Al ➝Al2(SO4)3➝Al➝Al2O3➝AlCl3➝Al(OH)3➞Al2O3➝Al➝AlCl3
a, Al=Al2O3= AlCl3=Al(OH)3=Al2O3=Al2S3
b, Al2O3=Al=Al2(SO4)3=AlCl3=Al(OH)3=Al2O3
al → al2o3 → al2(so4)3 → alcl3 → al(oh)3 → al(no3)3 → al → al2(so4)3 → al(oh)3 → al2o3 → al →naalo2
4Al+3O2----to--->2Al2O3
Al2O3 +3H2SO4----->Al2(SO4)3+3H2O
Al2(SO4)3+3BaCl2------>2AlCl3+3BaSO4
2AlCl3+3Ca(OH)2---->2Al(OH)3+3CaCl2
Al(OH)3+3HNO3---->Al(NO3)3+3H2O
2Al(NO3)3+3Mg----->3Mg(NO3)2+2Al
2Al+3H2SO4------->Al2(SO4)3+3H2
Al2(SO4)3+3Ca(OH)2------>2Al(OH)3+3CaSO4
2Al(OH)3-----to----->Al2O3+3H2O
2Al2O3----\(\dfrac{t^o}{criolit}\)---->4Al+3O2
2Al+2H2O+2NaOH------>2NaAlO2+3H2
4Al+3O2\(\underrightarrow{t^o}\) 2Al2O3
Al2O3+H2SO4 —> Al2(SO4)3+3H2O
Al2(SO4)3+3BaCl2–>3BaSO4\(\downarrow\)+2AlCl3
AlCl3+3NaOH—>Al(OH)3\(\downarrow\)+3NaCl
Al(OH)3+HNO3 —>Al(NO3)3+NO2\(\uparrow\)+H2O
2Al(NO3)3+3Mg—>3Mg(NO3)2+2Al\(\downarrow\)
2Al+3H2SO4–>Al2(SO4)3+3H2\(\uparrow\)
Al2(SO4)3+6NaOH—>2Al(OH)3+3Na2SO4
2Al(OH)3\(\underrightarrow{t^o}\)Al2O3+3H2O
2Al2O3\(\xrightarrow[criolit]{đien.phan.nong.chay}\)
4Al+3O2
2Al+2NaOH+2H2O—>2NaAlO2+3H2
\(\begin{array}{l} 4Al+3O_2\xrightarrow{t^o} 2Al_2O_3\\ Al_2O_3+3H_2SO_4\to Al_2(SO_4)_3+3H_2O\\ Al_2(SO_4)_3+3BaCl_2\to 3BaSO_4\downarrow+2AlCl_3\\ AlCl_3+3NaOH\to Al(OH)_3\downarrow+3NaCl\\ Al(OH)_3+3HNO_3\to Al(NO_3)_3+3H_2O\\ 2Al(NO_3)_3+3Mg\to 3Mg(NO_3)_2+2Al\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\uparrow\\ Al_2(SO_4)_3+6NaOH\to 2Al(OH)_3\downarrow+3Na_2SO_4\\ 2Al(OH)_3\xrightarrow{t^o} Al_2O_3+3H_2O\\ 2Al_2O_3\xrightarrow{\text{đpnc, Criolit}} 4Al+3O_2\uparrow\\ 2Al+2NaOH+2H_2O\to 2NaAlO_2+3H_2\uparrow\end{array}\)
Al->AlCl3->Al(OH)3->Al2(SO4)3->AlCl3->Al(NO3)3->Al(OH)3->Al2O3->Al(SO4)3
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(AlCl_3+3NaOH\rightarrow3NaCl+Al\left(OH\right)_3\)
\(2Al\left(OH\right)_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+6H_2O\)
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\)
\(AlCl_3+3AgNO_3\rightarrow3AgCl+Al\left(NO_3\right)_3\)
\(Al\left(NO_3\right)_3+3KOH\rightarrow3KNO_3+Al\left(OH\right)_3\)
\(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
\(Al+\dfrac{3}{2}Cl_2\rightarrow AlCl_3\\ AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\\ 2Al\left(OH\right)_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+6H_2O\\ Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\\ Al\left(NO_3\right)_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaNO_3\\ 2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\\ Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
Bài 3: Hoàn thành chuỗi phản ứng sau:
a. Al → Al2O3→Al2(SO4)3→Al(OH)3 →Al2O3→Al →NaAlO2
b.Al→AlCl3→Al(NO3)3→Al(OH)3→Al2(SO4)3→AlCl3→Al
c. Fe→FeCl2→Fe(OH)2→FeSO4→Fe(NO3)2→Fe→Fe3O4→Fe
d.Fe→FeCl3→Fe→Fe3O4→FeSO4.
