Theo đề ta có : nX = \(\dfrac{0,112}{22,4}=0,005\left(mol\right)\)

Ta có : \(MX=2.28=56\left(\dfrac{g}{mol}\right)\)

Ta có sơ đồ đường chéo :

=> nCO2/nSO2 = 3/2

=> nCO2 = 0,002 ; nSO2 = 0,003

=> %VCO2 = 40% ; %VSO2 = 60%

Theo giả thiết ta có : nCO2 = 6,72/22,4 = 0,3 (mol)

a) PTHH :

0,3mol......0,3mol................0,3mol.........0,3mol

b) nồng độ mol của dd Ba(OH)2 đã dùng là :

Câu 15: 

Bảo toàn nguyên tố: \(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)=n_{BaCO_3}=n_{Ba\left(OH\right)_2}\)

\(\Rightarrow\left\{{}\begin{matrix}m_{BaCO_3}=0,3\cdot197=59,1\left(g\right)\\C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,3}{0,6}=0,5\left(M\right)\end{matrix}\right.\)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\\ CO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ n_{BaCO_3}=n_{CO_2}=0,1mol\\ Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4+2H_2O\\ n_{H_2SO_4}=n_{Ba\left(OH\right)_2}=0,1mol\\ m_{ddH_2SO_4}=\dfrac{0,1.98}{20\%}\cdot100\%=49g\\ V_{ddH_2SO_4}=\dfrac{49}{1,14}=42,98ml\)

MgO+H₂SO₄ → MgSO₄+H₂O(1)

MgCO₃+H₂SO₄ → MgSO₄+ CO₂+H₂O (2)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT (2): n_MgCO3=n_CO2=0,1mol

=> m_MgCO3=0,1.84=8,4g

m_MgO=16,4-8,4=8g

=> n_MgO=\(\dfrac{8}{40}\) = 0,2mol

Theo PT (1,2) ta có:n_MgSO4=n_MgO+n_MgCO3=0,1+0,2=0,3 mol

n_Ba(OH)2=0,3.1,5 = 0,45 mol

Gọi x là số mol H₂SO₄ còn dư sau phản ứng (1,2).

H₂SO₄+Ba(OH)₂→BaSO₄↓+2H₂O(3)

MgSO₄+Ba(OH)₂→BaSO₄↓+Mg(OH)₂↓(4)

Kết tủa tạo thành gồm BaSO₄ và Mg(OH)₂

Do đó dd B thu được là Ba(OH)₂ dư

Ta có: 233x + 233.0,3 + 58.0,3 =110,6

=>x=0,1mol

Theo PT (3,4): n_{Ba(OH)2 pứ}=n_H2SO4+n_MgSO4=0,1+0,3=0,4mol

n_Ba(OH)2(dư)=0,45−0,4=0,05mol

CM_Ba(OH)2=\(\dfrac{0,05}{0,5}\)=0,1M

Ta có: \(n_{Ba\left(OH\right)_2}=0,025.0,02=0,0005\left(mol\right)\)

\(n_{NaOH}=0,025.0,05=0,00125\left(mol\right)\)

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}+n_{NaOH}=0,00225\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(\Rightarrow n_{H^+}=n_{OH^-}=0,00225\left(mol\right)\)

Gọi: V_X = x (l)

Ta có: \(n_{HCl}=0,1x\left(mol\right)\)

\(n_{CH_3COOH}=0,2x\left(mol\right)\)

\(\Rightarrow n_{H^+}=n_{HCl}+n_{CH_3COOH}=0,1x+0,2x=0,00225\)

\(\Rightarrow x=0,0075\left(l\right)=7,5\left(ml\right)\)

\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)

Theo PT:  \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,25\left(mol\right)\)

a, \(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)

b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)

c, \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)

Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}=0,5\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{20\%}=91,25\left(g\right)\)

PTHH: \(HCl+KOH\rightarrow KCl+H_2O\)

            \(2HCl_{\left(dư\right)}+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)

Axit dư nên tính theo KOH

Ta có: \(\left\{{}\begin{matrix}\Sigma n_{HCl}=\dfrac{109,5}{36,5}=3\left(mol\right)\\n_{KOH}=\dfrac{112}{56}=2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow n_{HCl\left(dư\right)}=1\left(mol\right)\)

\(\Rightarrow n_{Ba\left(OH\right)_2}=0,5\left(mol\right)\) \(\Rightarrow m_{ddBa\left(OH\right)_2}=\dfrac{0,5\cdot171}{25\%}=342\left(g\right)\)