Áp dụng sơ đồ đường chéo ta có:

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{H_2SO_4}=0.3\cdot0.5=0.15\left(mol\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.1..........0.05...............0.05\)

Dung dịch D : 0.05 (mol) K₂SO₄ , 0.1 (mol) H₂SO₄

\(\left[K^+\right]=\dfrac{0.05\cdot2}{0.1+0.3}=0.25\left(M\right)\)

\(\left[H^+\right]=\dfrac{0.1\cdot2}{0.1+0.3}=0.5\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.1}{0.1+0.3}=0.375\left(M\right)\)

\(2NaOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.2..................0.1\)

\(V_{dd_{NaOH}}=\dfrac{0.2}{1}=0.2\left(l\right)\)

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{HCl}=0.1\cdot0.5=0.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.05.......0.05.......0.05\)

Dung dịch D : 0.05 (mol) KOH , 0.05 (mol) KCl

\(\left[K^+\right]=\dfrac{0.05+0.05}{0.1+0.1}=0.5\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

\(0.05.........0.025\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.025}{1}=0.025\left(l\right)\)

a)

$KOH + HCl \to KCl + H_2O$

$n_{KOH} = 0,3(mol) < n_{HCl} = 1,05(mol)$ nên HCl dư

$n_{HCl\ dư} = 1,05 -0 ,3 = 0,75(mol)$
$n_{KCl} = n_{KOH} = 0,3(mol)$

$V_{dd} = 0,3+ 0,7 = 1(lít)$
Suy ra : 

$[K^+] = \dfrac{0,3}{1} = 0,3M$
$[Cl^-] = \dfrac{0,75 + 0,3}{1} = 1,05M$
$[H^+] = \dfrac{0,75}{1} = 0,75M$

b)

$Ba(OH)_2 + 2HCl \to BaCl_2 + 2H_2O$
$n_{Ba(OH)_2} = \dfrac{1}{2}n_{HCl} = 0,375(mol)$

$V_{Ba(OH)_2} = \dfrac{0,375}{1,5} = 0,25(lít)$

\(n_{KOH}=0.3\cdot1=0.3\left(mol\right)\)

\(n_{HCl}=0.7\cdot1.5=1.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.3...........0.3..........0.3\)

Dung dịch D gồm : 0.3 (mol) KCl , 0.75 (mol) HCl dư

\(\left[K^+\right]=\dfrac{0.3}{0.3+0.7}=0.3\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.3+0.75}{0.3+0.7}=1.05\left(M\right)\)

\(\left[H^+\right]=\dfrac{0.75}{0.3+0.7}=0.75\left(M\right)\)

\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

\(0.375..................0.75\)

\(V_{dd_{Ba\left(OH\right)_2}}=\dfrac{0.375}{1.5}=0.25\left(l\right)\)

[K+]=[Cl-]=0,25M

[KOH dư]=0,25M

b)   2KCl   +    H₂SO₄    ----------->K₂SO₄   + 2HCl

  0,05(mol)---->0,025(mol)

=>v_H2SO4=\(\frac{0,025}{1}\)=0,025(lít)

c)pH=-log(0,25)=0,602

(câu c mình không chắc chắn lắm nha bạn!!!)

câu a) làm sao vậy mn chỉ mik vs

Có gì đó sai sai

​

1,15 ở đâu v ạ

Câu 5:

\(Đặt:V_{H_2O}=a\left(l\right)\left(a>0\right)\\ n_{KOH}=160.2,4=384\left(mol\right)\\ Vì:C_{MddKOH\left(cuối\right)}=2\left(M\right)\\ \Leftrightarrow\dfrac{384}{160+a}=2\\ \Leftrightarrow a=32\left(lít\right)\)

Vậy cần thêm 32 lít H₂O

Câu 7:

\(m_{NaOH}=200.35\%=70\left(g\right)\)

Ta có:\(m_{ddNaOH\left(20\%\right)}=\dfrac{m_{NaOH\left(20\%\right)}.100}{20};m_{ddNaOH\left(40\%\right)}=\dfrac{m_{NaOH\left(40\%\right)}.100}{40}\)

  \(\Rightarrow m_{ddNaOH\left(20\%\right)}+_{ddNaOH\left(40\%\right)}=\dfrac{m_{NaOH\left(20\%\right)}.100}{20}+\dfrac{m_{NaOH\left(40\%\right)}.100}{40}\)

   \(\Leftrightarrow400=10m_{NaOH\left(20\%\right)}+5m_{NaOH\left(40\%\right)}\)

Ta có: \(\left\{{}\begin{matrix}m_{NaOH\left(20\%\right)}+m_{NaOH\left(40\%\right)}=70\\10m_{NaOH\left(20\%\right)}+5m_{NaOH\left(40\%\right)}=400\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}m_{NaOH\left(20\%\right)}=10\\m_{NaOH\left(40\%\right)}=60\end{matrix}\right.\)

\(\Rightarrow m_{ddNaOH\left(20\%\right)}=\dfrac{10.100}{20}=50\left(g\right);m_{ddNaOH\left(40\%\right)}=\dfrac{60.100}{40}=150\left(g\right)\)