nKOH = 0,7 . 1 = 0,7 (mol)

nSO2 = 6,72/22,4 = 0,3 (mol)

PTHH: 2KOH + SO2 -> K2SO3 + H2O

LTL: 0,7 > 0,3 => KOH dư

nK2SO3 = nKOH (p/ư) = 0,3 (mol)

nKOH (dư) = 0,7 - 0,3 = 0,4 (mol)

CMK2SO3 = 0,3/0,7 = 0,4285M

CMKOH = 0,4/0,7 = 0,5714M

a) nco2=v/22.4=0.1 mol

500ml=0.5l

=> nNaoh=Cm.v=0.2 . 0.5=0.1 mol

lập tỉ lệ:

nNaoh/nCo2=0.1/0.1=1

=> sảy ra phương trình

Naoh + co2 ->nahco3

mCo2=n.M=4.4 (g)

mNaoh=n.M=4 (g)

adđlbtkl ta có

mCo2 + mNaoh = mNahco3

=>mNahco3=8.4 (g)

\(n_{SO_2}=\dfrac{3}{14}\left(mol\right);n_{KOH}=0,3\left(mol\right)\)

Lập tỉ lệ : \(\dfrac{n_{KOH}}{n_{SO_2}}=\dfrac{0,3}{\dfrac{3}{14}}=1,4\)

=> Thu được 2 muối sau phản ứng

\(SO_2+KOH\rightarrow KHSO_3\)

\(SO_2+2KOH\rightarrow K_2SO_3+H_2O\)

Gọi x,y là số mol KHSO3, K2SO3

\(\left\{{}\begin{matrix}x+y=\dfrac{3}{14}\\x+2y=0,3\end{matrix}\right.\)

=> \(x=\dfrac{9}{70};y=\dfrac{3}{35}\)

=> \(m_{KHSO_3}=\dfrac{108}{7}\left(g\right);m_{K_2SO_3}=\dfrac{474}{35}\left(g\right)\)

b) \(V=\dfrac{84}{1,15}=\dfrac{1680}{23}\left(ml\right)=\dfrac{42}{575}\left(l\right)\)

=> \(CM_{KHSO_3}=\dfrac{\dfrac{9}{70}}{\dfrac{42}{575}}=1,76M\)

\(CM_{K_2SO_3}=\dfrac{\dfrac{3}{35}}{\dfrac{42}{575}}=1,17M\)

\(1,n_{SO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{KOH}=0,2.1=0,2\left(mol\right)\)

\(T=\dfrac{0,2}{0,2}=1\) => Tạo duy nhất muối axit

PTHHH: NaOH + SO₂ ---> NaHSO₃

                            0,2------>0,2

=> m_NaHSO3 = 0,2.104 = 20,8 (g)

\(2,n_{SO_2}=\dfrac{6,72}{22,4}=0,15\left(mol\right)\\ n_{KOH}=0,2.1=0,2\left(mol\right)\)

\(T=\dfrac{0,2}{0,15}=\dfrac{4}{3}\) => Tạo cả 2 muối

PTHH:

2KOH + SO₂ ---> K₂SO₃ + H₂O

0,2------>0,1------>0,1

K₂SO₃ + SO₂ + H₂O ---> 2KHSO₃

0,05<----0,01----------------->0,2

=> \(\left\{{}\begin{matrix}m_{K_2SO_3}=0,05.158=7,9\left(g\right)\\m_{KHSO_3}=0,2.120=24\left(g\right)\end{matrix}\right.\)

a. \(n_{CO_2}=0,02\left(mol\right);n_{Ca\left(OH\right)_2}=0,008\left(mol\right)\Rightarrow n_{OH^-}=0,016\\ Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,016}{0,02}=0,8\Rightarrow ChỉtạoCa\left(HCO_3\right)_2,CO_2dư\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2+H_2O\\ n_{Ca\left(HCO_3\right)_2}=n_{Ca\left(OH\right)_2}=0,016\left(mol\right)\\ \Rightarrow CM_{Ca\left(HCO_3\right)_2}=\dfrac{0,016}{0,4}=0,04M\)

\(b.n_{SO_2}=0,18\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow n_{OH^-}=0,4\left(mol\right)\\Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,4}{0,18}=2,22\Rightarrow Ba\left(OH\right) _2dư\\ SO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ n_{Ba\left(OH\right)_2dư}=0,2-0,18=0,02\left(mol\right)\\ \Rightarrow CM_{Ba\left(OH\right)_2dư}=\dfrac{0,02}{0,2}=0,1M\)

a) Chất rắn không tan là Cu

=> m Cu = 19,2(gam)

n Mg = a(mol) ; n Fe = b(mol)

=> 24a + 56b = 32,8 -19,2 = 13,6(1)

$Mg + H_2SO_4 \to MgSO_4 + H_2$
$Fe + H_2SO_4 \to FeSO_4 + H_2$
n H2 = a + b = 6,72/22,4 = 0,3(2)

Từ (1)(2) suy ra a = 0,1 ; b = 0,2

%m Cu = 19,2/32,8  .100% = 58,54%
%m Mg = 0,1.24/32,8   .100% = 7,32%
%m Fe = 100% -58,54% -7,32% = 34,14%

b)

m dd A = 32,8 + 200 - 0,3.2 = 232,2(gam)

n MgSO4 = a = 0,1(mol)

n FeSO4 = b = 0,2(mol)

C% MgSO4 = 0,1.120/232,2   .100% = 5,17%
C% FeSO4 = 0,2.152/232,2   .100% = 13,09%

a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)

\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)

Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)

b, Ta có: 126n_Na2SO3 + 158n_K2SO3 = 44,2 (1)

Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)

Có: m _{dd sau pư} = 44,2 + 147 - 0,3.64 = 172 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)

c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)

\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO₃.

PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)

\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)