$2NaHCO_3 + 2KOH \to Na_2CO_3 + K_2CO_3 + 2H_2O$
$n_{NaHCO_3} = n_{KOH} = 0,2.0,5 = 0,1(mol)$
$2NaOH + CO_2 \to Na_2CO_3 + H_2O$
$NaOH +C O_2 \to NaHCO_3$
$n_{NaOH} = 2n_{Na_2CO_3} + n_{NaHCO_3}$
$\Rightarrow n_{Na_2CO_3} = \dfrac{0,4 - 0,1}{2} = 0,15(mol)$

$\Rightarrow n_{CO_2} = 0,15 + 0,1 = 0,25(mol)$
$V = 0,25.22,4 = 5,6(lít)$

n_CO2=\(\dfrac{5.6}{22.4}\)=0.25 mol

n_KOH=0.4 mol

Xét tỉ lệ 1< \(\dfrac{n_{KOH}}{n_{CO2}}=\dfrac{0.4}{0.25}=1.6\)<2

=> DD A gồm K₂CO₃ và KHCO₃

2KOH+ CO₂ -----> K₂CO₃+ H₂O (1)

a.............0.5a..............0.5a......0.5a

KOH+ CO₂ -------> KHCO₃ (2)

b.............b....................b

Đặt a, b là số mol KOH ở (1), (2)

Theo đề bài ta có hệ pt\(\left\{{}\begin{matrix}n_{KOH}=a+b=0.4\\n_{CO2}=0.5a+b=0.25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0.3\\b=0.1\end{matrix}\right.\)

=>m_K2CO3=0.5a*138=20.7 g

=>m_KHCO3=b*100=10 g

\(n_{CO_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)

\(n_{NaOH}=\dfrac{12}{40}=0.3\left(mol\right)\)

\(T=\dfrac{0.3}{0.15}=2\)

\(\Rightarrow\text{Tạo ra muối trung hòa}\)

\(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\)

\(0.3...........0.15..............0.15\)

\(m_{Na_2CO_3}=0.15\cdot106=15.9\left(g\right)\)

Ta có: \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\)

\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=2\). Vậy: Pư tạo muối trung hòa Na₂CO₃.

PT: \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)

___0,15______________0,15 (mol)

⇒ m_Na2CO3 = 0,15.106 = 15,9 (g)

Bạn tham khảo nhé!

tỉ lệ mol: \(\dfrac{nNaOH}{nCO2}=\dfrac{\dfrac{12}{40}}{\dfrac{3,36}{22,4}}=2\)=>tạo muối Na2CO3

pthh: CO2+2NaOH->Na2CO3+H2O

=>nNa2CO3=nCO2=0,15mol=>mNa2CO3=0,15.106=15,9 gam

vậy Tính khối lượng muối tan trong dd X là 15,9 g

\(n_{CO_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)

\(n_{NaOH}=\dfrac{8}{40}=0.2\left(mol\right)\)

\(T=\dfrac{0.2}{0.2}=1\)

\(\Rightarrow\text{Tạo muối axit}\)

\(NaOH+CO_2\rightarrow NaHCO_3\)

\(0.2...............0.2............0.2\)

\(m_{NaHCO_3}=0.2\cdot84=16.8\left(g\right)\)

Ta có: \(n_{CO_2}=0,2\left(mol\right)\)

\(n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)

\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1\) ⇒ Pư tạo muối NaHCO₃.

PT: \(CO_2+NaOH\rightarrow NaHCO_3\)

___0,2________________0,2 (mol)

⇒ m_NaHCO3 = 0,2.84 = 16,8 (g)

Bạn tham khảo nhé!

\(\dfrac{nNaOH}{nCO2}=\dfrac{\dfrac{8}{40}}{\dfrac{4,48}{22,4}}=1\)=>tạo muối NaHCO3

pthh CO2+NaOH->NaHCO3=>nNaHCO3=NCO2=0,2mol

=>mNaHCO3=0,2.84=16,8 g

\(n_{CO_2}=\dfrac{7.84}{22.4}=0.35\left(mol\right)\)

\(n_{NaOH}=\dfrac{16}{40}=0.4\left(mol\right)\)

\(T=\dfrac{0.4}{0.35}=1.14\)

\(\Rightarrow\text{Tạo ra 2 muối}\)

\(n_{Na_2CO_3}=a\left(mol\right),n_{NaHCO_3}=b\left(mol\right)\)

\(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\)

\(NaOH+CO_2\rightarrow NaHCO_3\)

\(\left\{{}\begin{matrix}2a+b=0.4\\a+b=0.35\end{matrix}\right.\)

\(\Leftrightarrow\left\{{}\begin{matrix}a=0.05\\b=0.3\end{matrix}\right.\)

\(m_{Na_2CO_3}=0.05\cdot106=5.3\left(g\right)\)

\(m_{NaHCO_3}=0.3\cdot84=25.2\left(g\right)\)

\(n_{H_2S}=0,08\left(mol\right),n_{OH^-}=0,1.0,05+0,1.0,08=0,013\left(mol\right)\)

T=\(\dfrac{0,013}{0,08}=0,1625\)=> Tạo 1 muối HS- , H2S dư

Muối gồm KHS và NaHS

=> \(m_{muối}=0,1.0,05.56+0,1.0,08.72=0,856\left(g\right)\)