n_Fe = 11.2/56 = 0.2 (mol) 

Fe + H2SO4 => FeSO4 + H2 

0.2____0.2_______0.2___0.2 

mH2SO4 = 0.2*98 = 19.6 (g) 

mdd H2SO4 = 19.6*100/10 = 196 (g) 

m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g) 

mFeSO4 = 0.2*152 = 30.4 (g) 

C% FeSO4 = 30.4/206.8 * 100% = 14.7% 

Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml) 

CM FeSO4 = 0.2 / 0.1719 = 1.16 M 

n_Fe = 11.2/56 = 0.2 (mol) 

Fe + H2SO4 => FeSO4 + H2 

0.2____0.2_______0.2___0.2 

mH2SO4 = 0.2*98 = 19.6 (g) 

mdd H2SO4 = 19.6*100/10 = 196 (g) 

m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g) 

mFeSO4 = 0.2*152 = 30.4 (g) 

C% FeSO4 = 30.4/206.8 * 100% = 14.7% 

Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml) 

CM FeSO4 = 0.2 / 0.1719 = 1.16 M 

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

              a_______a_______a_____a    (mol)

            \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

                2b______3b__________b_____3b    (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27\cdot2b=11\\a+3b=0,2\cdot2=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{11}\cdot100\%\approx50,91\%\\\%m_{Al}=49,09\%\end{matrix}\right.\)

Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{FeSO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\) 

a) nH2SO4=0,4(mol)

Đặt: nFe=x(mol); nAl=y(mol) (x,y>0)

PTHH: Fe + H2SO4 -> FeSO4 + H2

x________x______x______x(mol)

2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2

y____1,5y_______0,5y_______1,5y(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=> mFe=0,1.56=5,6(g)

=>%mFe=(5,6/11).100=50,909%

=>%mAl= 49,091%

b) V(H2,đktc)=0,4.22,4=8,96(l)

c) nAl2(SO4)3= 0,5y=0,5.0,2=0,1(mol)

nFeSO4=x=0,1(mol)

Vddsau=VddH2SO4=0,2(l)

=>CMddAl2(SO4)3= 0,1/0,2=0,5(M)

CMddFeSO4=0,1/0,2=0,5(M)

a)

$Fe + H_2SO_4 \to FeSO_4 + H_2$

b) $n_{Fe} = \dfrac{14}{56} = 0,25(mol)$
Theo PTHH : $n_{H_2SO_4} = n_{Fe} =  0,25(mol)$

$\Rightarrow m_{dd\ H_2SO_4} = \dfrac{0,25.98}{10\%} = 245(gam)$

c)

$n_{H_2} = n_{Fe} = 0,25(mol)$

Sau phản ứng, $m_{dd} = 14 + 245 - 0,25.2 = 258,5(gam)$

$C\%_{FeSO_4} = \dfrac{0,25.152}{258,5}.100\% = 14,7\%$

\(n_{H_2SO_4}=0,2.2=0,4\left(mol\right)\)

Fe + H2SO4 → FeSO4 + H2 

2Al + 3H2SO4 → Al2(SO4)3 + 3H2

Gọi x,y lần lượt là số mol Fe, Al

\(\left\{{}\begin{matrix}56x+27y=11\\x+\dfrac{3}{2}y=0,4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=>\(\%m_{Fe}=\dfrac{0,1.56}{11}.100=50,91\%\)

=> %m _Al = 100 - 50,91 =49,09 %

b)Theo PT:  \(n_{H_2}=n_{H_2SO_4}=0,4\left(mol\right)\)

=> \(V_{H_2}=0,4.22,4=8,96\left(l\right)\)

c) \(CM_{FeSO_4}=\dfrac{0,1}{0,2}=0,5M\)

\(CM_{Al_2\left(SO_4\right)_3}=\dfrac{\dfrac{0,2}{2}}{0,2}=0,5M\)

Đáp án:

m =32,4g

mddH2SO4 = 49g

Giải thích các bước giải:

a) MgCO3 + H2SO4 → MgSO4 + H2O +CO2 ↑

MgSO4 + 2NaOH → Mg(OH)2 + Na2SO4

$Mg{(OH)_2}\buildrel {to} \over

\longrightarrow MgO + {H_2}O$

b) nCO2 = 2,24 : 22,4 = 0,1mol

nMgCO3 = nCO2 = 0,1 mol

nMgO = 12:40=0,3mol

nMgSO4 = nMgO - nMgCO3 = 0,3 - 0,1 = 0,2mol

m = mMgCO3 + mMgSO4

= 0,1 .84+0,2.120=32,4g

nH2SO4 = nCO2 = 0,1 mol

mH2SO4 = 0,1.98=9,8g

mddH2SO4 = 9,8:20.100=49g

chúc bạn học tốt

a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

Theo PT: \(n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeSO_4}=0,2.152=30,4\left(g\right)\)

c, \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)

d, \(n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,2}{0,2}=1\left(M\right)\)

a)\(PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(n_{H_2}=\frac{2,688}{22,4}=0,12\left(mol\right)\)

\(n_{SO^{ }_4}=\frac{1}{2}n_{H_2}=0,06\left(mol\right)\)

\(m_{muối}=m_{KL}+m_{SO_4}=6,44+0,06.96=12,2\left(g\right)\)

b) \(n_{H_2SO_4}=n_{H_2}=0,12\left(mol\right)\)

\(m_{ddH_2SO_4}=\frac{0,12.98}{9,8\%}=120\left(g\right)\)

\(PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(PTHH:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(n_{H_2}=\frac{2,688}{22,4}=0,12\left(mol\right)\)

Bảo toàn H: \(\Rightarrow n_{H_2SO_4}=0,12\left(mol\right)\)

Áp dụng ĐLBTKL ta có:

\(m_{hh}+m_{axit}=m_{dd}+m_{H_2}\)

\(\Rightarrow m_{dd}=m_{hh}+m_{axit}-m_{H_2}=6,44+98.0,12-0,12.2=17,96\left(g\right)\)

\(m_{ddaxxit}=\frac{98.0,12.100}{9,8}=120\left(g\right)\)

\(PTHH:2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

\(PTHH:2NaOH+MgSO_4\rightarrow Na_2SO_4+Mg\left(OH\right)_2\downarrow\)

\(PTHH:2NaOH+ZnSO_4\rightarrow Na_2SO_4+Zn\left(OH\right)_2\downarrow\)

1/Bt(e); 3*nFe pư HNO3 = 3*nNO 
- > nFe(3+) = 0,12 mol.
Fe +--- 2Fe(3+) -> 3Fe(2+)
0,03------0,06 mol.
nFe(3+) sau pư = 0,12 – 0,06 = 0,06 mol

2/nFeSO4 = 0,1 mol
BTE => 0,1 = 2x
=> nCl2 = 0,05 mol
m(muối) = mFeSO4 + mCl2 = 0,1.152 + 0,05.71 = 18,75 gam