a) \(n_{HCl}=0,1.2=0,2\left(mol\right)\)

PTHH: CuO + 2HCl --> CuCl₂ + H₂O

______0,1<---0,2------->0,1

=> a = 0,1.80 = 8(g)

b) \(C_{M\left(CuCl_2\right)}=\dfrac{0,1}{0,1}=1M\)

c) 

PTHH: CuCl₂ + 2NaOH --> Cu(OH)₂ + 2NaCl

______0,1------------------------>0,1

=> mCu(OH)₂ = 0,1.98 = 9,8(g)

a)

$n_{MgO} = \dfrac{8}{40} = 0,2(mol)$
$MgO + 2HCl \to MgCl_2 + H_2O$

$n_{HCl} = 2n_{MgO} = 0,4(mol) \Rightarrow V_{dd\ HCl} = \dfrac{0,4}{1} = 0,4(lít)$

b)

$n_{MgCl_2} = n_{MgO} = 0,2(mol) \Rightarrow C_{M_{MgCl_2}} = \dfrac{0,2}{0,4} = 0,5M$

c)

$MgCl_2 + 2NaOH \to Mg(OH)_2 + 2NaCl$
$n_{NaOH} = 2n_{MgCl_2} = 0,4(mol)$
$n_{Mg(OH)_2} = n_{MgCl_2} = 0,2(mol)$
Suy ra : 

$V = \dfrac{0,4}{1} = 0,4(lít)$
$m_{Mg(OH)_2} = 0,2.58 = 11,6(gam)$

\(n_{MgO}=\dfrac{8}{40}=0,2mol\)

\(MgO+2HCl\rightarrow MgCl_2+H_2O\)

 0,2         0,4          0,2         0,2

a)\(V_{HCl}=\dfrac{0,4}{1}=0,4\left(l\right)=400ml\)

c) \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)

     0,2              0,2

   \(\Rightarrow V_{NaOH}=\dfrac{0,2}{1}=0,2\left(l\right)=200ml\)

\(a.MgO+2HCl\rightarrow MgCl_2+H_2O\)

\(b.n_{MgO}=\dfrac{16}{40}=0,04mol\)

\(\rightarrow n_{HCl}=0,04.2=0,08mol\)

\(C_{M_{HCl}}=\dfrac{0,08}{0,15}=0,53M\)

\(c.m_{MgCl_2}=0,04.95=3,8g\)

Bài 1:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2\\ n_{Al}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ \Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\\ \%m_{Al}=\dfrac{5,4}{26,82}.100\approx20,134\%\\\Rightarrow \%m_{Al_2O_3}\approx79,866\%\\ b,n_{Al_2O_3}=\dfrac{26,82-5,4}{102}=0,21\left(mol\right)\\ n_{HCl}=6.0,21+2.0,3=1,86\left(mol\right)\\ V_{ddHCl}=\dfrac{1,86}{2}=0,93\left(l\right)=930\left(ml\right)\\ m_{ddHCl}=930.1,12=1041,6\left(g\right)\\ n_{AlCl_3}=2.0,21+0,2=0,62\left(mol\right)\\ C\%_{ddAlCl_3}=\dfrac{0,62.133,5}{1041,6-0,3.2}.100\approx7,951\%\)

2)

a) Gọi KL và oxit của nó là M và MO

n_HCl = 4.0,25 = 1 (mol)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: M + 2HCl --> MCl₂ + H₂

          0,3<-0,6<--------------0,3

            MO + 2HCl --> MCl₂ + H₂O

          0,2<---0,4

=> 0,3.M_M + 0,2.(M_M + 16) = 31,2

=> M_M = 56 (g/mol)

=> Kim loại là Sắt (Fe)

b) 

\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,3.56}{31,2}.100\%=53,85\%\\\%m_{FeO}=\dfrac{0,2.72}{31,2}.100\%=46,15\%\end{matrix}\right.\)

Bài 2:

Đặt A là kim loại cần tìm

\(a,A+2HCl\rightarrow ACl_2+H_2\left(1\right)\\ AO+2HCl\rightarrow ACl_2+H_2O\left(2\right)\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{HCl\left(ban.đầu\right)}=0,25.4=1\left(mol\right)\\ n_{HCl\left(1\right)}=2.n_{H_2}=0,6\left(mol\right)\\ n_{HCl\left(2\right)}=1-0,6=0,4\left(mol\right)\\ n_{AO}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ n_A=n_{H_2}=0,3\left(mol\right)\\ Vì:m_{hhđầu}=31,2\\ \Leftrightarrow m_A+m_{AO}=31,2\\ \Leftrightarrow0,3.M_A+0,2.\left(M_A+16\right)=31,2\\ \Leftrightarrow M_A=56\left(\dfrac{g}{mol}\right)\\ \Rightarrow A:Sắt\left(Fe=56\right)\\ b,\%m_{Fe}=\dfrac{0,3.56}{31,2}.100\approx53,846\%\\ \Rightarrow\%m_{FeO}\approx46,154\%\)

CuO + 2HCl -> CuCl₂ + H₂O (1)

Fe₂O₃ + 6HCl -> 2FeCl₃ + 3H₂O (2)

n_HCl=0,2.3,5=0,7(mol)

Đặt n_CuO=a

n_Fe2O3=b

Ta có hệ:

80a+160b=20

2a+6b=0,7

=>a=0,05;b=0,1

m_CuO=80.0,05=4(g)

m_Fe2O3=20-4=16(g)

Theo PTHH 1 và 2 ta có:

n_CuCl2=n_CuO=0,05(mol)

n_FeCl3=2n_Fe2O3=0,2(mol)

m_CuCl2=135.0,05=6,75(g)

m_FeCl3=162,5.0,2=32,5(g)

m_dd =20+200.1,1=240(g)

C% dd CuCl₂=6,72\240 .100%=2,8125%

C% dd FeCl₃= 32,5\240 .100%=13,54%

\(a.n_{Mg\left(OH\right)_2}=\dfrac{17,4}{58}=0,3\left(mol\right)\\ Mg\left(OH\right)_2+2HCl\rightarrow MgCl_2+2H_2O\\ n_{HCl}=2n_{Mg\left(OH\right)_2}=0,6\left(mol\right)\\ CM_{HCl}=\dfrac{0,6}{0,2}=3M\\b. n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,3\left(mol\right)\\ m_{MgCl_2}=0,3.85=25,5\left(g\right)\\c.CM_{MgCl_2}=\dfrac{0,3}{0,2}=1,5M \)