Na₂O + H₂O → 2NaOH

                                           1            1            2

                                          0,1                       0,2

a).  n_Na2O=\(\dfrac{6,2}{62}\)= 0,1(mol)

       C_M=\(\dfrac{n}{V}\)=\(\dfrac{0,1}{4}\)= 0,025M

b).              Na₂O + H₂SO₄ → Na₂SO₄ + H₂O

                      1            1                1            1

                     0,1        0,1

m_H2SO4= n.M = 0,1 . 98 = 9,8g

⇒m_ddH2SO4= m_ct=\(\dfrac{mct.100\%}{C\%}\)= \(\dfrac{9,8.100}{20}\)= 49(g).

a) PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)

Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{6,2}{62}=0,2\left(mol\right)\)

\(\Rightarrow C\%_{NaOH}=\dfrac{0,2\cdot40}{6,2+93,8}\cdot100\%=8\%\)

b) PTHH: \(HCl+NaOH\rightarrow NaCl+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{HCl}=\dfrac{400\cdot7,3\%}{36,5}=0,8\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,2\left(mol\right)\\n_{HCl\left(dư\right)}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{NaCl}=\dfrac{0,2\cdot58,5}{6,2+93,8+400}\cdot100\%=2,34\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,6\cdot36,5}{6,2+93,8+400}\cdot100\%=4,38\%\end{matrix}\right.\)

c) Tương tự các phần trên 

\(n_{Na_2O}=\dfrac{6.2}{62}=0.1\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

\(0.1...........................0.2\)

\(C_{M_{NaOH}}=\dfrac{0.2}{1}=0.2\left(M\right)\)

\(n_{Na_2O}=\dfrac{6,2}{62}=0,1 \left(mol\right)\)

\(2Na+2H_2O\rightarrow2NaOH+H_2\)

0,1 -----------------> 0,1

\(CM_{base}=CM_{NaOH}=\dfrac{0,1}{0,2}=0,5M\)

b

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

0,05 <------ 0,1

\(V_{H_2SO_4}=\dfrac{0,05}{0,2}=0,25\left(l\right)\Rightarrow V_{dd.H_2SO_4}=\dfrac{0,25.100}{20}=1,25\left(l\right)\)

n_Na2O = 3,1/62 = 0,05 mol

Na2O + H2O ➝ 2NaOH

 0,05                    0,1 mol

➝ mNaOH = 0,1.40 = 4 gam

Khối lượng dung dịch sau phản ứng: 3,1 + 169,9 = 173 gam

➝ Nồng độ dung dịch A = \(\dfrac{4}{173}.100=2,312\%\)

Anh bổ sung câu c)

\(C_{MddNa_2SO_4}=\dfrac{0,25}{0,09879+0,5}=0,4175\left(M\right)\)

\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)

a/

\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

0,15 0,3 (mol)

\(m_{NaOH}=0,3.40=12\left(g\right)\)

\(m_A=90,7+9,3=100\left(g\right)\)

\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)

b/

m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)

\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)

\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)

pư: 0,3 0,15 0,15 0,15 (mol)

dư: 0 \(\dfrac{23}{380}\) (mol)

\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)

\(m_C=100+200-13,5=286,5\left(g\right)\)

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)

\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)

\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)