\(Fe\left(NO_3\right)_2--->Fe_2O_3+NO_2+O_2\)

Bảo toàn nguyên tố Fe :

\(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(NO_3\right)_2}.90\%=\dfrac{1}{2}.\dfrac{23,4}{180}.90\%=0.065.90\%=0.0585\left(mol\right)\)

⇒ m_CR = 9.36(g)

\(a,n_{CuO}=\dfrac{59}{80}=0,7375\left(mol\right)\\ PTHH:2Cu\left(NO_3\right)_2\rightarrow^{t^o}2CuO+4NO_2\uparrow+O_2\uparrow\\ \Rightarrow\left\{{}\begin{matrix}n_{O_2}=\dfrac{1}{2}n_{CuO}=0,36875\left(mol\right)\\n_{NO_2}=2n_{CuO}=1,475\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,36875\cdot22,4=8,26\left(l\right)\\V_{NO_2}=1,475\cdot22,4=33,04\left(l\right)\end{matrix}\right.\)

\(b,\text{Chất rắn thu đc là }CuO\text{ gồm có }Cu,O\\ \%_O=\dfrac{16}{80}\cdot100\%=20\%\\ \Rightarrow m_O=59\cdot20\%=11,8\left(g\right)\\ \Rightarrow m_{Cu}=59-11,8=47,2\left(g\right)\)

ủa anh minh lm r mà trong này nè

Tham khảo:

https://hoc24.vn/cau-hoi/nung-752-gam-cuno32-bi-phan-huy-theo-so-do-phan-ung-sau-cuno32-cuo-no2-o2-sau-mot-thoi-gian-thay-con-lai-59-gam-chat-ran-a-tinh-the-ti.3307073058847

\(n_{Cu\left(NO_3\right)_2}=\dfrac{75,2}{188}=0,4mol\)

Gọi \(n_{Cu\left(NO_3\right)_2pứ}=x\left(mol\right)\)

\(Cu\left(NO_3\right)_2\underrightarrow{t^o}CuO+2NO_2+O_2\)

\(m_{CuO}=80x\left(g\right)\)

\(m_{Cu\left(NO_3\right)_2pứ}=188\cdot\left(0,4-x\right)mol\)

\(\Rightarrow m_{CuO}+m_{Cu\left(NO_3\right)_2pứ}=59\)

\(\Rightarrow x=0,15mol\)

\(V_{NO_2}=2\cdot0,15\cdot22,4=6,72l\)

\(V_{O_2}=0,15\cdot22,4=3,36l\)

\(m_{CuO}=0,15\cdot80=12g\)

Đặt : 

\(n_{O_2}=a\left(mol\right)\)

\(2Cu\left(NO_3\right)_2\underrightarrow{^{^{t^0}}}2CuO+4NO_2+O_2\)

\(2a..............2a.......4a......a\)

\(BTKL:\)

\(m_{khí}=75.2-59=16.2\left(g\right)\)

\(\Rightarrow4a\cdot46+32a=16.2\)

\(\Rightarrow a=0.075\)

\(V_{NO_2}=0.075\cdot4\cdot22.4=6.72\left(l\right)\)

\(V_{O_2}=0.075\cdot22.4=1.68\left(l\right)\)

Chất rắn gồm : Cu(NO₃)₂ dư , CuO 

\(m_{CuO}=0.075\cdot2\cdot80=12\left(g\right)\)

\(m_{Cu\left(NO_3\right)_2\left(dư\right)}=75.2-0.075\cdot2\cdot188=47\left(g\right)\)

Gọi \(n_{Cu\left(NO3\right)2\left(pư\right)}:a\left(mol\right)\)

\(n_{Cu\left(NO3\right)2\left(bđ\right)}=0,08\left(mol\right)\)

\(PTHH:2Cu\left(NO_3\right)_2\rightarrow2CuO+O_2+4NO_2\)

_____________a_______a__________0,5a____2a

\(n_{Cu\left(NO3\right)2\left(dư\right)}=0,08-a\left(mol\right)\)

\(n_{CuO}=a\left(mol\right)\Rightarrow\left(0,08-a\right).188+80a=8,56\)

\(\Leftrightarrow a=0,06\left(mol\right)\)

\(\Rightarrow H=\frac{0,06}{0,08}.100\%=75\%\)

\(\left\{{}\begin{matrix}n_{NO2}=0,06.2=0,12\left(mol\right)\\n_{O2}=0,5a=0,03\left(mol\right)\end{matrix}\right.\)

\(M_{khi}=43,2\left(\frac{g}{mol}\right)\Rightarrow d_{M_{khi}/H2}=\frac{43,2}{2}=21,6\)

Đáp án B

2Cu(NO₃)₂ → t o  2CuO + 4NO₂ + O₂

Do chất rắn thu được + HNO₃ giải phóng khí NO => Cu dư => O₂ sinh ra do phản ứng nhiệt phân phản ứng hết với Cu

=> m_{rắn giảm} = m_NO2 bay lên= 9,2 (g) => n_NO2 =0,2 (mol)

BTNT N => n_Cu(NO3)2 = ½ n_NO2 = 0,1 (mol)

=> % m_Cu =  31,6 – 0,1.188 =  12,8  (g)