\(n_{H_2}=0,015\left(mol\right)\)
\(n_{H_2SO_4}=0,0152\left(mol\right)\)
\(n_{CuSO_4}=0,0152\left(mol\right)\)
\(Ba^{2+}+SO_4^{2-}-->BaSO_4\)
\(Cu^{2+}+2OH^--->Cu\left(OH\right)_2\)
a) Do 2 kim loại có cùng số mol \(\Rightarrow\) đặt \(n_{Na}=n_{Ba}=a\left(mol\right)\)
BT e : \(n_{Na}+2n_{Ba}=2n_{H_2}\Leftrightarrow a+2a=0,15.2\Rightarrow a=0,1\left(mol\right)\)
\(n_{Na^+}=n_{Na}=0,1\left(mol\right);n_{Ba^{2+}}=n_{Ba}=0,1\left(mol\right)\)
\(\Sigma n_{SO_4^{2-}}=n_{H_2SO_4}+n_{CuSO_4}=0,0152+0,0152=0,0304\left(mol\right)\)
\(\Rightarrow SO_4^{2-}pư\) hết \(\Rightarrow n_{BaSO_4}=0,0304.233=7,0832\left(g\right)\)
\(\Sigma n_{OH^-}=n_{Na^+}+2n_{Ba^{2+}}=0,1+0,1.2=0,3\left(mol\right)\)
\(n_{OH\left(Cu\left(OH\right)_2\right)}=n_{OH^-Bđ}-n_{Ba^{2+}dư}-n_{Na^+}=0,3-\left(0,1-0,0304\right)-0,1=0,1304\left(mol\right)\)
\(n_{Cu\left(OH\right)_2}=\dfrac{0,1304}{2}=0,0652\left(mol\right)\Rightarrow m_{Cu\left(OH\right)_2}=0,0652.98=6,3896\left(g\right)\)
\(\Rightarrow m=m_{BaSO_4}+m_{Cu\left(OH\right)_2}\)