Bài 10:

- Giả sử có 100 gam dd H₂SO₄ 98%

\(m_{H_2SO_4}=\dfrac{100.98}{100}=98\left(g\right)\) => \(n_{H_2SO_4}=\dfrac{98}{98}=1\left(mol\right)\)

\(V_{dd.H_2SO_4.98\%}=\dfrac{100}{1,84}=\dfrac{1250}{23}\left(ml\right)=\dfrac{5}{92}\left(l\right)\)

\(C_{M\left(dd.H_2SO_4.98\%\right)}=\dfrac{1}{\dfrac{5}{92}}=18,4M\)

\(n_{H_2SO_4}=18,4.0,05=0,92\left(mol\right)\)

=> \(m_{H_2SO_4}=0,92.98=90,16\left(g\right)\)

=> \(m_{dd.H_2SO_4.10\%}=\dfrac{90,16.100}{10}=901,6\left(g\right)\)

Bài 11:

a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau

=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)

Gọi số mol Al, Zn là a, b (mol)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

             a----->1,5a------->0,5a----->1,5a

            Zn + H₂SO₄ --> ZnSO₄ + H₂

             b----->b--------->b----->b

=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)

=> 171a = 161b 

=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)

Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)

b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)

(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)

=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)

\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)

=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)

=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)

n Al 2 SO 4 3  = 0,05/3 x 1 ≈ 0,017 mol

C M   Al 2 SO 4 3  = 0,017/0,1 = 0,17M

\(a,n_{HCl}=3.0,2=0,6(mol)\\ PTHH:X(OH)_n+nHCl\to XCl_n+nH_2O\\ \Rightarrow n.n_{X(OH)_n}=n_{HCl}=0,6(mol)\\ \Rightarrow M_{X(OH)_n}=\dfrac{15,6n}{0,6}=26n\\ \Rightarrow M_X+17n=26n\\ \Rightarrow M_X=9n\)

Thay \(m=3\Rightarrow M_X=27(g/mol)\)

Vậy X là nhôm (Al) và CT của bazơ là \(Al(OH)_3\)

\(b,n_{Al(OH)_3}=\dfrac{15,6}{78}=0,2(mol)\\ n_{H_2SO_4}=\dfrac{196.20\%}{100\%.98}=0,4(mol)\\ PTHH:2Al(OH)_3+3H_2SO_4\to Al_2(SO_4)_3+6H_2O\)

Vì \(\dfrac{n_{Al(OH)_3}}{2}<\dfrac{n_{H_2SO_4}}{3}\) nên \(H_2SO_4\) dư

\(\Rightarrow n_{Al_2(SO_4)_3}=\dfrac{1}{2}n_{Al(OH)_3}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{15,6+196}.100\%=16,16\%\)

1.

n_Al=\(\dfrac{5,4}{27}\)=0,2 mol

m_HCl=\(\dfrac{175.14,6}{100}\)=25,55g

n_HCl=\(\dfrac{25,55}{36,5}\)=0,7

                     2Al + 6HCl → 2AlCl₃ + 3H₂↑

n trước pứ    0,2     0,7  

n pứ              0,2 →0,6  →    0,2  →  0,3  mol

n sau pứ       hết   dư 0,1

Sau pứ HCl dư.

m_HCl (dư)= 36,5.0,1=3,65g

m_{các chất sau pư}= 5,4 +175 - 0,3.2= 179,8g

m_AlCl3= 133,5.0,2=26,7g

C%_ddHCl (dư)= \(\dfrac{3,65.100}{179,8}=2,03%\)%

C%_ddAlCl3 = \(\dfrac{26,7.100}{179,8}\)= 14,85%

2.

           200ml= 0,2l

m_Mg= \(\dfrac{4,2}{24}=0,175mol\)

    Mg + 2HCl → MgCl₂ + H₂↑

0,175→ 0,35 → 0,175→0,175 mol

a) V_H2= 0,175.22,4=3,92l.

b)C%_dHCl= \(\dfrac{0,35}{0,2}=1,75\)M

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)

Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)

c, Ta có: m _{dd HCl} = 1,05.500 = 525 (g)

m _{dd sau pư} = m_hh + m _{dd HCl} - m_H2 = 541,2 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)

\(a,n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\\ C_{M\left(HCl\right)}=\dfrac{0,2}{0,4}=0,5M\\ b,n_{H_2SO_4}=\dfrac{73,5}{98}=0,75\left(mol\right)\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,75}{0,5}=1,5M\\ n_{NaOH}=\dfrac{16}{40}=0,4\left(mol\right)\\ C_{M\left(NaOH\right)}=\dfrac{0,4}{0,25}=1,6M\\ n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\\ C_{M\left(Ba\left(OH\right)_2\right)}=\dfrac{0,2}{0,8}=0,25M\)

Khj cho B td H2SO4 ko co chat khj thoat ra chung to Al va Zn da pu het. 
nCu(NO3)2=0,03=>nCu[+2]=0,03. 
nAgNO3=0,01=>nAg+=0,01 
goi x,y la so mol Al,Zn. 
Al>Al[+3]+3e 
Zn>Zn[+2]+2e 
=>ne nhuog=3x+2y 
Cu[+2]+2e>Cu 
Ag+ + 1e>Ag 
=>ne nhan=0,03.2+0,01=0,07 
theo dlbt e=>3x+2y=0,07 
27x+65y=1,57 
=>x=0,01,y=0,02 
=>nAl(NO3)3=0,01 
=>mAl(NO3)3=2,13g 
nZn(NO3)2=nZn[+2]=0,02=>mZn(NO3)2=3,78g 
khoi luog Cu va Ag la=0,03.64+0,01.108=3g 
=>kl dd giam la 3-1,57=1,43 
=>kl dd luc sau la 101,43-1,43=100g 
=>C%Al(NO3)3=2,13/100=2,13% 
C%Zn(NO3)2=3,78% 

PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

a, Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)

\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\). ta được H₂SO₄ dư.

Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)

b, Ta có: \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)

c, \(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5M\)

\(C_{M_{ZnSO_4}}=\dfrac{0,1}{0,2}=0,5M\)

Bạn tham khảo nhé!

1.nH2=5.04/22.4=0.225mol

Đặt x,y lần lượt là số mol của Al,Mg

a)2Al + 3H2SO4 --> Al2(SO4)3 + 3H2

      x                                                    3/2 x                    

 Mg+ H2SO4 --> MgSO4 + H2

 y                                            y

b) theo đề, ta có hệ pt: 27x + 24y= 4.5

                                      1.5x + y =0.225

giải hệ pt trên,ta có :x=0.1 ; y=0.075

thay vào pt,suy ra :

mAl=0.1*27=2.7g =>%Al=(2.7/4.5)*100=60%

=>%Mg=40%

vậy % của Al,Mg lần lượt là 60% và 40%

2.nAl=5.4/27=0.2mol

 nH2SO4=0.5*0.1=0.05 mol

pt:2Al + 3H2SO4 --> Al2(SO4)3 + 3H2

   0.2           0.05               0.02          0.05

a)theo pt, ta thấy Al dư

VH2=0.05*22.4=1.12 l

b)CM_Al2(SO4)3= 0.02/0.1=0.2M

Bài này không khó đâu nh,tính theo pthh thôi à.

Chúc em học tốt!!!:))