\(a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ b.n_{H_2}=\dfrac{4,48}{22,4}-0,2mol\\ n_{Zn}=n_{H_2SO_4}=n_{H_2}=0,2mol\\ \%m_{Zn}=\dfrac{0,2.65}{19,4}\cdot100=67,01\%\\ \%m_{Cu}=100-67,01=32,99\%\\ m_{ddH_2SO_4}=\dfrac{0,2.98}{20}\cdot100=98g\)

\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)

Anh có làm rồi nha!

a) 

TN1: Gọi (n_Zn; n_Fe; n_Cu) = (a; b; c)

=> 65a + 56b + 64c = 18,5 (1)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            a---------------------->a

            Fe + 2HCl --> FeCl₂ + H₂

             b----------------------->b

=> a + b = 0,2 (2)

TN2: Gọi (n_Zn; n_Fe; n_Cu) = (ak; bk; ck)

=> ak + bk + ck = 0,15 (3)

PTHH: Zn + Cl₂ --t^o--> ZnCl₂

           ak-->ak

           2Fe + 3Cl₂ --t^o--> 2FeCl₃

            bk--->1,5bk

           Cu + Cl₂ --t^o--> CuCl₂

           ck-->ck

=> \(ak+1,5bk+ck=\dfrac{3,92}{22,4}=0,175\)(4)

(1)(2)(3)(4) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,1\left(mol\right)\\c=0,1\left(mol\right)\\k=0,5\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{18,5}.100\%=35,135\%\\\%m_{Fe}=\dfrac{0,1.56}{18,5}.100\%=30,27\%\\\%m_{Cu}=\dfrac{0,1.64}{18,5}.100\%=34,595\%\end{matrix}\right.\)

b) n_O(oxit) = \(\dfrac{23,7-18,5}{16}=0,325\left(mol\right)\)

=> n_H2O = 0,325 (mol)

=> n_HCl = 0,65 (mol)

=> \(V=\dfrac{0,65}{1}=0,65\left(l\right)=650\left(ml\right)\)

Số mol của 2,24 lít khí H2:

\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH:

\(2Na+2H_2O\rightarrow2NaOH+H_2\uparrow\left(1\right)\)

2     :    2        :    2             : 1 

0,1->   0,1     :   0,1           :  0,05(mol)

\(Na_2O+H_2O\rightarrow2NaOH\left(2\right)\)

Khối lượng của 0,2 mol Na:

\(m_{Na}=n.M=0,2.23=4,6\left(g\right)\)

Do hỗn hợp A gồm Na và H2O nên ta có:

\(m_{Hỗnhợp}=m_{Na}+m_{Na_2O}\\ \Rightarrow m_{Na_2O}=m_{Hỗnhợp}-m_{Na}\\ \Rightarrow m_{Na_2O}=12,4-4,6\\ \Rightarrow m_{Na_2O}=7,8\left(g\right)\)

PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)

           \(Na_2O+H_2O\rightarrow2NaOH\)

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)

\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)

Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)

Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)