nAgNO₃ = 0,4 mol

nCaCl₂ = 0,45 mol

Pt: CaCl₂ + 2AgNO₃ --> 2AgCl + Ca(NO₃)₂

.....0,2<--------0,4--------> 0,4--------> 0,2

Xét tỉ lệ mol giữa CaCl₂ và AgNO₃:

\(\dfrac{0,45}{1}>\dfrac{0,4}{2}\)

Vậy CaCl₂ dư

mAgCl = 0,4 . 143,5 = 57,4 (g)

C_{M CaCl2 dư} = \(\dfrac{0,45-0,2}{0,5}=0,5\left(M\right)\)

C_{M Ca(NO3)2} = \(\dfrac{0,2}{0,5}=0,4\left(M\right)\)

\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)

\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)

\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)

\(0.1.............0.05...............0.05...........0.05\)

\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)

\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)

\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)

2NaOH + CuSO4 → Cu(OH)2 + Na2SO4

n NaOH = 0,2.5 = 1(mol)

n CuSO4 = 0,1.2 = 0,2(mol)

Ta có :

n NaOH / 2 = 0,5 > n CuSO4 / 1 = 0,2 => NaOH dư

n Cu(OH)2 = n CuSO4 = 0,2 mol

=> m A = 0,2.98 = 19,6 gam

n Na2SO4 = n CuSO4 = 0,2 mol

n NaOH pư = 2n CuSO4 = 0,4(mol)

V dd = 0,2 + 0,1 = 0,3(lít)

Suy ra:

CM Na2SO4 = 0,2/0,3 = 0,67M

CM NaOH = (1 - 0,4)/0,3 = 2M

\(n_{Ba\left(OH\right)_2}=0,5.0,2=0,1\left(mol\right);n_{H_2SO_4}=0,3.0,4=0,12\left(mol\right)\)

PTHH: Ba(OH)₂ + H₂SO₄ → BaSO₄↓ + 2H₂O

Mol:        0,1             0,1           0,1

Ta có: \(\dfrac{0,1}{1}< \dfrac{0,12}{1}\) ⇒ Ba(OH)₂ hết, H₂SO₄ dư

\(C_{M_{H_2SO_4dư}}=\dfrac{0,12-0,1}{0,2+0,3}=0,04M\)

m_{dd sau pứ} = 200.2,3+300.1,6-0,1.233 = 916,7 (g)

\(C\%_{H_2SO_4dư}=\dfrac{0,02.98.100\%}{916,7}=0,21\%\)

a/ \(n_{KOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,3.1=0,3\left(mol\right)\)

PTHH: 2KOH + H₂SO₄ → K₂SO₄ + 2H₂O

Mol:        0,2         0,1            0,1

Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ KOH hết, H₂SO₄ dư

b/ \(m_{H_2SO_4dư}=\left(0,3-0,1\right).98=19,6\left(g\right)\)

c/ V_{dd sau pứ} = 0,2 + 0,3 = 0,5 (l)

d/ \(C_{M_{ddK_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)

 \(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,5}=0,4M\)

\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)

PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)

            \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,2\cdot2=0,4\left(mol\right)\\n_{NaOH}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) \(\Rightarrow\) CuCl₂ còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,4\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}=n_{CuCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2\cdot80=16\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,2+0,2}=1\left(M\right)\\C_{M_{CuCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\\\end{matrix}\right.\)