đồng 3 oxit á ý c ik 

\(\left\{{}\begin{matrix}CuO:a\\Fe2O3:2a\end{matrix}\right.\)

a.\(80a+320a=24\Leftrightarrow a=0.06\)

\(\Rightarrow\left\{{}\begin{matrix}CuO=0.06\\Fe2O3=0.12\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}CuO=4.8g\\Fe2O3=19.2g\end{matrix}\right.\)

b.\(CuO+H2\rightarrow Cu+H2O\)

    a           a         a

\(Fe2O3+3H2\rightarrow2Fe+3H2O\)

    2a          6a       4a

\(\Rightarrow V_{H2}=\left(a+6a\right)\times22.4=9.408l\)

c.nHCl = 0.2 mol

\(Fe+2HCl\rightarrow FeCl2+H2\)

 0.1     0.2

m chất rắn còn lại = mCu + m Fe ban đầu - m Fe bị hòa tan

                             = \(a\times64+4a\times56-0.1\times56=11.68g\)

\(n_{H_2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)

PTHH: CuO + H₂ → Cu + H₂O

Mol:      x         x         x

PTHH: Fe₂O₃ + 3H₂ → 2Fe + 3H₂O

Mol:       y            3y        2y

Ta có hpt:\(\left\{{}\begin{matrix}80x+160y=14\\x+3y=0,225\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,075\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)

\(m_{hh.kim.loại}=m_{Cu}+m_{Fe}=0,075.64+2.0,05.56=10,4\left(g\right)\)

\(n_{H_2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)

PTHH:

\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)

Theo 2 pthh trên: \(n_{H_2O}=n_{H_2}=0,225\left(mol\right)\)

\(\rightarrow m_{H_2O}=0,225.18=4,05\left(g\right)\\ \rightarrow m_{H_2}=0,225.2=0,45\left(g\right)\)

Áp dụng ĐLBTKL, ta có:

\(m_{oxit\left(CuO,Fe_2O_3\right)}+m_{H_2}=m_{\text{kim loại}\left(Cu,Fe\right)}+m_{H_2O}\\ \rightarrow m_{\text{kim loại}\left(Cu,Fe\right)}=14+0,45-4,05=10,4\left(g\right)\)

\(n_{Pb}=\dfrac{2,07}{207}=0,01mol\)

\(n_{Cu}=\dfrac{1,6}{64}=0,025mol\)

\(PbO+H_2\rightarrow\left(t^o\right)Pb+H_2O\)

0,01    0,01            0,01            ( mol )

\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)

0,025  0,025        0,025            ( mol )

\(m_{hh}=m_{PbO}+m_{CuO}=\left(0,01.223\right)+\left(0,025.80\right)=4,23g\)

\(V_{H_2}=\left(0,01+0,025\right).22,4=0,784l\)

\(n_{Pb}=\dfrac{2,07}{207}=0,01\left(mol\right)\\ n_{Cu}=\dfrac{1,6}{64}=0,025\left(mol\right)\\ PTHH:PbO+H_2\underrightarrow{t^o}Pb+H_2O\\ Mol:0,01\leftarrow0,01\leftarrow0,01\\ CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Mol:0,025\leftarrow0,025\leftarrow0,025\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,025.80=2\left(g\right)\\m_{PbO}=0,01.223=2,23\left(g\right)\end{matrix}\right.\Rightarrow m_{oxit}=2+2,23=4,23\left(g\right)\\ V_{H_2}=\left(0,01+0,025\right).22,4=0,784\left(l\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,\%m_{Fe}=\dfrac{0,02.56}{4,36}.100\approx25,688\%\\ \Rightarrow\%m_{Ag}\approx74,312\%\\ b,Ta.thấy:2,18=\dfrac{1}{2}.4,36\\ \Rightarrow m_{hh\left(câuB\right)}=\dfrac{1}{2}.m_{hh\left(câuA\right)}\\ n_{Fe}=\dfrac{0,02}{2}=0,01\left(mol\right)\\ n_{Ag}=\dfrac{2,18-0,01.56}{108}=0,015\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ 2Ag+Cl_2\rightarrow\left(t^o\right)2AgCl\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+\dfrac{1}{2}.n_{Ag}=\dfrac{3}{2}.0,01+\dfrac{1}{2}.0,015=0,0225\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc\right)}=0,0225.22,4=0,504\left(l\right)\)

Theo đề gọi \(\left\{{}\begin{matrix}n_{Fe_2O_3}=3x\left(mol\right)\\n_{CuO}=2x\left(mol\right)\end{matrix}\right.\)

Có: \(m_{hh}=m_{Fe_2O_3}+m_{CuO}=160.3x+80.2x=32\)

\(\Rightarrow x=0,05\\ \Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,05.3=0,15\left(mol\right)\\n_{CuO}=0,05.2=0,1\left(mol\right)\end{matrix}\right.\)

\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)

0,15 ---->0,45-->0,3

\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

0,1 --->0,1-->0,1

a. \(m_{kim.loại}=m_{Fe}+m_{Cu}=0,3.56+0,1.64=23,2\left(g\right)\)

b. \(V_{H_2}=\left(0,45+0,1\right).22,4=12,32\left(l\right)\)

\(a,\\ Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ Fe_3O_4+4H_2\rightarrow\left(t^o\right)3Fe+4H_2O\)

Loại phản ứng: Phản ứng thế

\(b,n_{Fe}=2.n_{Fe_2O_3}+3.n_{Fe_3O_4}=2.\dfrac{32}{160}+3.0,15=0,85\left(mol\right)\\ m_{Fe}=0,85.56=47,6\left(g\right)\\ c,n_{H_2}=\dfrac{32}{160}.3+4.0,15=1,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=1,2.22,4=28\left(l\right)\)

Em xem sao oxit sắt lại hỏi KL nhôm nha! Vô lí!!!