a, PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{14,8}.100\%\approx72,97\%\\\%m_{MgO}\approx27,03\%\end{matrix}\right.\)

b, Ta có: \(n_{MgO}=\dfrac{14,8-0,4.27}{40}=0,1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{H_2}+n_{MgO}=0,7\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,7.98=68,6\left(g\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{68,6}{10\%}=686\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\\n_{MgSO_4}=n_{MgO}=0,1\left(mol\right)\end{matrix}\right.\)

Ta có: m _{dd sau pư} = 14,8 + 686 - 0,6.2 = 699,6 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,2.342}{699,6}.100\%\approx9,78\%\\C\%_{MgSO_4}=\dfrac{0,1.120}{699,6}.100\%\approx1,72\%\end{matrix}\right.\)

1. Gọi mol của Mg và Al là x, y mol

=> 24x + 27y = 12,6 (1)

nH2 = 0,6 mol => x + 1,5y = 0,6 (2)

Từ (1) (2) => x = 0,3 ; y = 0,2 

=> %Mg = 57,14%

=> %Al = 42,86%

nH2=13,44/22,4=0,6(mol)

Đặt: nMg=a(mol); nAl=b(mol) (a,b>0)

1) PTHH: Mg + H2SO4 -> MgSO4 + H2

a__________a________a_____a(mol)

2Al +3 H2SO4 -> Al2(SO4)3 + 3 H2

b___1,5b______0,5b____1,5b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24a+27b=12,6\\a+1,5b=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,3\\b=0,2\end{matrix}\right.\)

=> mMg=0,3.24=7,2(g)

=>%mMg= (7,2/12,6).100=57,143%

=>%mAl=42,857%

2) mMgSO4=120.a=120.0,3=36(g)

mAl2(SO4)3=342.0,5b=342.0,5.0,2= 34,2(g)

mH2SO4= (0,3+0,2.1,5).98=58,8(g)

=>mddH2SO4=58,8: 14,7%=400(g)

=>mddsau= 12,6+400 - 2.0,6= 411,4(g)

=>C%ddAl2(SO4)3= (34,2/411,4).100=8,313%

C%ddMgSO4=(36/411,4).100=8,751%

PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

a, Giả sử: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)

⇒ 24x + 27y = 12,6 (1)

Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Mg}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y\left(mol\right)\)

\(\Rightarrow x+\dfrac{3}{2}y=0,6\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{MG}=\dfrac{0,3.24}{12,6}.100\%\approx57,1\%\\\%m_{Al}\approx42,9\%\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\n_{MgSO_4}=n_{Mg}=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{H_2SO_4}=0,6.98=58,8\left(g\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{58,8}{14,7\%}=400\left(g\right)\)

Ta có: m _{dd sau pư} = 12,6 + 400 - 0,6.2 = 411,4 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO_4}=\dfrac{0,3.120}{411,4}.100\%\approx8,75\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{411,4}.100\%\approx8,31\%\end{matrix}\right.\)

Bạn tham khảo nhé!

Bài 6 : Chất rắn không tan là Cu

$m_{Cu} = 6,4(gam)$

Gọi $n_{Al} = a(mol) ; n_{Mg} = b(mol) \Rightarrow 27a + 24b + 6,4 = 14,2(1)$

$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 +3 H_2$
$Mg + H_2SO_4 \to MgSO_4 + H_2$
$n_{H_2} = 1,5a + b = 0,4(2)$

Từ (1)(2) suy ra a = 0,2 ; b = 0,1

$\%m_{Al} = \dfrac{0,2.27}{14,2}.100\% = 38,03\%$
$\%m_{Mg} = \dfrac{0,1.24}{14,2}.100\% =16,9\%$
$\%m_{Cu} = 100\% -38,03\% - 16,9\% = 45,07\%$

Bài 7 : 

Gọi $n_{CuO} = a(mol) ; n_{ZnO} = b(mol) \Rightarrow 80a + 81b = 12,1(1)$
$CuO + 2HCl \to CuCl_2 + H_2O$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
$n_{HCl} = 2a + 2b = 0,1.3 = 0,3(2)$

Từ (1)(2) suy ra a= 0,05 ; b = 0,1

$\%m_{CuO} = \dfrac{0,05.80}{12,1}.100\% = 33,06\%$
$\%m_{ZnO}  = 100\% - 33,06\% = 66,94\%$

Đáp án D

• a gam Mg (x mol), Al (y mol) + HCl → 0,8 mol H₂↑

→ x + 3/2y = 0,8 (*)

• a gam Mg, Al + NaOH dư → 0,6 mol H₂↑

→ 3/2y = 0,6 → y = 0,4 mol → x = 0,2 mol

→ a = m_Mg + m_Al = 0,2 × 24 + 0,4 × 27 = 15,6 gam

Đáp án C.

Kim loại không phản ứng với H₂SO₄ loãng là Cu.

Gọi n_Cu = x, n_Mg = y, n_Al = z

Ta có:

64x + 24y + 27z = 33,2 (1)

Bảo toàn e:

2n_Mg + 3n_Al = 2n_H2  

=> 2y + 3z = 2.1 (2)

2n_Cu = 2n_SO2  =>  x = 0.2 (mol) (3)

Từ 1, 2, 3 => x = 0,2; y = z = 0,4 (mol)

m_Cu = 0,2.64 = 12,8 (g)

m_Mg = 0,4.24 = 9,6 (g)

m_Al = 10,8 (g)

Đáp án là D. 38,55%.

Bạn tham khảo link :     https://hoidap247.com/cau-hoi/307206