\(a,\left\{{}\begin{matrix}m_{BaCl_2}=\dfrac{100\cdot10,4\%}{100\%}=10,4\left(g\right)\\m_{H_2SO_4}=\dfrac{200\cdot9,8\%}{100\%}=19,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\\n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\end{matrix}\right.\)

\(PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)

Vì \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{2}\) nên \(H_2SO_4\) dư

\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,05\cdot233=11,65\left(g\right)\)

\(b,n_{HCl}=n_{BaSO_4}=0,05\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,05\cdot36,5=1,825\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=100+200-11,65=288,35\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{1,825}{288,35}\cdot100\%\approx0,63\%\)

\(m_{ct}=\dfrac{19,6.200}{100}=39,2\left(g\right)\)

\(n_{H2SO4}=\dfrac{39,2}{98}=0,4\left(mol\right)\)

\(m_{ct}=\dfrac{5,2.200}{100}=10,4\left(g\right)\)

\(n_{BaCl2}=\dfrac{10,4}{208}=0,05\left(mol\right)\)

Pt : \(H_2SO_4+BaCl_2\rightarrow2HCl+BaSO_4|\)

            1             1             2             1

          0,4           0,05        0,1         0,05

a) Lập tỉ số so sánh: \(\dfrac{0,4}{1}>\dfrac{0,05}{1}\)

             ⇒ H₂SO₄ dư , BaCl₂ phản ứng hết

             ⇒ Tính toán dựa vào số mol của BaCl₂

\(n_{BaSO4}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)

⇒ \(m_{BaSO4}=0,05.233=11,65\left(g\right)\)

b) \(n_{HCl}=\dfrac{0,05.2}{1}=0,1\left(mol\right)\)

⇒ \(m_{HCl}=0,1.36,5=3,65\left(g\right)\)

\(n_{H2SO4\left(dư\right)}=0,4-0,05=0,35\left(mol\right)\)

⇒ \(m_{H2SO4\left(dư\right)}=0,35.98=34,3\left(g\right)\)

\(m_{ddspu}=200+200-11,65=388,35\left(g\right)\)

\(C_{ddHCl}=\dfrac{3,65.100}{388,35}=0,94\)⁰/₀

\(C_{ddH2SO4\left(dư\right)}=\dfrac{34,3.100}{388,35}=8,83\)⁰/₀

 Chúc bạn học tốt

\(a.n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\\ n_{BaCl_2}=\dfrac{200.5,2\%}{208}=0,05\left(mol\right)\\ BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ Vì:\dfrac{0,05}{1}< \dfrac{0,4}{1}\\ \Rightarrow H_2SO_4dư\\ n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{\downarrow}=m_{BaSO_4}=0,05.233=11,65\left(g\right)\\ b.m_{ddsau}=200+200-11,65=388,35\left(g\right)\\ C\%_{ddHCl}=\dfrac{0,05.2.36,5}{388,35}.100\approx0,94\%\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{\left(0,4-0,05\right).98}{388,35}.100\approx8,832\%\)

\(n_{H_2SO_4\left(bđ\right)}=0,5.0,2=0,1\left(mol\right)\)

Gọi số mol SO₃ thêm vào là a (mol)

PTHH: SO₃ + H₂O --> H₂SO₄

              a--------------->a

=> \(C_{M\left(dd.sau.pư\right)}=\dfrac{a+0,1}{0,2}=0,8M\)

=> a = 0,06 (mol)

=> m_SO3 = 0,06.80 = 4,8 (g)

m Na2SO4=10.\(\dfrac{150}{100}\)=15g

đề có dd là 5%

=>5%=\(\dfrac{15}{mdd}.100\)

=>mdd =300g

=> mH2O cần thêm =300-150=150g

\(1.SO_3+H_2O\rightarrow H_2SO_4\\ 2.m_{H_2SO_4}=\dfrac{200.19,6\%}{100\%}=39,2g\\ n_{H_2SO_4}=\dfrac{39,2}{98}=0,4mol\\ n_{SO_2}=n_{H_2SO_4}=0,4mol\\ m=m_{SO_2}=0,4.64=25,6g\)

\(n_{SO_3}=a\left(mol\right)\)

\(m_{H_2SO_4}=500\cdot22.5\%=112.5\left(g\right)\)

\(SO_3+H_2O\rightarrow H_2SO_4\)

\(a.................a\)

\(m_{H_2SO_4}=98a+112.5\left(g\right)\)

\(m_{dd_{H_2SO_4}}=80a+500\left(g\right)\)

\(C\%_{H_2SO_4}=\dfrac{98a+112.5}{80a+500}\cdot100\%=42.5\%\)

\(\Leftrightarrow a=1.5625\)

\(m_{SO_3}=125\left(g\right)\)

cái này áp dụng đg chéo đc ko ạ

Số mol SO3 cần thân vào là x (mol)

Ta có: SO3 + H2O -> H2SO4

             x          x

mH2SO4 tạo thành là: 98x (gam)

mH2SO4 22,5% là: 500 x 22,5% = 112,5 (gam)

-> (98x + 112,5). 100/80x + 500 = 42,5

-> x = 1,5625

mSO3 = 1,5625 x 80 = 125 (gam)