\(n_{CuSO_4}=2.0,34=0,68(mol)\\ a,CuSO_4+2NaOH\to Na_2SO_4+Cu(OH)_2\downarrow\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{Cu(OH)_2}=0,68(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,68.98=66,64(g)\\ b,n_{CuO}=0,68(mol)\\ \Rightarrow m_{CuO}=0,68.80=54,4(g)\\ c,V_{dd_{NaOH}}=\dfrac{200}{1,25}=160(ml)\\ n_{NaOH}=\dfrac{200.32\%}{100\%.40}=1,6(mol)\)

Vì \(\dfrac{n_{CuSO_4}}{1}<\dfrac{n_{NaOH}}{2}\) nên \(NaOH\) dư

\(\Rightarrow n_{NaOH(dư)}=1,6-0,68.2=0,24(mol); n_{Na_2SO_4}=0,68(mol)\\ \Rightarrow \begin{cases} C_{M_{NaOH(dư)}}=\dfrac{0,24}{0,16}=1,5M\\ C_{M_{Na_2SO_4}}=\dfrac{0,68}{0,16}=4,25M \end{cases}\)

a, \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)

b, \(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)

Theo PT: \(n_{CuCl_2}=n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,125\left(mol\right)\)

\(\Rightarrow m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)

c, \(C_{M_{CuCl_2}}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)

\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)

a) PTHH : \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)

                   0,125<-----0,25---------------------->0,125

b) \(m_{Kt}=m_{Cu\left(OH\right)2}=0,125.98=12,25\left(g\right)\)

c) \(C_{MCuCl2}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)

\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)

PTHH:

\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)

0,125       0,25                0,125         0,25

\(m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)

\(C_{M\left(CuCl_2\right)}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)

PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)

            \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,2\cdot2=0,4\left(mol\right)\\n_{NaOH}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) \(\Rightarrow\) CuCl₂ còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,4\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}=n_{CuCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2\cdot80=16\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,2+0,2}=1\left(M\right)\\C_{M_{CuCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\\\end{matrix}\right.\)

\(n_{CuSO_4}=\dfrac{20}{160}=0,125(mol)\\ a,CuSO_4+2NaOH\to Cu(OH)_2\downarrow+2NaCl\\ \Rightarrow n_{NaOH}=0,25(mol)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{0,25}{0,2}=1,25M\\ b,n_{Cu(OH)_2}=0,125(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,125.98=12,25(g)\\ c,Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=0,125(mol)\\ \Rightarrow m_{CuO}=0,125.80=10(g)\)

Đáp án:

m =32,4g

mddH2SO4 = 49g

Giải thích các bước giải:

a) MgCO3 + H2SO4 → MgSO4 + H2O +CO2 ↑

MgSO4 + 2NaOH → Mg(OH)2 + Na2SO4

$Mg{(OH)_2}\buildrel {to} \over

\longrightarrow MgO + {H_2}O$

b) nCO2 = 2,24 : 22,4 = 0,1mol

nMgCO3 = nCO2 = 0,1 mol

nMgO = 12:40=0,3mol

nMgSO4 = nMgO - nMgCO3 = 0,3 - 0,1 = 0,2mol

m = mMgCO3 + mMgSO4

= 0,1 .84+0,2.120=32,4g

nH2SO4 = nCO2 = 0,1 mol

mH2SO4 = 0,1.98=9,8g

mddH2SO4 = 9,8:20.100=49g

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Đáp án A

→ a =   0 , 0325

a.

b.