\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)

\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)

1/ nNaCl=5,85/58,5=0,1 mol. 
nAgNO3=34/170=0,2 mol. 
PTPU: NaCl+AgNO3=>AgCl+NaNO3 
vì NaCl và AgNO3 phan ung theo ti le 1:1 (nAgNO3 p.u=nNaCl=0,1 mol) 
=>AgNO3 du 
nAgNO3 du= 0,2-0,1=0,1 mol. 
Ta tinh luong san pham theo chat p.u het la NaCl 
sau p.u co: AgNO3 du:0,1 mol; AgCl ket tua va NaCl: nAgCl=nNaNO3=nNaCl=0,1 mol.V(dd)=300+200=500ml=0,5 ()l 
=>khoi lg ket tua: mAgCl=0,1.143,5=14,35 g 
C(M)AgNO3=C(M)NaNO3=n/V=0,1/0,5=0,2 M

a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)

Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=2n_{Fe}=0,5\left(mol\right)\\n_{H_2}=n_{Fe}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)

\(a=C_{M_{HCl}}=\dfrac{0,5}{0,1}=5\left(M\right)\)

b, Theo PT: \(n_{FeCl_2}=n_{Fe}=0,25\left(mol\right)\)

Ta có: \(n_{AgNO_3}=0,4.1,3=0,52\left(mol\right)\)

PT: \(2AgNO_3+FeCl_2\rightarrow Fe\left(NO_3\right)_2+2AgCl_{\downarrow}\)

______0,5______0,25______0,25________0,5 (mol)

\(AgNO_3+Fe\left(NO_3\right)_2\rightarrow Fe\left(NO_3\right)_3+Ag_{\downarrow}\)

0,02______0,02________0,02________0,02 (mol)

⇒ m = m_AgCl + m_Ag = 0,5.143,5 + 0,02.108 = 73,91 (g)

- Dd sau pư gồm: Fe(NO₃)₃: 0,02 (mol) và Fe(NO₃)₂: 0,25 - 0,02 = 0,23 (mol)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Fe\left(NO_3\right)_3}}=\dfrac{0,02}{0,1+0,4}=0,04\left(M\right)\\C_{M_{Fe\left(NO_3\right)_2}}=\dfrac{0,23}{0,1+0,4}=0,46\left(M\right)\end{matrix}\right.\)

\(Fe+2HCl->FeCl_2+H_2\\ a.V=\dfrac{14}{56}\cdot22,4=5,6\left(L\right)\\ a=\dfrac{\dfrac{14}{56}\cdot2}{0,1}=5\left(M\right)\\ b.n_{AgNO_3}=0,4\cdot1,3=0,52mol\\ FeCl_2+AgNO_3->Fe\left(NO_3\right)_2+AgCl\\ Fe\left(NO_3\right)_2+AgNO_3->Ag+Fe\left(NO_3\right)_3\\ m=0,25\cdot143,5+0,25\cdot108=62,875\left(g\right)\\ C_{M\left(AgNO_3\right)}=\dfrac{0,02}{0,5}=0,04M\\ C_{M\left(Fe\left(NO_3\right)_3\right)}=\dfrac{0,25}{0,5}=0,5M\)

Em tham khảo nhé !!

Bảo toàn khối lượng

\(m_{O_2}=m_{Oxit}-m_{KL}=48,84-34,44=14,4g\)

\(\rightarrow n_{O_2}=\frac{14,4}{32}=0,45mol\)

BTNT (O) \(n_{H_2O}=2n_{O_2}=0,9mol\)

\(n_{H_2}=\frac{4,032}{22,4}=0,18mol\)

BTNT (H)  \(n_{HCl}=2n_{H_2O}+2n_{H_2}=2,16mol\)

\(\rightarrow m_{HCl}=2,16.36,5=78,84g\)

\(m_{H_2}=0,18.2=0,36g\) và \(m_{H_2O}=0,9.18=16,2g\)

Bảo toàn khối lượng \(m_A+m_{HCl}=m_{\text{muối}}+m_{H_2O}+m_{H_2}\)

\(\rightarrow m_{\text{muối}}=48,84+78,84-0,36-16,2=111,12g\)

câu này dễ mà bn

Có đăng nhầm chỗ ko vậy bn???

CHÚC BẠN HỌC TỐT!!

Theo đề bài, ta có: \(\left\{{}\begin{matrix}n_{CO2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\\n_{CaCl2}=\dfrac{66,6}{111}=0,6\left(mol\right)\end{matrix}\right.\)

PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)

pư............0,45............0,9............0,45..........0,45........0,45 (mol)

\(\Rightarrow n_{CaCl2\left(còn\right)}=0,6-0,45=0,15\left(mol\right)\)

PTHH: \(CaO+2HCl\rightarrow CaCl_2+H_2\)

pư..........0,15.........0,3...........0,15.........0,15 (mol)

a) % khối lượng mỗi chất trong A

\(m_{hhA}=m_{CaO}+m_{CaCO3}=56.0,15+100.0,45=53,4\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%CaO=\dfrac{56.0,15}{53,4}.100\%\approx15,73\%\\\%CaCO_3\approx84,27\%\end{matrix}\right.\)

b) \(\Rightarrow m_{ddHCl7,3\%}=\dfrac{36,5.\left(0,9+0,3\right)}{7,3\%}=600\left(g\right)\)

\(\Rightarrow V_{ddHCl7,3\%}=\dfrac{600}{1,1}\approx545,45\left(ml\right)\)

c) Ta có: \(m_{dds}=m_{hh}+m_{ddHCl}-m_{CO2}=53,4+600-44.0,45=633,6\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%CaCl_{2\left(I\right)}=\dfrac{111.0,15}{633,6}.100\%\approx2,63\%\\\%CaCl_{2\left(II\right)}=\dfrac{111.0,45}{633,6}.100\%\approx7,9\%\end{matrix}\right.\)

\(a,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl ---> ZnCl₂ + H₂

          0,2-->0,4--------->0,2--->0,2

=> V = 0,2.22,4 = 4,48 (l)

b, Thiếu V dd

\(c,m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)