+FeCl_2}=1,4+11,68-0,32=12,76\left(g\right)\)

Bài 12:

Theo ĐLBTKL, ta có:

\(m_{hhkl}+m_{O_2}=m_{hh.oxit}\\ \Leftrightarrow11,9+m_{O_2}=18,3\\ \Leftrightarrow m_{O_2}=18,3-11,9=6,4\left(g\right)\\ n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

a) Theo Pt : \(n_{H2}=n_{Fe}=n_{FeCl2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\)

\(\%m_{Cu}=100\%-56\%=44\%\)

b) Theo Pt : \(n_{H2}=2n_{HCl}=2.0,1=0,2\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}.100\%=100\left(g\right)\)

c) \(m_{ddspu}=10+100-0,1.2=109,8\left(g\right)\)

\(C\%_{FeCl2}=\dfrac{0,1.127}{109,8}.100\%=11,57\%\)

Đặt nAl=a(mol); nFe=b(mol) (a,b>0)

Ta có: nH2=8,96/22,4=0,4(mol)

PTHH: 2 Al + 6 HCl -> 2 AlCl3 + 3 H2

a_________3a____a____1,5a(mol)

Fe +2 HCl -> FeCl2 + H2

b__2b____b____b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}27a+56b=16,7\\1,5a+b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,25\end{matrix}\right.\)

=> mAl= 0,1.27=2,7(g) =>%mAl= (2,7/16,7).100=16,17%

=> CHỌN B

a)

$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$

b)

Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$

$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$

$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$

c) $Fe + CuSO_4 \to FeSO_4 + Cu$

$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$

$= 3,6 + 0,15.64 = 13,2(gam)$

\(n_{Cu} = a ; n_{Al} = b ; n_{Fe} = c(mol)\\ \Rightarrow 64a + 27b + 56c = 28,6(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5b + c = \dfrac{13,44}{22,4} = 0,6(2)\\ \text{Mặt khác} : n_{O_2} = \dfrac{8,96}{22,4} = 0,4(mol)\\ 2Cu + O_2 \xrightarrow{t^o} 2CuO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 4Fe + 3O_2 \xrightarrow{t^o} 2Fe_2O_3\\ \)

Ta có :

\(\dfrac{n_X}{n_{O_2}}=\dfrac{a+b+c}{0,5a +0,75b + 0,75c} = \dfrac{0,6}{0,4}(3)\\ (1)(2)(3)\Rightarrow a = \dfrac{317}{1460} ; b = \dfrac{121}{365}; c = \dfrac{15}{146}\\ \%m_{Cu} = \dfrac{\dfrac{317}{1460}.64}{28,6}.100\% = 48,59\%\\ \%m_{Al} = \dfrac{\dfrac{121}{365}.27}{28,6}.100\% = 31,3\%\\ \%m_{Fe} = 100\% - 41,59\% - 31,3\% = 27,11\%\)