2Al+6HCl->2AlCL3+3H2(1)

Mg+2HCL->MgCL2+H2(2)

Cu+2H2SO4(đặc)->CuSO4+SO2+2H2O(3)

(3)=>nCu=nSO2=2,24/22,4=0,1mol

=>mCu=0,1.64=6,4g ???? lớn hơn m hỗn hợp đề chắc sai

\(n_{SO_2}=\dfrac{V_{SO_2}}{22,4}=\dfrac{2,24}{22,4}=0,1mol\)

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Cu}=y\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=24x\\m_{Cu}=64y\end{matrix}\right.\)

\(Mg+2H_2SO_4\rightarrow MgSO_4+SO_2+2H_2O\) 

 x           2x                               x                  ( mol )

\(Cu+2H_2SO_4\rightarrow CuSO_4+SO_2+2H_2O\)

 y            2x                              y                   ( mol )

Ta có:

\(\left\{{}\begin{matrix}24x+64y=4,4\\x+y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,05\end{matrix}\right.\)

\(\Rightarrow m_{Mg}=0,05.24=1,2g\)

\(\Rightarrow m_{Cu}=0,05.64=3,2\)

\(m_{H_2SO_4}=n_{H_2SO_4}.M_{H_2SO_4}=\left(2.0,05+2.0,05\right).98=0,2.98=19,6g\)

\(n_{SO_2}=\dfrac{2,24}{22,4}=0,1mol\)

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Cu}=y\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}24x+64y=4,4\\BTe:2x+2y=2n_{SO_2}=2\cdot0,1=0,2\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,05\\y=0,05\end{matrix}\right.\)

\(m_{Mg}=0,05\cdot24=1,2g\)

\(m_{Cu}=0,05\cdot64=3,2g\)

\(n_{H_2SO_4}=2n_{Mg}+2n_{Cu}=2\cdot0,05+2\cdot0,05=0,2mol\)

\(m_{H_2SO_4}=0,2\cdot98=19,6g\)

Đặt nMg=x(mol),nCu=y(mol)

Bảo toàn e : 2nMg+2nCu=2nSO2=0,2(mol)

Từ  giải được:

mMg=0,05.24=1,2(g)

mCu=0,05.64=3,2(g)

nH2SO4=2nSO2=0,2(mol)

mH2SO4=0,2.98=19,6(g)

Đặt nMg=x(mol);nCu=y(mol)

→24x+64y=4,4(1)

nSO2=\(\dfrac{2,24}{22,4}\)=0,1(mol)

Bảo toàn e: x+y=nSO2=0,1(2)

Từ (1)(2)→x=y=0,05(mol)

=>mMg=0,05.24=1,2(g)

mCu=0,05.64=3,2(g)

b)

Mg+2H2SO4→MgSO4+SO2+3H2O

Cu+2H2SO4→CuSO4+SO2+2H2O

Tho PT: ∑nH2SO4=2∑nSO2=0,2(mol)

→m_axit=0,2.98=19,6(g)

- Kim loại Cu sẽ không tan trong dung dịch HCl ở đk thường. Nên nó sẽ là kim loại duy nhất trong hỗn hợp này tác dụng với dd H₂SO_{4 đặc,nóng} .

\(Cu+2H_2SO_{4\left(đặc,nóng\right)}\rightarrow CuSO_4+SO_2+H_2O\)

Ta có: \(n_{Cu}=n_{SO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

=> m_Cu= 0,1.64=6,4(g)

\(\rightarrow m_{hh\left(Mg,Al\right)}=11,5-6,4=5,1\left(g\right)\\ Đặt\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \rightarrow\left\{{}\begin{matrix}24a+27b=5,1\\a+1,5b=\dfrac{5,6}{22,4}=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \left\{{}\begin{matrix}\%m_{Cu}=\dfrac{6,4}{11,5}.100\approx55,652\%\\\%m_{Mg}=\dfrac{24.0,1}{11,5}.100\approx20,87\%\\\%m_{Al}=\dfrac{27.0,1}{11,5}.100\approx23,478\%\end{matrix}\right.\)

1)

Fe + 2HCl --> FeCl₂ + H₂

Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

2)

- Xét TN1:

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

         0,15<------------------0,15

=> m_Fe = 0,15.56 = 8,4 (g)

\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{8,4}{14,8}.100\%=56,757\%\\\%m_{Cu}=100\%-56,757\%=43,243\%\end{matrix}\right.\)

3) 

- Xét TN2:

\(n_{Cu}=\dfrac{29,6.43,243\%}{64}=0,2\left(mol\right)\)

