a,Hiện tượng: Màu vàng nâu của dung dịch FeCl₃ nhạt dần và xuất hiện kết tủa nâu đỏ Fe(OH)₃.

\(m_{FeCl_3}=100.13\%=13\left(g\right)\Rightarrow n_{FeCl_3}=\dfrac{13}{162,5}=0,08\left(mol\right)\)

PTHH: 3NaOH + FeCl₃ → 3NaCl + Fe(OH)₃

Mol:       0,24        0,08         0,24       0,08

b, \(m=m_{ddNaOH}=\dfrac{0,24.40.100\%}{10\%}=96\left(g\right)\)

m_NaCl = 0,24.58,5 = 14,04 (g)

m_ddNaCl = 96 + 100 - 0,08.107 = 187,44 (g)

\(C\%_{ddNaCl}=\dfrac{14,04.100\%}{187,44}=7,49\%\)

a) 2NaOH + H₂SO₄ -- Na₂SO₄ + 2H₂O

b) \(n_{NaOH}=\dfrac{100.20}{100.40}=0,5\left(mol\right)\)

PTHH: 2NaOH + H₂SO₄ -- Na₂SO₄ + 2H₂O

______0,5----->0,25------>0,25

=> m_H2SO4 = 0,25.98 = 24,5 (g)

=> \(m_{ddH_2SO_4}=\dfrac{24,5.100}{19,6}=125\left(g\right)\)

c) m_Na2SO4 = 0,25.142 = 35,5 (g)

m_{dd sau pư} = 100 + 125 = 225 (g)

=> \(C\%\left(Na_2SO_4\right)=\dfrac{35,5}{225}.100\%=15,778\%\)

mNaOH=11(g) -> nNaOH= 0,275(mol)

mH3PO4=9,8(g) -> nH3PO4=0,1(mol)

Ta có: 2< nNaOH/nH3PO4 = 0,275/0,1=2,75< 3 

=> P.ứ kết thúc thu được hỗn hợp dd Na3PO4 và Na2HPO4

PTHH: 3 NaOH + H3PO4 -> Na3PO4 + 3 H2O

3x_____________x________x(mol)

2 NaOH + H3PO4 -> Na2HPO4 +2 H2O

2y_____y__________y(mol)

mddX=55+24,5=79,5(g)

\(\left\{{}\begin{matrix}3x+2y=0,275\\x+y=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,075\\y=0,025\end{matrix}\right.\)

=> mNa3PO4=0,075.164=12,3(g)

mNa2HPO4=142.0,025=3,55(g)

=>C%ddNa3PO4=(12,3/79,5).100=15,472%

C%ddNa2HPO4=(3,55/79,5).100=4,465%

Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=\dfrac{55\cdot20\%}{40}=0,275\left(mol\right)\\n_{H_3PO_4}=\dfrac{24,5\cdot40\%}{98}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo HPO₄^2- và PO₄^3-

PTHH: \(2NaOH+H_3PO_4\rightarrow Na_2HPO_4+2H_2O\)

                     2a_______a___________a_______2a   (mol)

           \(3NaOH+H_3PO_4\rightarrow Na_3PO_4+3H_2O\)

                     3b_______b_________b______3b    (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}2a+3b=0,275\\a+b=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,025\\b=0,075\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2HPO_4}=\dfrac{0,025\cdot142}{55+24,5}\cdot100\%\approx4,47\%\\C\%_{Na_3PO_4}=\dfrac{0,075\cdot164}{55+24,5}\cdot100\%\approx15,47\%\end{matrix}\right.\)

a)m dd sau=100gam
mNaCl không đổi=80.15%=12 gam
C% dd NaCl sau=12/100.100%=12%
b)mdd sau=200+300=500 gam
Tổng mNaCl sau khi trộn=200.20%+300.5%=55 gam
C% dd NaCl sau=55/500.100%=11%
c) mdd sau=150 gam
mNaOH trg dd 10%=5 gam
mNaOH trong dd sau khi trộn=150.7,5%=11,25 gam
=>mNaOH trong dd a%=11,25-5=6,25 gam
=>C%=a%=6,25/100.100%=6,25% => a=6,25

