a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)

b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)

\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)

\(\overline{M_x}=24.2=48\)

\(\left\{{}\begin{matrix}SO_2:64\\O_2:32\end{matrix}\right.\)       48    = \(\dfrac{16}{16}=1\)

\(\Rightarrow n_{SO_2=}n_{O_2}=0,3mol\)

1. \(m_{hh}=0,3.64+0,3.32=28,8g\)

2. \(\%V_{SO_2}=\dfrac{0,3.22,4}{13,44}.100\%=50\%\)

\(\Rightarrow\%V_{O_2}=50\%\)

3. \(m_{SO_2}=0,3.64=19,2g\)

\(m_{O_2}=0,3.32=9,6g\)

Áp dụng quy tắc đường chéo:

\(a.\\ \Rightarrow\dfrac{V_{Cl_2}}{V_{O_2}}=\dfrac{15,6}{23,4}=\dfrac{2}{3}\\ \Rightarrow\left\{{}\begin{matrix}\%V_{Cl_2}=40\%\\\%V_{O_2}=60\%\end{matrix}\right.\)

\(b.\) 

Ta có: \(\dfrac{n_{Cl_2}}{n_{O_2}}=\dfrac{2}{3}\Leftrightarrow\dfrac{m_{Cl_2}}{m_{O_2}}=\dfrac{71.2}{32.3}=\dfrac{71}{48}\Leftrightarrow48m_{Cl_2}-71m_{O_2}=0\)

Mặt khác: \(m_{Cl_2}+m_{O_2}=5,95\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Cl_2}=3,55\left(g\right)\\m_{O_2}=2,4\left(g\right)\end{matrix}\right.\)

Đặt x và y là số mol O 3  và  O 2  có trong 1 mol hỗn hợp khí

Hỗn hợp khí A : (48x + 32y)/(x+y) = 19,2 x 2 = 38,4

→ 3x = 2y → 40% O 3  và 60%  O 2

Đặt x và y là số mol  H 2  và CO có trong 1 mol hỗn hợp khí

Hỗn hợp khí B : (2x + 28y)/(x+y) = 3,6 x 2 = 7,2

→ x = 4y → 80%  H 2  và 20% CO

\(\overline{M}=16,75.2=33,5\). Áp dụng quy tắc đường chéo:

\(\Rightarrow\dfrac{x}{y}=\dfrac{10,5}{3,5}\Rightarrow\dfrac{x}{y}=3\Rightarrow x=3y\)

\(\%m_{NO}=\dfrac{30x}{30x+44y}.100\%=\dfrac{30.3y}{30.3y+44y}.100\%\simeq67,2\%\)

\(\Rightarrow\%m_{N_2O}=100\%-67,2\%=32,8\%\)

a) Gọi n_O2 =a (mol); n_O3 = b(mol)

Có: \(\dfrac{32a+48b}{a+b}=20.2=40\)

=> 32a + 48b = 40a + 40b

=> 8a = 8b => a = b

=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+a}.100\%=50\%\\\%V_{O_3}=100\%-50\%=50\%\end{matrix}\right.\)

b) Gọi n_N2 =a (mol); n_NO = b(mol)

Có: \(\dfrac{28a+30b}{a+b}=14,75.2=29,5\)

=> 28a + 30b = 29,5a + 29,5b

=> 1,5a = 0,5b

=> 3a = b

=> \(\left\{{}\begin{matrix}\%V_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+3a}.100\%=25\%\\\%V_{NO}=100\%-25\%=75\%\end{matrix}\right.\)

1)

Coi \(n_X = 1(mol)\)

Gọi : \(n_{CO_2} = a(mol) ; n_{N_2} = b(mol)\)

Ta có :

\(n_X = a + b = 1(mol)\\ m_X = 44a + 28b = 1.1,225.32(gam)\\ \Rightarrow a = 0,7 ; b = 0,3\)

Vậy :

\(\%V_{CO_2} = \dfrac{0,7}{1}.100\% = 70\%\\ \%V_{N_2} = 100\% - 70\% = 30\%\)

2)

\(n_X = \dfrac{1}{22,4}(mol)\\ \Rightarrow m_X = n.M = \dfrac{1}{22,4}.1,225.32 = 1,75(gam)\)

a)

$n_{Cl_2} :  n_{O_2} = 1 : 2$

Suy ra : 

$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$

b)

Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$

c)

$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$