a) Gọi n Zn = a(mol) ; n ZnO =  b(mol)

=> 65a + 81b = 14,6(1)

$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$

n ZnCl2 = a + b = 27,2/136 = 0,2(2)

Từ (1)(2) suy ra : a = b = 0,1

%m Zn = 0,1.65/14,6  .100% = 44,52%
%m ZnO = 100% -44,52% = 55,45%

b)

n HCl = 2n Zn + 2n ZnO = 0,4(mol)

m dd HCl = 0,4.36,5/7,3% = 200(gam)

a) CuO + 2HCl ⟶CuCl2 + 2H2O 

6HCl + Fe2O3 → 2FeCl3 + 3H2O

Gọi x, y lần lượt là số mol CuO, Fe2O3

\(\left\{{}\begin{matrix}80x+160y=16\\135x+162,5.2y=29,75\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)

=> \(\%m_{CuO}=\dfrac{0,1.80}{16}.100=50\%\)

\(\%m_{Fe_2O_3}=100-50=50\%\)

b) \(n_{HCl}=2n_{CuO}+6n_{Fe_2O_3}=0,5\left(mol\right)\)

=> \(CM_{HCl}=\dfrac{0,3}{0,1}=3M\)

Gọi số mol Fe₂O₃, CuO là a, b (mol)

n_HCl = 0,3.2 = 0,6 (mol)

PTHH: Fe₂O₃ + 6HCl --> 2FeCl₃ + 3H₂O

                 a----->6a------->2a

            CuO + 2HCl --> CuCl₂ + H₂O

              b----->2b------->b

=> \(\left\{{}\begin{matrix}\dfrac{2a}{b}=\dfrac{3}{4}\\6a+2b=0,6\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}a=\dfrac{9}{170}\left(mol\right)\\b=\dfrac{12}{85}\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{\dfrac{9}{170}.160}{\dfrac{9}{170}.160+\dfrac{12}{85}.80}.100\%=42,857\%\\\%m_{CuO}=\dfrac{\dfrac{12}{85}.80}{\dfrac{9}{170}.160+\dfrac{12}{85}.80}.100\%=57,143\%\end{matrix}\right.\)

\(n_{HCl}=0,3.2=0,6\left(mol\right)\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,6}{2}>\dfrac{0,25}{1}\Rightarrow HCldư\\ Đặt:n_{Al}=t\left(mol\right);n_{Fe}=r\left(mol\right)\\ \left(t,r>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27t+56r=8,3\\1,5t+r=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}t=0,1\\r=0,1\end{matrix}\right.\\ \Rightarrow m_{Al}=0,1.27=2,7\left(g\right);m_{Fe}=0,1.56=5,6\left(g\right)\\ b,n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\Rightarrow m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\ n_{Fe}=n_{FeCl_2}=0,1\left(mol\right)\Rightarrow m_{ddFeCl_2}=127.0,1=12,7\left(g\right)\\ m_{ddHCl}=300.1,15=345\left(g\right)\\ m_{ddsau}=8,3+345-0,25.2=352,8\left(g\right)\)

\(n_{HCl\left(dư\right)}=0,6-0,25.2=0,1\left(mol\right)\\ \Rightarrow m_{ddHCl}=0,1.36,5=3,65\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{3,65}{352,8}.100\approx1,035\%\\ C\%_{ddAlCl_3}=\dfrac{13,35}{352,8}.100\approx3,784\%\\ C\%_{ddFeCl_2}=\dfrac{12,7}{352,8}.100\approx3,6\%\)

a) \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

_____0,2<---0,6<--------------0,3

=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,2.27}{15,6}.100\%=34,615\%\\\%Al_2O_3=\dfrac{15,6-0,2.27}{15,6}.100\%=65,385\%\end{matrix}\right.\)

b) \(n_{Al_2O_3}=\dfrac{15,6-0,2.27}{102}=0,1\left(mol\right)\)

PTHH: Al₂O₃ + 6HCl --> 2AlCl₃ + 3H₂O

______0,1--->0,6

=> n_HCl = 0,6+0,6 = 1,2(mol)

=> \(V_{dd}=\dfrac{1,2}{2}=0,6\left(l\right)\)

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