Ta có: \(m_{NaOH}=200.20\%=40\left(g\right)\Rightarrow n_{NaOH}=\dfrac{40}{40}=1\left(mol\right)\)

PT: \(NaOH+HCl\rightarrow NaCl+H_2O\)

a, Theo PT: \(n_{HCl}=n_{NaOH}=1\left(mol\right)\)

\(\Rightarrow C\%_{HCl}=\dfrac{0,1.36,5}{100}.100\%=36,5\%\)

b, \(n_{NaCl}=n_{NaOH}=1\left(mol\right)\)

Ta có: m _{dd sau pư} = 200 + 100 = 300 (g)

\(\Rightarrow C\%_{NaCl}=\dfrac{1.58,5}{300}.100\%=19,5\%\)

C là \(BaSO_4\), D là \(HCl\)

\(a,PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ n_{BaCl_2}=\dfrac{31,2}{208}=0,15\left(mol\right)\\ \Rightarrow n_{BaSO_4}=0,15\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,15\cdot233=34,95\left(g\right)\\ b,n_{HCl}=2n_{BaCl_2}=0,3\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,3\cdot36,5=10,95\left(g\right)\\ m_{dd_{HCl}}=31,2+100-34,95=96,25\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{10,95}{96,25}\cdot100\%\approx11,38\%\)

Bài 9:

\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ n_{HCl}=\dfrac{14,6\%.100}{36,5}=0,4\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,1}{1}< \dfrac{0,4}{2}\Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,4-2.0,1=0,2\left(mol\right)\\ m_{HCl\left(dư\right)}=0,2.36,5=7,3\left(g\right)\)

Bài 10:

\(n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ PTHH:CaO+H_2O\rightarrow Ca\left(OH\right)_2\\ n_{Ca\left(OH\right)_2}=n_{CaO}=0,1\left(mol\right)\\ m_{Ca\left(OH\right)_2}=0,1.74=7,4\left(g\right)\\ m_{ddCa\left(OH\right)_2}=m_{CaO}+m_{H_2O}=5,6+500.1=505,6\left(g\right)\\ a,C\%_{ddCa\left(OH\right)_2}=\dfrac{7,4}{505,6}.100\approx1,464\%\\ b,V_{ddCa\left(OH\right)_2}=V_{H_2O}=500\left(ml\right)=0,5\left(l\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

Ta có: \(C_{\%_{NaOH}}=\dfrac{m_{NaOH}}{44}.100\%=10\%\)

=> m_NaOH = 4,4(g)

=> \(n_{NaOH}=\dfrac{4,4}{40}=0,11\left(mol\right)\)

Ta lại có: \(C_{\%_{H_3PO_4}}=\dfrac{m_{H_3PO_4}}{10}.100\%=39,2\%\)

=> \(m_{H_3PO_4}=3,92\left(g\right)\)

=> \(n_{H_3PO_4}=\dfrac{3,92}{98}=0,04\left(mol\right)\)

PTHH: 3NaOH + H₃PO₄ ---> Na₃PO₄ + 3H₂O

Ta thấy: \(\dfrac{0,11}{3}< \dfrac{0,04}{1}\)

Vậy H₃PO₄ dư.

Theo PT: \(n_{Na_3PO_4}=\dfrac{1}{3}.n_{NaOH}=\dfrac{1}{3}.0,11=\dfrac{11}{300}\left(mol\right)\)

=> \(m_{Na_3PO_4}=\dfrac{11}{300}.164=6,01\left(3\right)\left(g\right)\)

Ta có; \(m_{dd_{Na_3PO_4}}=44+10=54\left(g\right)\)

=> \(C_{\%_{Na_3PO_4}}=\dfrac{6,01\left(3\right)}{54}.100\%=11,14\%\)