Khí thoát ra là metan

\(\%V_{CH_4} = \dfrac{5,6}{13,44}.100\% =41,67\%\\ \%V_{C_2H_4} = 100\% - 41,67\% = 58,33\%\\ b) V_{C_2H_2} = 13,44 -5,6 = 7,84(lít)\\ n_{C_2H_2} = \dfrac{7,84}{22,4} = 0,35(mol)\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ n_{Br_2} = 2n_{C_2H_2} = 0,7(mol)\\ \Rightarrow C_{M_{Br_2}} = \dfrac{0,7}{0,25} = 2,8M\\ c)\)

\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ V_{O_2} = 2V_{CH_4} + 3V_{C_2H_4} = 5,6.2 + 7,84.3 = 34,72(lít)\)

\(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1mol\)

\(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)

a) \(n_{SO_2}=n_{Na_2SO_3}=0,1mol\) \(\Rightarrow V=2,24l\)

b) \(n_{H_2SO_4}=n_{Na_2SO_3}=0,1mol\) \(\Rightarrow C_M=\dfrac{0,1}{0,2}=0,5M\)

c) \(m_{Na_2SO_4}=0,1\cdot142=14,2g\)

\(a,H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=1.0,4=0,4\left(mol\right)\\ n_{NaOH}=0,4.2=0,8\left(mol\right)\\ b,V_{ddNaOH}=\dfrac{0,8}{0,5}=1,6\left(l\right)\\ c,n_{Na_2SO_4}=n_{H_2SO_4}=0,4\left(mol\right)\\ V_{ddNa_2SO_4}=0,4+1,6=2\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,4}{2}=0,2\left(M\right)\)

a)

$Zn + H_2SO_4 \to ZnSO_4 + H_2$
Theo PTHH : 

$n_{H_2} = n_{Zn} = \dfrac{6,5}{65} = 0,1(mol)$
$V_{H_2} = 0,1.22,4 = 2,24(lít)$

b) $n_{H_2SO_4} = n_{Zn} = 0,1(mol)$
$V_{dd\ H_2SO_4} = \dfrac{0,1}{1} = 0,1(lít)$

c) $n_{ZnSO_4} = 0,1(mol) \Rightarrow m_{ZnSO_4} = 0,1.161 = 16,1(gam)$

d) $C_{M_{ZnSO_4}} = \dfrac{0,1}{0,1} = 1M$

a) \(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)

PTHH: Na₂CO₃ + 2HCl --> 2NaCl + CO₂ + H₂O

                0,2------------------>0,4---->0,2

m_{dd sau pư} = 200 + 21,2 - 0,2.44 = 212,4(g)

=> \(C\%\left(NaCl\right)=\dfrac{0,4.58,5}{212,4}.100\%=11,017\%\)

$PTHH:Na_2CO_3+2HCl\to 2NaCl+H_2O+CO_2\uparrow$

$n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2(mol)$

Theo PT: $n_{NaCl}=n_{CO_2}=0,2(mol)$

$\Rightarrow m_{NaCl}=0,4.58,5=23,4(g);m_{CO_2}=0,2.44=8,8(g)$

$\Rightarrow C\%_{NaCl}=\dfrac{23,4}{21,2+200-8,8}.100\%\approx 11,01\%$

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)

Theo pt: \(n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,4=0,6\left(mol\right)\)

\(V_{H_2}=0,6.22,4=13,44\left(l\right)\)

b) Theo pt: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,4=0,6\left(mol\right)\)

\(m_{H_2SO_4}=0,6.98=58,8g\)

\(C_{\%}dd_{H_2SO_4}=\dfrac{m_{ct}}{m_{dd}}.100\%=\dfrac{58,8}{200}.100\%=29,4\%\)

c) Theo pt: \(n_{Al_2\left(SO_4\right)_3}=\dfrac{n_{Al}}{2}=0,2\left(mol\right)\)

\(m_{Al_2\left(SO_4\right)_3}=0,2.342=68,4\left(g\right)\)

Áp dụng định luật bảo toàn khối lượng

\(m_{dd_{Al_2\left(SO_4\right) _3}}=m_{Al}+m_{dd_{H_2SO_4}}-m_{H_2}\)

\(=10,8+200-0,6.2=209,6g\)

\(C_{\%_{Al_2\left(SO_4\right)_3}}=\dfrac{68,4}{209,6}.100\%\approx32,6\%\)

Đề câu 2 sao khỏi làm đi

a) Khí thoát ra là CH₄

\(\%V_{CH_4} = \dfrac{6,72}{13,44}.100\% = 50\%\\ \%V_{C_2H_4} = 100\% -50\% = 50\%\\ b)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4}= \dfrac{13,44.50\%}{22,4} = 0,3(mol)\\ C_{M_{Br_2}} = \dfrac{0,3}{0,2} = 1,5M\)

$n_{CO_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$n_{Na_2CO_3} = 0,4.0,1 = 0,04(mol)$
Bảo toàn Cacbon : $n_{NaHCO_3} = 0,2 - 0,04 = 0,16(mol)$
Bảo toàn Natri  :$n_{NaOH} = 0,16 + 0,04.2 = 0,24(mol)$
$C_{M_{NaOH}} = \dfrac{0,24}{0,4} = 0,6M$

\(n_{Na_2CO_3}=0.1\cdot0.4=0.04\left(mol\right)\)

\(n_{CO_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)

\(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\)

\(0.08...........0.04.............0.04\)

\(NaOH+CO_2\rightarrow NaHCO_3\)

\(0.16......0.2-0.04\)

\(n_{NaOH}=0.08+0.16=0.24\left(mol\right)\)

\(C_{M_{NaOH}}=\dfrac{0.24}{0.4}=0.6\left(M\right)\)