\(a)Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ b)Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\\ Tacó:\left\{{}\begin{matrix}65x+56y=12,1\\x+y=0,2\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\\ \Rightarrow m_{Fe}=0,1.56=5,6\left(g\right);m_{Zn}=0,1.65=6,5\left(g\right)\\ c)n_{H_2SO_4}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow C\%_{H_2SO_{\text{ 4}}}=\dfrac{0,2.98}{196}.100=10\%\)

\(a) Mg + H_2SO_4 \to MgSO_4 + H_2\\ n_{Mg} = n_{H_2} = \dfrac{1,12}{22,4} =0,05(mol)\\ m_{Mg} = 0,05.24 =1,2(gam)\\ m_{Cu} = 7,6 -1,2 = 6,4(gam)\\ b) n_{H_2SO_4} = n_{H_2} = 0,05(mol) \Rightarrow V_{dd\ H_2SO_4} = \dfrac{0,05}{0,5} =0,1(lít)\\ c) n_{MgSO_4} = n_{H_2} = 0,05(mol) \Rightarrow m_{MgSO_4} = 0,05.120 = 6(gam)\\ d) \text{Bảo toàn electron: } 2n_{Mg} + 2n_{Cu} = 2n_{SO_2}\\ \Rightarrow n_{SO_2} = 0,05 + \dfrac{6,4}{64} = 0,15(mol) \Rightarrow V_{SO_2} = 0,15.22,4 = 3,36(lít)\)

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)

a) Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)=n_{Fe}\)

\(\Rightarrow m_{Fe}=0,25\cdot56=14\left(g\right)\) \(\Rightarrow m_{Cu}=6\left(g\right)\)

b) Theo PTHH: \(n_{FeSO_4}=0,25mol\) \(\Rightarrow m_{FeSO_4}=0,25\cdot152=38\left(g\right)\)

Mặt khác: \(\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,25\cdot98}{10\%}=245\left(g\right)\\m_{H_2}=0,25\cdot2=0,5\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{dd}=m_{hh}+m_{H_2SO_4}-m_{Cu}-m_{H_2}=258,5\left(g\right)\)

\(\Rightarrow C\%_{FeSO_4}=\dfrac{38}{258,5}\cdot100\%\approx14,7\%\)

pthh : Fe +H₂SO₄ → FeSO₄ +H₂

theo bài ra số mol của h2 =0,15 (mol)

theo pt : nFe=nH₂=0,15 (mol)

mFe=0,15 .56 =8,4 (g) ⇒mCu=20-8,4=11,6 (g)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl ---> ZnCl₂ + H₂

           0,2<--0,4<------0,2<-----0,2

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,2.65}{21,1}.100\%=61,61\%\\\%m_{ZnO}=100\%-61,61\%=38,39\%\end{matrix}\right.\)

\(n_{ZnO}=\dfrac{21,1-0,2.65}{81}=0,1\left(mol\right)\)

PTHH: ZnO + 2HCl ---> ZnCl₂ + H₂O

            0,1---->0,2------>0,1

=> \(C\%_{HCl}=\dfrac{\left(0,2+0,4\right).36,5}{200}.100\%=10,95\%\)

\(m_{mu\text{ố}i}=m_{ZnCl_2}=\left(0,1+0,2\right).136=40,8\left(g\right)\)

a/ \(n_{CO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\)

\(0,5---0,5----0,5---0,5-0,5\)

\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

\(b---b----b-----b\)

\(\Rightarrow m_{MgCO_3}=0,5.\left(24+12+16.3\right)=42\left(g\right)\)

\(\dfrac{m_{MgCO_3}}{m_{MgO}}=\dfrac{7}{3}\Rightarrow m_{MgO}=42.\dfrac{3}{7}=18\left(g\right)\Rightarrow n_{MgO}=b=0,45\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4}=0,45+0,5=0,95\left(mol\right)\) \(\Rightarrow m_{dd}=\dfrac{0,95.98}{0,05}=1862\left(g\right)\)

\(A.Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ B.n_{H_2}=\dfrac{1,12}{22,4}=0,05mol\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

0,05      0,05           0,05           0,05

\(\%m_{Mg}=\dfrac{0,05.24}{6,4}\cdot100=18,75\%\\ \%m_{Cu}=100-18,75=81,25\%\\ C.m_{ddH_2SO_4}=\dfrac{0,05.98}{20}\cdot100=24,5g\)

a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)

Theo Pt : \(n_{Mg}=n_{H2SO4}=n_{MgSO4}=n_{H2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

b)  \(\%m_{Mg}=\dfrac{0,05.24}{6,4}.100\%=18,75\%\)

\(\%m_{Cu}=100\%-18,75\%=81,25\%\)

c) \(m_{H2SO4}=0,05.98=4,9\left(g\right)\)

\(\Rightarrow m_{ddH2SO4}=\dfrac{4.100\%}{20\%}=20\left(g\right)\)

 Chúc bạn học tốt

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,3\left(mol\right)=n_{ZnCl_2}\\n_{HCl}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0.3\cdot65}{35,5}\cdot100\%\approx54,93\%\\\%m_{Cu}=45,07\%\\C\%_{HCl}=\dfrac{0,6\cdot36,5}{500}\cdot100\%=4,38\%\\m_{ZnCl_2}=0,3\cdot136=40,8\left(g\right)\end{matrix}\right.\)

Mặt khác: \(\left\{{}\begin{matrix}m_{Cu}=35,5-0,3\cdot65=16\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{dd}=m_{KL}+m_{ddHCl}-m_{Cu}-m_{H_2}=518,9\left(g\right)\)

\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{518,9}\cdot100\%\approx7,86\%\)

a. PTHH:

2Al + 3H₂SO₄ ---> Al₂(SO₄)₃ + 3H₂

Cu + H₂SO₄ ---x--->

b. Theo PT: \(n_{Al}=\dfrac{2}{3}.n_{H_2}=\dfrac{2}{3}.\dfrac{6,72}{22,4}=0,2\left(mol\right)\)

=> \(m_{Al}=0,2.27=5,4\left(g\right)\)

=> \(m_{Cu}=10-5,4=4,6\left(g\right)\)

c. \(\%_{m_{Al}}=\dfrac{5,4}{10}.100\%=54\%\)

\(\%_{m_{Cu}}=100\%-54\%=46\%\)

d. Theo PT: \(n_{H_2SO_4}=n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

=> \(m_{H_2SO_4}=0,3.98=29,4\left(g\right)\)

Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{29,4}{m_{dd_{H_2SO_4}}}.100\%=20\%\)

=> \(m_{dd_{H_2SO_4}}=147\left(g\right)\)