a.

\(V_{H_2S}=0.75\cdot22.4=16.8\left(l\right)\)

\(V_{SO_2}=\dfrac{12.8}{64}\cdot22.4=4.48\left(l\right)\)

\(V_{O_2}=\dfrac{3.2}{32}\cdot22.4=2.24\left(l\right)\)

b.

\(n_{hh}=\dfrac{22}{44}+\dfrac{3.55}{71}+\dfrac{0.14}{28}=0.555\left(mol\right)\)

\(V_{hh}=0.555\cdot22.4=12.432\left(l\right)\)

$n_{CO_2} = 0,5(mol) ; n_{H_2O} = 0,5625(mol)$
$\Rightarrow n_A = 0,5625 - 0,5 = 0,0625(mol)$

$\Rightarrow n_B = 0,3 - 0,0625 = 0,2375(mol)$

Bảo toàn C : 

$0,0625.C_A + 0,2375.C_B = 0,5$

Không có số nguyên $C_A,C_B$ nào thỏa mãn

\(n_{CO_2}=\dfrac{22}{44}=0,5\left(mol\right)\\ n_{O_2}=\dfrac{16}{32}=0,5\left(mol\right)\\ V_{hh.khí}=V_{CO_2}+V_{O_2}=\left(0,5+0,5\right).24,79=24,79\left(l\right)\)

\(n_{CO_2}=\dfrac{22}{44}=0,5\left(mol\right)\)

\(n_{H_2O}=\dfrac{10,8}{18}=0,6\left(mol\right)\)

Do \(n_{H_2O}>n_{CO_2}\Rightarrow n_{ankan}=0,6-0,5=0,1\left(mol\right)\)

Đặt CT của ankan :\(C_nH_{2n+2}\) 0,1 mol  , anken : \(C_mH_{2m}\)0,1 mol 

BT C : 0,1n+ 0,1 m=0,5 (1)

Lại có : \(\dfrac{14n+2}{14m}=\dfrac{11}{7}\Leftrightarrow98n-154m=0\left(2\right)\)

(1) , (2) : \(\Rightarrow\left\{{}\begin{matrix}m=3\\n=2\end{matrix}\right.\Rightarrow}\left\{{}\begin{matrix}C_3H_8\\C_2H_4\end{matrix}\right.\)

Câu 19

\(n_{CO_2}=\dfrac{22}{44}=0,5\left(mol\right)\)

=> V_CO2 = 0,5.22,4 = 11,2 (l)

\(n_{O_2}=\dfrac{8}{32}=0,25\left(mol\right)\)

=> V_O2 = 0,25.22,4 = 5,6 (l)

\(n_{N_2}=\dfrac{2,8}{28}=0,1\left(mol\right)\)

=> V_N2 = 0,1.22,4 = 2,24 (l)

Câu 20

a) 2Mg + O₂ --t^o--> 2MgO

b) \(n_{Mg}=\dfrac{24}{24}=1\left(mol\right)\)

2Mg + O₂ --t^o--> 2MgO

_1--->0,5-------->1

=> m_MgO = 1.40 = 40(g)

=> V_O2 = 0,5.22,4 = 11,2 (l)

Trong A : 

\(n_{CO_2}=n_X=a\left(mol\right)\)

Trong B: 

\(n_{N_2}=2b\left(mol\right),n_{CO_2}=3b\left(mol\right)\)

\(n_A=2a=0.1\left(mol\right)\Rightarrow a=0.05\)

\(n_B=5b=0.05\left(mol\right)\Rightarrow b=0.01\)

\(m=0.05\cdot44+0.05\cdot X+0.02\cdot28+0.03\cdot44=4.18\left(g\right)\)

\(\Rightarrow X=2\)

\(X:H_2\)

\(n_{Cu}=a\left(mol\right),n_{Fe}=b\left(mol\right)\)

\(m_X=64a+56b=16.2\left(g\right)\left(1\right)\)

\(n_{SO_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)

Bảo toàn e : 

\(2a+3b=0.4\cdot2=0.8\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.0475,b=0.235\)

\(\%Cu=\dfrac{0.0475\cdot64}{16.2}\cdot100\%=18.76\%\)

\(\%Fe=81.24\%\)

\(b.\)

\(\dfrac{a}{b}=\dfrac{0.0475}{0.235}=\dfrac{19}{94}\)

\(\Rightarrow n_{Cu}=19x\left(mol\right),n_{Fe}=94x\left(mol\right)\)

\(m_X=19x\cdot64+94x\cdot56=22\left(g\right)\)

\(\Rightarrow x=\dfrac{11}{3240}\)

\(n_{H_2}=n_{Fe}=\dfrac{11}{3240}\cdot94=\dfrac{517}{1620}\left(mol\right)\)

\(V_{H_2}=7.15\left(l\right)\)

\(n_C = n_S = x\ mol\\ \Rightarrow 12x + 32x = 22 \Rightarrow x = 0,5\\ C + O_2 \xrightarrow{t^o} CO_2\\ S + O_2 \xrightarrow{t^o} SO_2\)

Theo PTHH : 

\(n_{O_2} = n_C + n_S = 0,5 + 0,5 = 1\ mol\\ \Rightarrow V_{O_2} = 1.22,4 = 22,4(lít)\)

nC = nS = a (mol) 

mhh = 44a + 32a = 22 (g) 

=> a = 11/38 

C + O2 -to-> CO2 

S + O2 -to-> SO2 

VO2 = 11/38*2*22.4=13(l)