Đáp án : A

MnO₂ + 4HCl -> MnCl₂ + Cl₂ + 2H₂O

=> n_Cl2 = n_MnO2 = 0,15 mol

=> V_Cl2 = 3,36 lit

\(n_{H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(n_{Cl_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)

\(H_2+Cl_2\underrightarrow{^{^{as}}}2HCl\)

\(n_{H_2}>n_{Cl_2}\Rightarrow H_2dư\)

\(m_{HCl}=0.05\cdot2\cdot36.5=3.65\left(g\right)\)

$n_{H_2} = 0,3(mol) ; n_{Cl_2} = 0,05(mol)$
$H_2 + Cl_2 \xrightarrow{ánh\ sáng} 2HCl$

Ta thấy : $n_{H_2} > n_{Cl_2}$ nên Hidro dư

$n_{HCl} = 2n_{Cl_2} = 0,1(mol)$
$m_{HCl} = 0,1.36,5 = 3,65(gam)$

nCl2=1.1222.4=0.05(mol)nCl2=1.1222.4=0.05(mol)

H2+Cl2as→2HClH2+Cl2as→2HCl

nH2>nCl2⇒H2dưnH2>nCl2⇒H2dư

mHCl=0.05⋅2⋅36.5=3.65(g)

#HT#

\(n_{Zn}=\dfrac{m}{M}=\dfrac{32,5}{65}=0,5\left(mol\right)\\ PTHH:Zn+2HCl->ZnCl_2+H_2\)

tỉ lệ            1    :       2      :          1    :   1

n(mol)       0,5------------------------------->0,5

\(V_{H_2\left(dktc\right)}=n\cdot22,4=0,5\cdot22,4=11,2\left(l\right)\)

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=\dfrac{18,25}{35}=0,5\left(mol\right)\\ a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,5}{2}>\dfrac{0,2}{1}\Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\\ m_{HCl}=0,1.36,5=3,65\left(g\right)\\ c.n_{ZnCl_2}=n_{Zn}=n_{H_2}=0,2\left(mol\right)\\ m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\)

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)

            1          2            1            1

           0,2       0,5         0,2         0,2

b) Lập tỉ số so sánh : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)

                 ⇒ Zn phản ứng hết , HCl dư

                 ⇒ Tính toán dựa vào số mol của Zn

\(n_{HCl\left(dư\right)}=0,5-\left(0,2.2\right)=0,1\left(mol\right)\)

⇒ \(m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)

c) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)

\(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)

 Chúc bạn học tốt

`Fe + 2HCl -> FeCl_2 + H_2 \uparrow`

 `0,1`      `0,2`          `0,1`       `0,1`         `(mol)`

`n_[Fe]=[5,6]/56=0,1(mol)`

`a)V_[H_2]=0,1.22,4=2,24(l)`

`b)C_[M_[HCl]]=[0,2]/[0,1]=2(M)`

a) nAl=2,7/27=0,1(mol)

PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3H2

0,1_________0,3___0,1_____0,15(mol)

b) mHCl=0,3.36,5=10,95(g)

c) mAlCl3=0,1.133,5=13,35(g)

d) V(H2,đktc)=0,15.22,4=3,36(l)

a. PTHH: 2Al + 6HCl \(\rightarrow\) 2AlCl\(_3\) + 3H\(_2\)

b. \(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{2,7}{27}=0,1\) (mol)

\(n_{HCl}=\dfrac{0,1.6}{2}=0,3\) (mol)

\(m_{HCl}=n_{HCl}.M_{HCl}=0,3.36,5=10,95\) (g)

c. \(n_{AlCl_3}=\dfrac{0,1.2}{2}=0,1\) (mol)

\(m_{AlCl_3}=n_{AlCl_3}.M_{AlCl_3}=0,1.133,5=13,35\) (g)

d. \(n_{H_2}=\dfrac{0,1.2}{3}=0,15\) (mol)

\(V_{H_2}=n_{H_2}.22,4=0,15.22,4=3,36\) (l)

$n_{Mg} = \dfrac{4,8}{24} = 0,2(mol) ; n_{HCl} = 0,5(mol)$
$Mg + 2HCl \to MgCl_2 + H_2$
Ta thấy : 

$n_{Mg} : 1 < n_{HCl} : 2$ nên HCl dư

$n_{H_2} = n_{Mg} = 0,2(mol) \Rightarrow V_{H_2} = 0,2.22,4 = 4,48(lít)$