a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)

Ta có: m _{dd Br2 tăng} = m_C2H4 = 2,8 (g)

\(\Rightarrow n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)

Có: \(n_{CH_4}=\dfrac{3,36}{22,4}-0,1=0,05\left(mol\right)\)

⇒ m _hh = m_CH4 + m_C2H4 = 0,05.16 + 0,1.28 = 3,6 (g)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{3,6}.100\%\approx22,22\%\\\%m_{C_2H_4}\approx77,78\%\end{matrix}\right.\)

a, Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)

\(16n_{CH_4}+28n_{C_2H_4}=3\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,1\left(mol\right)\\n_{C_2H_4}=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%\approx53,33\%\\\%m_{C_2H_4}\approx46,67\%\end{matrix}\right.\)

- Ở cùng điều kiện nhiệt độ và áp suất, % số mol cũng là %V.

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)

b, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Có: m _tăng = m_C2H4 = 0,05.28 = 1,4 (g)

a) \(n_{hh}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a+b=0,15\\16a+28b=3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\\%V_{C_2H_4}=100\%-66,67\%=33,33\%\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%=53,33\%\\\%m_{C_2H_4}=100\%-53,33\%=46,67\%\end{matrix}\right.\)

b) \(m=m_{C_2H_4}=0,05.28=1,4\left(g\right)\)

a, Ta có \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)

PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_4}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)

b, \(m_{CH_4}=0,05.16=0,8\left(g\right)\)

c, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,1}{1}=0,1\left(l\right)\)

\(m_{C_2H_4}=0,1.28=2,8\left(g\right)\)

\(n_{hh}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)

\(n_{Br_2}=\dfrac{24}{160}=0.15\left(mol\right)\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(0.15..........0.15\)

\(n_{CH_4}=0.4-0.15=0.25\left(mol\right)\)

\(\%V_{C_2H_4}=\dfrac{0.15}{0.4}\cdot100\%=37.5\%\)

\(\%V_{CH_4}=100-37.5=62.5\%\)

\(n_{hh}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(n_{Br_2}=0.1\cdot2=0.2\left(mol\right)\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(0.2..........0.2\)

\(n_{CH_4}=0.3-0.2=0.1\left(mol\right)\)

Câu b anh nghĩ phải là đốt cháy sau đó dẫn sản phẩm vào Ba(OH)₂ dư nha .

\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)

\(0.1.....................0.1\)

\(Ba\left(OH\right)_2+CO_2\rightarrow BaCO_3+H_2O\)

\(.............0.1.......0.1\)

\(m_{BaCO_3}=0.1\cdot197=19.7\left(g\right)\)

\(n_{hh}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(n_{Br_2}=n_{C_2H_4}=\dfrac{2}{160}=0.0125\left(mol\right)\)

\(\Rightarrow n_{CH_4}=0.3-0.0125=0.2875\left(mol\right)\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(\%V_{CH_4}=\dfrac{0.2875}{0.3}\cdot100\%=95.83\%\)

\(\%V_{C_2H_4}=100\%-95.83\%=4.17\%\)