PTHH: Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

            0,2-------------------------->0,2

=> V = 0,2.22,4 = 4,48 (l)

a)

Gọi $n_{Mg} = a(mol) ; n_{Zn} = b(mol)$

Suy ra: $24a + 65b = 24,3(1)$
$n_{SO_2} = 0,5(mol)$

Bảo toàn electron : $2n_{Mg} + 2n_{Zn} = 2n_{SO_2}$
$\Rightarrow a + b = 0,5(2)$

Từ (1)(2) suy ra a = 0,2 ; b = 0,3

$m_{Mg} = 0,2.24 = 4,8(gam)$
$m_{Zn} = 0,3.65 = 19,5(gam)$
b)

Ta có :

$n_{H_2SO_4} = 2n_{SO_2} = 1(mol)$
$m_{H_2SO_4\ pư} = 1.98 = 98(gam)$

a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

b, Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{10,5}.100\%\approx61,9\%\\\%m_{Cu}\approx38,1\%\end{matrix}\right.\)

c, \(n_{H_2SO_4}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ b.n_{Zn}=n_{H_2SO_4}=n_{H_2}=0,1mol\\ m_{Zn}=0,1.65=6,5g\\ \%m_{Zn}=\dfrac{6,5}{10,5}\cdot100\%=61,9\%\\ \%m_{Cu}=100\%-61,9=38,1\%\\ c.C_{M_{H_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)

Bạn sửa đề thành 7.84 (l) nha

nH2 = 7.84/22.4 = 0.35 (mol) 

Đặt : 

nFe = x mol 

nMg = y mol 

mhh = 56x + 24y = 14.8 g (1) 

Fe + H2SO4 => FeSO4 + H2 

Mg + H2SO4 => MgSO4 + H2 

nH2 = x + y = 0.35 (2) 

(1) , (2) : 

x = 0.2 => mFe = 0.2*56 = 11.2 g 

y = 0.15 => mMg = 0.15*24=3.6 g 

%Fe = 75.67%

%Mg = 24.33%

Gọi n_Fe = a (mol); n_Mg = b (mol)

=> 56a + 24b = 14,8

\(n_{H_2}=\dfrac{7,89}{22,4}=\dfrac{789}{2240}\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

______a-------------------------->a _________(Mol)

Mg + 2HCl --> MgCl₂ + H₂

_b--------------------------->b_______(mol)

=> \(\left\{{}\begin{matrix}56a+24b=14,8\\a+b=\dfrac{789}{2240}\end{matrix}\right.\) => \(\left\{{}\begin{matrix}a=\dfrac{1777}{8960}\left(mol\right)\\b=\dfrac{197}{1280}\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{\dfrac{1777}{8960}.56}{14,8}.100\%=75\%\\\%m_{Mg}=\dfrac{\dfrac{197}{1280}.24}{14,8}.100\%=25\%\end{matrix}\right.\)

a, Mg + 2HCl \(\rightarrow\) MgCl₂ + H₂             Cu + 2HCl \(\rightarrow\) CuCl₂ + H₂

b, \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Cu}=y\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}24x+64y=16\\x+y=\dfrac{2,24}{22,4}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=-0,24\\y=0,34\end{matrix}\right.\)

Xem lại đầu bài nha

a) PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)  (1)

                \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)  (2) 

b) Vì H₂SO₄ chắc chắn còn dư nên tính theo mol của H₂

Ta có: \(n_{H_2}=\dfrac{0,224}{22,4}=0,01\left(mol\right)\)

Gọi số mol của Zn là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=a\left(mol\right)\)

Gọi số mol của Mg là \(b\) \(\Rightarrow n_{H_2\left(2\right)}=b\left(mol\right)\)

Ta lập được hệ phương trình:

\(\left\{{}\begin{matrix}a+b=0,01\\65a+24b=0,445\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,005\\b=0,005\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,005\cdot65=0,325\left(g\right)\\m_{Mg}=0,005\cdot24=0,12\left(g\right)\end{matrix}\right.\)

PTHH Zn+ H₂SO₄--->ZnSO₄ +H₂

Mg+H₂SO₄----->MgSO₄+H₂

Đặt n_Zn=a,n_Mg=b

=>m_hh=65a+24b=0,445(I)

Theo các phương trình phản ứng

=>\(n_{H_2}\)=a+b=\(\dfrac{0,224}{22,4}=0,01\)(II)

Từ(I),(II)=>a=b=0.005(mol)

=>m_Zn=0,005.65=0,325(g)

m_Mg=0,005.24=0.12(g)