nH2SO4=0,02.1=0,02(ol)

a) PTHH: 2 NaOH + H2SO4 -> Na2SO4 + 2 H2O

0,04____________0,02____0,02(mol)

mNaOH=0,04.40= 1,6(g)

=>mddNaOH= (1,6.100)/20= 8(g)

b) PTHH: H2SO4 + 2 KOH -> K2SO4 + 2 H2O

0,2____________0,04(mol)

=>mKOH=0,04.56=2,24(g)

=>mddKOH= (2,24.100)/5,6=40(g)

=>VddKOH= mddKOH/DddKOH= 40/1,045=38,278(ml)

Đáp án C

C % = C M . M 10. D = 2.56 10.1,43 = 7,832 %

n_Fe = 11.2/56 = 0.2 (mol) 

Fe + H2SO4 => FeSO4 + H2 

0.2____0.2_______0.2___0.2 

mH2SO4 = 0.2*98 = 19.6 (g) 

mdd H2SO4 = 19.6*100/10 = 196 (g) 

m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g) 

mFeSO4 = 0.2*152 = 30.4 (g) 

C% FeSO4 = 30.4/206.8 * 100% = 14.7% 

Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml) 

CM FeSO4 = 0.2 / 0.1719 = 1.16 M 

n_Fe = 11.2/56 = 0.2 (mol) 

Fe + H2SO4 => FeSO4 + H2 

0.2____0.2_______0.2___0.2 

mH2SO4 = 0.2*98 = 19.6 (g) 

mdd H2SO4 = 19.6*100/10 = 196 (g) 

m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g) 

mFeSO4 = 0.2*152 = 30.4 (g) 

C% FeSO4 = 30.4/206.8 * 100% = 14.7% 

Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml) 

CM FeSO4 = 0.2 / 0.1719 = 1.16 M 

\(pH=10\)

\(\Rightarrow\left[H^+\right]=10^{-10}\)

\(\Rightarrow\left[OH^-\right]=10^{-4}\)

\(n_{OH^-}=10^{-4}.0,1=10^{-5}\left(mol\right)\)

\(n_{H^+}=0,1.2.0,01=0,003\left(mol\right)\)

\(\Rightarrow n_{H^+dư}=2,99.10^{-3}\left(mol\right)\)

\(\Rightarrow\left[H^+_{dư}\right]=\dfrac{2,99.10^{-3}}{0,2}=0,01495M\)

\(\Rightarrow pH\approx1,83\)

\(m_{ddKOH}=1,045.47,85=50\left(g\right)\)

\(\Rightarrow m_{KOH}=\dfrac{5,6.50}{100}=2,8\left(g\right)\)

\(n_{KOH}=0,05\left(mol\right)\)

\(m_{ddH_3PO_4}=1,08.18,25=19,71\left(g\right)\)

\(\Rightarrow m_{H_3PO_4}=\dfrac{14,7.19,71}{100}=2,89737\left(g\right)\)

\(n_{H_3PO_4}=0,03\left(mol\right)\)

\(\dfrac{n_{KOH}}{n_{H_3PO_4}}=\dfrac{0,05}{0,03}=1,67\)

=> Tạo muối NaH2PO4 và muối Na2HPO4

\(NaOH\left(0,03\right)+H_3PO_4\left(0,03\right)--->NaH_2PO_4\left(0,03\right)+H_2O\)\(\left(1\right)\)

\(NaOH\left(0,02\right)+NaH_2PO_4\left(0,02\right)--->Na_2HPO_4\left(0,02\right)+H_2O\)\(\left(2\right)\)

Sau phản ứng, muối thu được là: \(\left\{{}\begin{matrix}NaH_2PO_4:0,03-0,02=0,01\left(mol\right)\\Na_2HPO_4:0,02\left(mol\right)\end{matrix}\right.\)

\(m dd sau =50+19,71=69,71(g)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{NaH_2PO_4}=1,72\%\\C\%_{Na_2HPO_4}=4,07\%\end{matrix}\right.\)

\(n_{Al_2(SO_4)_3}=0,1.0,2=0,02(mol)\\ n_{KOH}=0,2.0,3=0,06(mol)\\ PTHH:Al_2(SO_4)_3+6KOH\to 2Al(OH)_3\downarrow+3K_2SO_4\)

Vì \(\dfrac{n_{Al_2(SO_4)_3}}{1}>\dfrac{n_{KOH}}{6}\) nên \(Al_2(SO_4)_3\) dư

\(a,n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,3(mol)\\ n_{Al(OH)_3}=\dfrac{1}{3}n_{KOH}=0,2(mol)\\ \Rightarrow m_{Al(OH)_3}=0,2.78=15,6(g)\\ C_{M_{K_2SO_4}}=\dfrac{0,3}{0,5}=0,6M\)

\(b,K_2SO_4\) ko tác dụng được với \(KOH\), bạn xem lại đề 

\(a,PTHH:KOH+HNO_3\rightarrow KNO_3+H_2O\\ b,n_{HNO_3}=3\cdot0,15=0,45\left(mol\right)\\ \Rightarrow n_{KOH}=n_{HNO_3}=0,45\left(mol\right)\\ \Rightarrow m_{CT_{KOH}}=0,45\cdot56=25,2\left(g\right)\\ \Rightarrow m_{dd_{KOH}}=\dfrac{25,2\cdot100\%}{25\%}=100,8\left(g\right)\\ c,V_{dd_{KOH}}=\dfrac{m_{dd_{KOH}}}{D}=\dfrac{100,8}{2,12}\approx47,5\left(ml\right)\)