a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(Cu+2H_2SO_{4\left(đ\right)}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)

\(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)

\(n_{SO_2}=\dfrac{2,9748}{24,79}=0,12\left(mol\right)\)

\(n_{Cu}=n_{SO_2}=0,12\left(mol\right)\)

\(\Rightarrow m=m_{Zn}+m_{Cu}=0,1.65+0,12.64=14,18\left(g\right)\)

Có: \(n_{H_2SO_{4\left(đ\right)}}=2n_{SO_2}=0,24\left(mol\right)\Rightarrow x=m_{ddH_2SO_4\left(đ\right)}=\dfrac{0,24.98}{98\%}=24\left(g\right)\)

Số mol HCl tham gia pư là 

nHCl = 0.6(mol) 
gọi số mol K2CO3 = x (mol) 
số mol Na2CO3 = y(mol) 
Ta có : x + y = nCO2 = 0.25(mol) 
theo bra ta có pt 
K2CO3 + 2HCl ---> 2KCl + H2O + CO2 
x----------->2x-------------------------... 
Na2CO3 + 2HCl ---> 2NaCl + H2O + CO2 
y-------------->2y----------------------... Vậy số mol HCl pư là 
n(HCl) = 2 x 0.25 = 0.5(mol) 
Vậy số mol HCl còn dư là 
n(HCl dư) = 0.1(mol) = nNaOH( pt HCl+ NaOH---> NaCl + H2O) 
muối khan là NaOH 
Vậy ta có dd thu được gồm : K(+) , Na(+), Cl(-) , Na(+) 
Ta có : 78x + 46y = 39.9 - 0.6*35.5 - 23*0.1 = 16.3 
Lâp hệ gồm pt : x+y =0,25 => x=0,15; y=0,1 
78x+ 46y= 16,3 
Vậy m(K2CO3)=n.M = 0,15 . 138=20,7 g 
m( Na2CO3)= n.M= 0,1 . 106=10,6 (g) 
vậy m (hh) là 20,7 + 10,6= 31,3(g) 
Vậy % m (K2CO3) = 20,7: 31,3.100%=66,15 %( xấp xỉ) 
% m( Na2CO3)= 100%- 66,15%=33,85% 

đề bài 1 có vấn đề

1.a) \(A+HCl\rightarrow ACl+\dfrac{1}{2}H_2\)

Ta có : \(n_A=2n_{H_2}=2.\dfrac{2,8}{22,4}=0,25\left(mol\right)\)

\(\Rightarrow M_A=\dfrac{9,75}{0,25}=39\)

Vậy A là Kali (K)

b)\(n_{HCl}=2n_{H_2}=0,25\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,25.26,5=9,125\left(g\right)\)

\(n_{Zn}=a\left(mol\right),n_{Al}=b\left(mol\right)\)

\(n_{H_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+H_2\)

\(n_{H_2}=a+1.5b=0.4\left(mol\right)\left(1\right)\)

\(m_{Muối}=m_{ZnCl_2}+m_{AlCl_3}=136a+133.5b=40.3\left(g\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.1,b=0.2\)

\(m_{hh}=0.1\cdot65+0.2\cdot27=11.9\left(g\right)\)

\(\%Zn=\dfrac{0.1\cdot65}{11.9}\cdot100\%=54.62\%\)

\(\%Al=100-54.62=45.38\%\)

\(n_{H_2}=\dfrac{1,85925}{24,79}=0,075\left(mol\right)\)

\(m_{dd.HCl}=500.1,2=600\left(g\right)\)

\(2R+6HCl\rightarrow2RCl_3+3H_2\)

0,05<-0,15<--0,05<----0,075

a. \(R=\dfrac{1,35}{0,05}=27\left(g/mol\right)\)

Vậy tên kim loại là nhôm (Al)

b. 

\(n_{AgCl}=\dfrac{14,35}{143,5}=0,1\left(mol\right)\)

\(HCl+AgNO_3\rightarrow AgCl+HNO_3\)

0,025<-------------0,025

\(AlCl_3+3Ag\left(NO_3\right)\rightarrow3AgCl+Al\left(NO_3\right)_3\)

0,025------------------->0,075

\(CM_{HCl.đã.dùng}=\dfrac{0,025}{0,5}=0,05M\)

c.

\(m_{dd.X}=1,35+600-0,075.2=601,2\left(g\right)\)

\(n_{HCl.dư}=0,025.2=0,05\left(mol\right)\)

\(C\%_{AlCl_3}=\dfrac{0,05.133,5.100\%}{601,2}=1,11\%\)

\(C\%_{HCl.dư}=\dfrac{0,05.36,5.100\%}{601,2}=0,3\%\)

a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

           0,1<----------------------------0,15

=> \(\%m_{Al}=\dfrac{0,1.27}{7,5}.100\%=36\%\)

\(\%m_{Cu}=100\%-36\%=64\%\)

b) \(n_{Cu}=\dfrac{7,5-0,1.27}{64}=0,075\left(mol\right)\)

PTHH: Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

          0,075------------------------>0,075

            2Al + 6H₂SO₄ --> Al₂(SO₄)₃ + 3SO₂ + 6H₂O

              0,1----------------------------->0,15

=> V_SO2 = (0,075 + 0,15).22,4 = 5,04 (l)

Tham khảo: https://hoidap247.com/cau-hoi/1781711