\(2NaOH\left(0,02006\right)+H_2SO_4\left(0,01003\right)\rightarrow Na_2SO_4\left(0,01003\right)+2H_2O\)

\(m_{NaOH}=25.0,04=1\left(g\right)\)

\(\Rightarrow n_{NaOH}=\dfrac{1}{40}=0,025\left(mol\right)\)

\(V_{H_2SO_4}=\dfrac{51}{1,02}=50\left(ml\right)=0,05\left(l\right)\)

\(\Rightarrow n_{H_2SO_4}=0,05.0,2=0,01\left(mol\right)\)

Theo đề bài thì NaOH dư 0,26%

\(\Rightarrow m_{NaOH\left(d\text{ư}\right)}=0,26\%.\left(25+51\right)=0,1976\left(g\right)\)

\(\Rightarrow n_{NaOH\left(d\text{ư}\right)}=\dfrac{0,1976}{40}=0,00494\left(mol\right)\)

\(\Rightarrow n_{NaOH\left(p\text{ứ}\right)}=0,025-0,00494=0,02006\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4\left(d\text{ư}\right)}=0,05-0,01003=0,03997\left(mol\right)\\n_{Na_2SO_4}=0,01003\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{H_2SO_4\left(d\text{ư}\right)}=0,03997.98=3,91706\left(g\right)\\m_{Na_2SO_4}=0,01003.142=1,42426\left(g\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C\%\left(NaOH\right)=0,26\%\\C\%\left(H_2SO_4\right)=\dfrac{3,91706}{25+51}.100\%=5,15\%\\C\%\left(Na_2SO_4\right)=\dfrac{1,42426}{25+51}.100\%=1,87\%\end{matrix}\right.\)

PTHH: \(CuSO_4+2NaOH\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

Ta có: \(\left\{{}\begin{matrix}n_{CuSO_4}=0,08\cdot3,5=0,28\left(mol\right)\\n_{NaOH}=0,12\cdot1,5=0,18\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,28}{1}>\dfrac{0,18}{2}\) \(\Rightarrow\) CuSO₄ còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_4}=0,09\left(mol\right)=n_{Cu\left(OH\right)_2}\\n_{CuSO_4\left(dư\right)}=0,19\left(mol\right)\\\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Na_2SO_4}=0,09\cdot142=12,78\left(g\right)\\m_{Cu\left(OH\right)_2}=0,09\cdot98=8,82\left(g\right)\\m_{CuSO_4\left(dư\right)}=0,19\cdot160=30,4\left(g\right)\end{matrix}\right.\)

Mặt khác: \(\left\{{}\begin{matrix}C_{M_{Na_2SO_4}}=\dfrac{0,09}{0,08+0,12}=0,45\left(M\right)\\C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0,19}{0,08+0,12}=0,95\left(M\right)\end{matrix}\right.\)

\(a,n_{H_2SO_4}=0,3.0,75+0,3.0,25=0,3\left(mol\right)\\ V_{ddH_2SO_4}=300+300=600\left(ml\right)=0,6\left(l\right)\\ \rightarrow C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,6}=0,5M\\ m_{H_2SO_4}=0,3.98=29,4\left(g\right)\\ m_{ddH_2SO_4}=600.1,02=612\left(g\right)\\ \rightarrow C\%_{H_2SO_4}=\dfrac{29,4}{612}.100\%=4,8\%\)

\(b,\) Đặt kim loại M có hoá trị n (n ∈ N*)

PTHH: \(2M+nH_2SO_4\rightarrow M_2\left(SO_4\right)_n+nH_2\uparrow\)

           \(\dfrac{0,6}{n}\)<---0,3--------------------------->0,3

\(\rightarrow M_M=\dfrac{5,4}{\dfrac{0,6}{n}}=9n\left(g\text{/}mol\right)\)

Vì n là hoá trị của M nên ta xét bảng

Vậy M là Al

\(c,n_{KClO_3}=\dfrac{15,3125}{122,5}=0,125\left(mol\right)\)

PTHH:

\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)

0,3-->0,15

\(2KClO_3\xrightarrow[]{t^o}2KCl+3O_2\uparrow\)

0,1<---------------------0,15

\(\rightarrow H=\dfrac{0,1}{0,125}.100\%=80\%\)

\(n_{NaOH}=\dfrac{25.4\%}{40}=0,025\left(mol\right)\)

\(n_{H_2SO_4}=0,052.0,2=0,0104\left(mol\right)\)

PTHH : \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

Theo đề: 0,025..........0,0104

Lập tỉ lệ: \(\dfrac{0,025}{2}>\dfrac{0,0104}{1}\) => Sau phản ứng NaOH dư, H2SO4 hết

\(m_{ddsaupu}=25+51=76\left(g\right)\)

\(C\%_{NaOH\left(dư\right)}=\dfrac{(0,025-0,0104\cdot2).40}{76}.100=0,22\%\)

\(C\%_{Na_2SO_4}=\dfrac{0,0104.142}{76}.100=1,94\%\)

\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,095          0,19              0,095            0,095

\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)

0,095                 0,095

\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)

a, \(Na_2O+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

b, Số mol \(H_2SO_4\) là: \(n_1=V.C_M=0,5.0,5=0,25\) (mol)

Số mol \(Na_2SO_4\) là \(n_2=\dfrac{28,4}{142}=0,2\) (mol)

Do \(n_2< n_1\) nên \(H_2SO_4\) còn dư

Suy ra số mol \(Na_2O\) tham gia phản ứng là: \(n=n_2=0,2\) (mol)

Khối lượng là: \(m_{Na_2O}=0,2.62=12,4g\)

n_Fe = 11.2/56 = 0.2 (mol) 

Fe + H2SO4 => FeSO4 + H2 

0.2____0.2_______0.2___0.2 

mH2SO4 = 0.2*98 = 19.6 (g) 

mdd H2SO4 = 19.6*100/10 = 196 (g) 

m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g) 

mFeSO4 = 0.2*152 = 30.4 (g) 

C% FeSO4 = 30.4/206.8 * 100% = 14.7% 

Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml) 

CM FeSO4 = 0.2 / 0.1719 = 1.16 M 

n_Fe = 11.2/56 = 0.2 (mol) 

Fe + H2SO4 => FeSO4 + H2 

0.2____0.2_______0.2___0.2 

mH2SO4 = 0.2*98 = 19.6 (g) 

mdd H2SO4 = 19.6*100/10 = 196 (g) 

m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g) 

mFeSO4 = 0.2*152 = 30.4 (g) 

C% FeSO4 = 30.4/206.8 * 100% = 14.7% 

Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml) 

CM FeSO4 = 0.2 / 0.1719 = 1.16 M