PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)

\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)

a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)

\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)

b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)

\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)

\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)

\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)

Vậy Fe dư

Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)

\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)

a) Chất tham gia: Sắt (Fe), Oxi (O₂)

Sản phẩm: Sắt từ (Fe₃O₄)

b) Theo ĐLBTKL

 \(m_{Fe}+m_{O_2}=m_{Fe_3O_4}\) (1)

c) \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\); \(n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2\left(mol\right)\)

PTHH: 3Fe + 2O₂ --t^o--> Fe₃O₄

______0,2----------------->\(\dfrac{0,2}{3}\) ________(mol)

=> vô lí ...

a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

b, \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)

\(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,2}{4}< \dfrac{0,4}{5}\), ta được O₂ dư.

Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\Rightarrow n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)

\(\Rightarrow m_{O_2\left(dư\right)}=0,15.32=4,8\left(g\right)\)

c, Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)

d, \(m_{P_2O_5}=14,2.80\%=11,36\left(g\right)\)

Giúp mik vs T-T

n_Fe = 16.8/56 = 0.3 (mol) 

3Fe + 2O₂ -to-> Fe₃O₄ 

0.3......0.2...........0.1

VO2 = 0.2*22.4 = 4.48 (l) 

mFe3O4 = 0.1*232 = 23.2 (g) 

\(a,m_C=48\left(g\right)\rightarrow n_C=\dfrac{m_C}{M_C}=\dfrac{48}{12}=4\left(mol\right)\)

\(V_{O_2}=44,8\left(l\right)\rightarrow n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{44,8}{22,4}=2\left(mol\right)\)

\(PTHH:C+O_2\underrightarrow{t^o}CO_2\)

\(pt:\)      \(1mol\)  \(1mol\)

\(đb:\)      \(4mol\)  \(2mol\)

Xét tỉ lệ:

\(\dfrac{n_{C\left(đb\right)}}{n_{C\left(pt\right)}}=\dfrac{4}{1}=4>\dfrac{n_{O_2\left(đb\right)}}{n_{O_2\left(pt\right)}}=\dfrac{2}{1}=2\)

\(\Rightarrow\) \(O_2\) hết, \(C\) dư.

\(b,PTHH:C+O_2\underrightarrow{t^o}CO_2\)

\(pt:\)                  \(1mol\)   \(1mol\)

\(đb:\)                  \(2mol\)   \(2mol\)

\(\Rightarrow m_{CO_2}=n_{CO_2}.M_{CO_2}=2.\left(1.C+2.O\right)=2.\left(1.12+2.16\right)=88\left(g\right)\)

\(a.n_C=\dfrac{48}{12}=4\left(mol\right);n_{O_2}=\dfrac{44,8}{22,4}=2\left(mol\right)\\ C+O_2\xrightarrow[t^0]{}CO_2\)

Theo pt:\(\dfrac{4}{1}>\dfrac{2}{1}\Rightarrow C\) dư, O₂ pư hết

\(b.C+O_2\xrightarrow[t^0]{}CO_2\\ \Rightarrow n_{CO_2}=n_{O_2}=2mol\\ m_{CO_2}=2.44=88\left(g\right)\)

\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)

\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)

\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)

\(4........5\)

\(0.2.........0.4\)

Lập tỉ lệ : \(\dfrac{0.2}{4}< \dfrac{0.4}{5}\Rightarrow O_2dư\)

\(n_{P_2O_5}=0.2\cdot\dfrac{2}{4}=0.1\left(mol\right)\)

\(m_{P_2O_5}=0.1\cdot142=14.2\left(g\right)\)

\(m_{P_2O_5\left(tt\right)}=14.2\cdot80\%=11.36\left(g\right)\)

Bài 1 : 

a. \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)

\(n_{O_2}=\dfrac{16}{32}=0,5\left(mol\right)\)

b. PTHH : 4Al + 3O₂ -t^o> 2Al₂O₃

                 0,4       0,3       0,2

Xét tỉ lệ : \(\dfrac{0,4}{4}< \dfrac{0,5}{3}\) => Al đủ , O₂ dư

\(m_{O_2\left(dư\right)}=\left(0,5-0,3\right).32=6,4\left(g\right)\)

c. \(m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)

Bài 2:

C9:

nP = 6,2/31 = 0,2 (mol)

nO2 = 6,4/32 = 0,2 (mol)

PTHH: 4P + 5O2 -> (t°) 2P2O5

LTL: 0,2/4 > 0,2/5 => P dư

nP (p/ư) = 0,2/5 . 4 = 0,16 (mol)

nP (dư) = 0,2 - 0,16 = 0,04 (mol)

nP2O5 = 0,2/5 . 2 = 0,08 (mol)

mP2O5 = 0,08 . 142 = 11,36 (g)

C10: 

Áp dụng ĐLBTKL, ta có:

mR + mO2 = mRO

=> mO2 = 21,6 - 16,8 = 4,8 (g(

=> nO2 = 4,8/32 = 0,15 (mol)

PTHH: 2R + O2 -> (t°) 2RO

nR = 0,15 . 2 = 0,3 (mol)

M(R) = 16,8/0,3 = 56 (g/mol(

=> R là Fe

PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,3}{3}< \dfrac{0,3}{2}\) , ta được O₂ dư.

Mà: H% = 80% \(\Rightarrow n_{Fe\left(pư\right)}=0,3.80\%=0,24\left(mol\right)\)

\(\Rightarrow n_{Fe\left(dư\right)}=0,3.0,24=0,06\left(mol\right)\)

Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\)

Chất rắn thu được gồm Fe dư và Fe₃O₄.

⇒ m_cr = m_{Fe (dư)} + m_Fe3O4 = 0,06.56 + 0,1.232 = 26,56 (g)

Bạn tham khảo nhé!