a/ Fe + 2HCl \(\rightarrow\) FeCl₂ + H₂

n_H2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PTHH: n_H2 = n_Fe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)

\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)

\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)

\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)

b/ Theo PTHH ta có: n_HCl = 2n_Fe = 2.0,15 = 0,3 (mol)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)

c/ m_HCl = 36,5 . 0,3 = 10,95(g)

\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)

b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)

c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)

PTHH\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)

tl............1................2.............2.............1.............1..(mol

br     0,1.................0,2......................................0,1(mol)

NaCl không phản ứng đc vsHCl

b)\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(C_{MHCl}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)(đổi 400ml=0,4(l))

c)\(Tacom_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)

\(\Rightarrow\%m_{Na_2CO_3}=\dfrac{10,6}{20}.100=53\%\)

\(\Rightarrow\%mNaCl=100\%-53\%=47\%\)

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+3H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=11\\1,5a+b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ a,n_{HCl}=2.n_{H_2}=2.0,4=0,8\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,8}{8}=0,1\left(l\right)\\ b,FeCl_2+2AgNO_3\rightarrow Fe\left(NO_3\right)_2+2AgCl\downarrow\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\downarrow\\ n_{AgCl}=n_{AgNO_3}=3.n_{AlCl_3}+2.n_{FeCl_2}=3.a+2.b=3.0,2+2.0,1=0,8\left(mol\right)\\ \Rightarrow a=\dfrac{170.0,8}{250}.100=54,4\%\\ b=m_{\downarrow}=m_{AgCl}=0,8.143,5=114,8\left(g\right)\)

a, \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: 2Al + 6HCl → 2AlCl₃ + 3H₂

Mol:      x                                   1,5x

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:     y                                   y

b, Ta có hpt: \(\left\{{}\begin{matrix}27x+56y=11\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\Rightarrow\%m_{Al}=\dfrac{0,2.27.100\%}{11}=49,09\%\Rightarrow\%m_{Fe}=100\%-49,09\%=50,91\%\)

c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

Ta có: \(\dfrac{0,2}{1}< \dfrac{0,4}{1}\) ⇒ CuO hết, H₂ dư

PTHH: CuO + H₂ → Cu + H₂O

Mol:      0,2                0,2

\(m_{Cu}=0,2.64=12,8\left(g\right)\)

Gọi \(m_{Al}=a\left(g\right)\left(0< a< 11\right)\)

\(\rightarrow m_{Fe}=11-a\left(g\right)\)

\(\rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{a}{27}\left(mol\right)\\n_{Fe}=\dfrac{11-a}{56}\left(mol\right)\end{matrix}\right.\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\dfrac{a}{27}\)                                       \(\dfrac{a}{18}\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(\dfrac{11-a}{56}\)                             \(\dfrac{11-a}{56}\)

\(\rightarrow pt:\dfrac{a}{18}+\dfrac{11-a}{56}=0,4\\ \Leftrightarrow m_{Al}=a=5,4\left(g\right)\left(TM\right)\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{5,4}{11}=49,1\%\\\%m_{Fe}=100\%-49,1\%=50,9\%\end{matrix}\right.\)

\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PTHH: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

LTL: \(0,2< 0,4\rightarrow\) H₂ dư

\(n_{Cu}=n_{CuO}=0,2\left(mol\right)\rightarrow m_{CuO}=0,2.64=12,8\left(g\right)\)

a. \(n_{H_2}=\dfrac{8.96}{22,4}=0,4\left(mol\right)\)

PTHH : 2Al + 6HCl -> 2AlCl₃ + 3H₂

              \(\dfrac{0.8}{3}\)                             0,4

             Fe + 2HCl -> FeCl₂ + H₂

\(m_{Al}=\dfrac{0,8.27}{3}=7,2\left(g\right)\)

\(m_{Fe}=11-7,2=3,8\left(g\right)\)

b. \(\%m_{Al}=\dfrac{7.2}{11}.100=65,5\%\)

\(\%m_{Fe}=100\%-65,5\%=34,5\%\)

c. \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PTHH : H₂ + CuO ----t^o----> Cu + H₂O

                      0,2                  0,2

\(m_{Cu}=0,2.64=12,8\left(g\right)\)

\(a,Fe+2HCl\rightarrow FeCl_2+H_2\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\Rightarrow n_{Fe}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Fe}=\dfrac{0,1.56}{13,6}.100\%\approx41,176\%\\ \Rightarrow\%m_{CuO}\approx58,824\%\\ b,n_{CuO}=\dfrac{13,6-0,1.56}{80}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.\left(n_{Fe}+n_{CuO}\right)=2.\left(0,1+0,1\right)=0,4\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)

a)

$2Al + 6HCl \to 2AlCl_3 + 3H_2$

$MgO + 2HCl \to MgCl_2 + H_2O$

Theo PTHH : $n_{Al} = \dfrac{2}{3}n_{H_2} = 0,2(mol)$
$\%m_{Al} = \dfrac{0,2.27}{18,8}.100\% = 28,7\%$

$\%m_{MgO} = 100\% - 28,7\% =71,3\%$

b) $n_{MgO} = 0,335(mol)$

Theo PTHH : $n_{HCl} = 2n_{H_2} + 2n_{MgO} =1,27(mol)$

$V_{dd\ HCl} = \dfrac{1,27}{1,6} = 0,79375(lít)$

c) 

$H_2 + O_{oxit} \to H_2O$

$\Rightarrow n_{O(oxit)} = n_{H_2} = 0,3(mol)$
$\Rightarrow n_{Fe} = \dfrac{17,4 - 0,3.16}{56} = 0,225(mol)$

Ta có : 

$n_{Fe} : n_O = 0,225 : 0,3 = 3 : 4$

Vậy oxit là $Fe_3O_4$