Bài 3: Hoàn thành chuỗi phản ứng sau:
a. Al → Al2O3→Al2(SO4)3→Al(OH)3 →Al2O3→Al →NaAlO2
b.Al→AlCl3→Al(NO3)3→Al(OH)3→Al2(SO4)3→AlCl3→Al
c. Fe→FeCl2→Fe(OH)2→FeSO4→Fe(NO3)2→Fe→Fe3O4→Fe
d.Fe→FeCl3→Fe→Fe3O4→FeSO4.
Al --> Al2O3 --> AlCl3 --> Al2(SO4)3 --> Al(OH)3 --> Al2O3 --> Al
2Al + 3/2O2 ---> Al2O3
Al2O3 + 6HCl ---> 2AlCl3 + 3H2O
2AlCl3 + 3Ag2SO4 ---> Al2(SO4)3 + 6AgCl
Al2(SO4)3 + 6NaOH ---> 2Al(OH)3 + 3Na2SO4
2Al(OH)3 --to--> Al2O3 +3H2O
Al2O3 --dpnc(có trộn cryolit Na3AlF6)--> 2Al + 3/2O2
a)Mg(OH)2------> MgO--------> MgSO4--------> MgCl2---------> Mg(OH)2
b) Al2O3---------> Al----------> AlCl3--------> Al(NO3)3--------> Al2O3------> Al2(SO4)3
a)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
\(MgSO_4+BaCl_2\rightarrow BaSO_4\downarrow+MgCl_2\)
\(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2\downarrow+2NaCl\)
b)
\(2Al_2O_3\xrightarrow[criolit]{npnc}4Al+3O_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\downarrow\)
\(4Al\left(NO_3\right)_3\underrightarrow{t^o}2Al_2O_3+12NO_2+3O_2\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
Hoàn thành chuỗi biến hóa sau:
a) Fe → FeCl2 → Fe(OH)2 → Fe(OH)3 → Fe2O3 → FeCl3
b) Al → Al2O3 → AlCl3 → Al(OH)3 → Al2O3 → Al2(SO4)3
a.
\(\left(1\right)Fe+2HCl--->FeCl_2+H_2\)
\(\left(2\right)FeCl_2+2NaOH--->2NaCl+Fe\left(OH\right)_2\)
\(\left(3\right)4Fe\left(OH\right)_2+O_2+2H_2O\overset{t^o}{--->}4Fe\left(OH\right)_3\)
\(\left(4\right)2Fe\left(OH\right)_3\overset{t^o}{--->}Fe_2O_3+3H_2O\)
\(\left(5\right)Fe_2O_3+6HCl--->2FeCl_3+3H_2O\)
b.
\(\left(1\right)4Al+3O_2\overset{t^o}{--->}2Al_2O_3\)
\(\left(2\right)Al_2O_3+6HCl--->2AlCl_3+3H_2O\)
\(\left(3\right)AlCl_3+3NaOH--->Al\left(OH\right)_3+3NaCl\)
\(\left(4\right)2Al\left(OH\right)_3\overset{t^o}{--->}Al_2O_3+3H_2O\)
\(\left(5\right)Al_2O_3+3H_2SO_4--->Al_2\left(SO_4\right)_3+3H_2O\)
Hoàn thành chuỗi biến hóa sau:
a) Fe → FeCl2 → Fe(OH)2 → Fe(OH)3 → Fe2O3 → FeCl3
b) Al → Al2O3 → AlCl3 → Al(OH)3 → Al2O3 → Al2(SO4)3
\(b,\left(1\right)4Al+3O_2\rightarrow^{t^o}2Al_2O_3\\ \left(2\right)Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\\ \left(3\right)AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\\ \left(4\right)2Al\left(OH\right)_3\rightarrow^{t^o}Al_2O_3+3H_2O\\ \left(5\right)Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
\(a,\left(1\right)Fe+2HCl\rightarrow FeCl_2+H_2\\ \left(2\right)FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl_2\\ \left(3\right)4Fe\left(OH\right)_2+O_2+2H_2O\rightarrow4Fe\left(OH\right)_3\\ \left(4\right)2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\\ \left(5\right)Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)