\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)

\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)

\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)

nP= 0.1 mol

nO2= 0.15 mol

4P + 5O2 -to-> 2P2O5

4____5

0.1___0.15

Lập tỉ lệ: 0.1/4 < 0.15/5 => O2 dư

nO2 dư= 0.15 - 0.125=0.025 mol

mO2 dư= 0.8g

nP2O5= 0.05 mol

mP2O5= 7.1g

\(n_P = \dfrac{6,2}{31} = 0,2(mol)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)

Do đó : O₂ dư.

4P       +        5O₂        \(\xrightarrow{t^o} \)  2P₂O₅

0,2..............0,25..................0,1..................(mol)

\(n_{O_2\ dư} = 0,3 - 0,25 = 0,05(mol)\)

\(m_{P_2O_5} = 0,1.142 = 14,2(gam)\)

\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)

\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)

4P + 5O₂ \(\underrightarrow{t^o}\) 2P₂O₅

\(\dfrac{0,1}{4}< \dfrac{0,2}{5}\) => O₂ dư, Photpho đủ

\(n_{O_2}=0,2-0,04=0,16\left(mol\right)\)

\(m_{P_2O_5}=\) 0,05 . 142 = 7,1 ( g )

nP = 2,48/31 = 0,08 (mol)

PTHH: 4P + 5O2 -> (t°) 2P2O5

Mol: 0,08 ---> 0,1 ---> 0,04

mP2O5 = 0,04 . 142 = 5,68 (g)

b) nO2 = 4/32 = 0,125 (mol)

So sánh: 0,125 > 0,1 => O2 dư

nO2 (dư) = 0,125 - 0,1 = 0,025 (mol)

mO2 (dư) = 0,025 . 32 = 0,8 (g)

\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\\ n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,1}{4}>\dfrac{0,1}{5}\) 
=> P dư 
\(n_{P\left(p\text{ư}\right)}=\dfrac{4}{5}n_{O_2}=0,08\left(mol\right)\\ m_{P\left(d\right)}=\left(0,1-0,08\right).31=0,62\left(g\right)\)

\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\\ n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\)

PTHH: \(4P+5O_2\xrightarrow[]{t^o}2P_2O_5\)

bđ      0,1       0,1

pư     0,08     0,1

spư    0,02     0         

=> P dư

\(m_{P\left(dư\right)}=0,02.31=0,62\left(g\right)\)

nP = 6.2/31 = 0.2 (mol) 

nO2 = 6.72/22.4 = 0.3 (mol) 

4P + 5O2 -to-> 2P2O5 

0.2___0.25_____0.1

mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g) 

mP2O5 = 0.1*142 = 14.2 (g) 

Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)

\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)

PTHH:

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

ta có:

\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)

=> \(O_2\) dư 

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

4   ----------->2                

0.2---------->0.1=n_P2O5

=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)