là tâm trạng

muối sunfua k phải sunfat

Vì sau p/ứ thu được 2 kết tủa \(\Rightarrow\) Hỗn hợp không chứa NaF

Gọi công thức chung của 2 muối là NaX

PTHH: \(NaX+AgNO_3\rightarrow NaNO_3+AgX\downarrow\)

Theo PTHH: \(n_{NaX}=n_{AgX}\)

\(\Rightarrow\dfrac{26,45}{23+\overline{M}_X}=\dfrac{51,95}{108+\overline{M}_X}\) \(\Rightarrow\overline{M}_X\approx65,17\)

\(\Rightarrow\) 2 halogen cần tìm là Clo và Brom

Đặt \(\left\{{}\begin{matrix}n_{NaCl}=a\left(mol\right)=n_{AgCl}\\n_{NaBr}=b\left(mol\right)=n_{AgBr}\end{matrix}\right.\)

Ta lập được HPT:

\(\left\{{}\begin{matrix}58,5a+103b=26,45\\143,5a+188b=51,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=n_{NaCl}=0,1\left(mol\right)\\b=n_{NaBr}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Leftrightarrow\left\{{}\begin{matrix}\%m_{NaCl}=\dfrac{0,1\cdot58,5}{0,2\cdot143,5+0,1\cdot58,5}\cdot100\%\approx16,93\%\\\%m_{NaBr}=83,07\%\end{matrix}\right.\)

Tăng giảm khối lượng ta có; $n_{NaX}=\frac{2,35-1,5}{108-23}=0,01(mol)$

$\Rightarrow M_{NaX}=150\Rightarrow X=127$

Vậy CTHH của muối là NaI

Bảo toàn nguyên tố X và Ag ta có: $n_{AgNO_3}=n_{AgI}=0,01(mol)\Rightarrow C_{M}=1M$

PTHH: \(NaX+AgNO_3\rightarrow NaNO_3+AgX\downarrow\)

Theo PTHH: \(n_{NaX}=n_{AgX}\) 

\(\Rightarrow\dfrac{1,5}{23+X}=\dfrac{2,35}{108+X}\) \(\Leftrightarrow X=127\)  (Iot)

\(\Rightarrow\) Công thức: NaI

Ta có: \(n_{AgNO_3}=n_{NaI}=\dfrac{1,5}{150}=0,01\left(mol\right)\)

\(\Rightarrow C_{M_{AgNO_3}}=\dfrac{0,01}{0,01}=1\left(M\right)\)

\(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)

PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

a, \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\Rightarrow C\%_{HCl}=\dfrac{0,2.36,5}{200}.100\%=3,65\%\)

b, \(n_{CuCl_2}=n_{CuO}=0,1\left(mol\right)\)

\(\Rightarrow C\%_{CuCl_2}=\dfrac{0,1.135}{8+200}.100\%\approx6,49\%\)

\(n_{CuSO4}=\dfrac{16\%.50}{100\%.160}=0,05\left(mol\right)\)

Pt : \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

       0,05-------->0,1---------->0,05--------->0,05

a) \(C\%_{ddNaOH}=\dfrac{0,1.40}{250}.100\%=1,6\%\)

b) \(m_{ddspu}=50+250-0,05.98=295,1\left(g\right)\)

\(C\%_{Na2SO4}=\dfrac{0,05.142}{295,1}.100\%=2,41\%\)

\(n_{CuSO_4}=\dfrac{m_{dd}\cdot C\%}{100\cdot M}=\dfrac{50\cdot16\%}{100\cdot\left(64+32+16\cdot4\right)}=0,05\left(mol\right)\)

\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

                     1                  2                    1                    1

                   0,05              0,1                 0,05               0,05 (mol)

\(a)C\%_{NaOH}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{01\cdot100\cdot\left(23+16+1\right)}{250}=1,6\%\)

\(b)m_{dd-sau-pư}=m_{dd_đ}+m_{ct_đ}-m\downarrow-m\uparrow\)

\(=50+250-\left(0,05\cdot23+32+16\cdot4\right)=294,05\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{0,05\cdot100\cdot\left(23\cdot2+32+16\cdot4\right)}{294,05}\approx2,41\%.\)

nCuSO4​=100%.16016%.50​=0,05(mol)

Pt : ����4+2����→��(��)2+��2��4CuSO4​+2NaOH→Cu(OH)2​+Na2​SO4​

       0,05-------->0,1---------->0,05--------->0,05

a) �%������=0,1.40250.100%=1,6%C%ddNaOH​=2500,1.40​.100%=1,6%

b) ������=50+250−0,05.98=295,1(�)mddspu​=50+250−0,05.98=295,1(g)

�%��2��4=0,05.142295,1.100%=2,41%C%Na2SO4​=295,10,05.142​.100%=2,41%