Mg+2HCl->MgCl2+H2

a..............................a(mol)

Fe+2HCl->FeCl2+H2

b............................b(mol)

=>nCu=3,2/64=0,05mol

=>%mCu=(3,2.100%)/11,2=28,6%

\(=>\left\{{}\begin{matrix}24a+56b=11,2-3,2\\a+b=0,2\end{matrix}\right.=>\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

=>mMg=24.0,1=2,4g=>%Mg=(2,4.100%)/11,2=21,4%

=>%Fe=100%-21,4%-28,6%=50%

b, MgCl2+2NaOH->Mg(OH)2+2NaCL

FeCl2+2NaOH->Fe(OH)2+2NaCl

=>m(kết tủa)=mMg(OH)2+mFe(OH)2

=0,1(58+90)=14,8g

a) mCu= m(k tan)= 3,2(g)

=> m(Mg, Fe)= 11,2- 3,2=8(g)

nH2= 4,48/22,4=0,2(mol)

PTHH: Mg + 2 HCl -> MgCl2 + H2

a______________2a__a______a(mol)

Fe + 2 HCl -> FeCl2 + H2

b____2b_____b_____b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24a+56b=8\\a+b=0,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}m_{Mg}=24.0,1=2,4\left(g\right)\\m_{Fe}=56.0,1=5,6\left(g\right)\end{matrix}\right.\)

=> %mMg= (2,4/11,2).100=21,429%

%mFe= (5,6/11,2).100=50%

=>%mCu= (3,2/11,2).100=28,571%

b/ MgCl2 + 2 NaOH -> Mg(OH)2 + 2 NaCl

0,1___________________0,1(mol)

FeCl2 + 2 NaOH -> Fe(OH)2 +2 NaCl

0,1__________________0,1(mol)

m(kt)=mMg(OH)2 + mFe(OH)2= 58.0,1+ 90.0,1= 14,8(g)

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

            \(MgO+2HCl\rightarrow MgCl_2+H_2O\)

a) Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)=n_{Mg}\)

\(\Rightarrow\%m_{Mg}=\dfrac{0,5\cdot24}{16}=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)

b) Ta có: \(\left\{{}\begin{matrix}n_{Mg}=0,5\left(mol\right)\\n_{MgO}=\dfrac{16\cdot25\%}{40}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl}=2n_{Mg}+2n_{MgO}=1,2\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{1,2\cdot36,5}{20\%}=219\left(g\right)\)

c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,5\left(mol\right)\\n_{MgCl_2}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{H_2}=0,5\cdot2=1\left(g\right)\\m_{MgCl_2}=0,6\cdot95=57\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{hhA}+m_{ddHCl}-m_{H_2}=234\left(g\right)\) \(\Rightarrow C\%_{MgCl_2}=\dfrac{57}{234}\cdot100\%\approx24,36\%\)

Bài 1 :

PTHH : Zn + H₂SO₄ ------> ZnSO₄ + H₂

\(n_{Zn}=\frac{m}{M}=\frac{26}{65}=0,4\left(mol\right)\)

Theo PTHH : n_H2 = n_Zn = 0,4 mol

=> Khối lượng H₂ được tạo ra ở đktc là :

\(V=n\times22,4\)

\(\Rightarrow V_{H_2}=0,4\times22,4\)

\(\Rightarrow V_{H_2}=8,96\left(l\right)\)

Theo PTHH : n_ZnSO4 = n_Zn = 0,4 mol

=> Khối lượng muối được tạo thành là :

\(m=n\times M\)

\(\Rightarrow m_{ZnSO_4}=0,4\times161\)

\(\Rightarrow m_{ZnSO_4}=64,4\left(g\right)\)

b) Theo PT : \(n_{H_2SO_4}=n_{Zn}=0,4\left(mol\right)\)

=> Khối lượng \(H_2SO_4\)cần dùng cho phản ứng là :

\(m=n\times M\)

\(\Rightarrow m_{H_2SO_4}=0,4\times98\)

\(\Rightarrow m_{H_2SO_4}=39,2\left(g\right)\)

c) Nồng độ phần trăm thu được sau phản ứng là :

\(C\%=\frac{m_{ct}}{m_{dd}}\times100\%\)

\(\Rightarrow C\%=\frac{39,2}{64,4}\times100\%\approx60,9\%\)

Vậy :.........................

a) Gọi $n_{Al} = a(mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 33,4(1)$

$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH : $n_{H_2} = 1,5a + b = \dfrac{17,92}{22,4} = 0,8(2)$

Từ (1)(2) suy ra : a = 0,2 ; b = 0,5

$\%m_{Al} = \dfrac{0,2.27}{33,4}.100\% = 16,17\%$
$\%m_{Fe} = 100\% - 16,17\% = 83,83\%$

b) $n_{HCl} = 2n_{H_2} = 1,6(mol)$

c) $m_{muối} = m_{hh} + m_{HCl} - m_{H_2} = 33,4 + 1,6.36,5 - 0,8.2 = 90,2(gam)$