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Đáp án : C.

Xét Na : n H 2 = 1 2 n N a = a 46 m o l

Bảo toàn khối lượng :

m_{dd sau} = m_Na + m H 2 O – m H 2  = a + p – 2.  a 46 (g)

=> C%_NaOH = x %

Xét Na₂O

=> m_{dd sau} = m N a 2 O + m H 2 O = b + p

a)

\(n_{H_2}=\dfrac{0,336}{22,4}=0,015\left(mol\right)\)

PTHH: 2Na + 2H₂O --> 2NaOH + H₂

          0,03<------------0,03<----0,015

=> \(\%m_{Na}=\dfrac{0,03.23}{1,31}.100\%=52,67\%\)

=> \(\%m_{Na_2O}=100\%-52,67\%=47,33\%\)

b)

\(n_{Na_2O}=\dfrac{1,31.47,33\%}{62}=0,01\left(mol\right)\)

PTHH: Na₂O + H₂O --> 2NaOH

            0,01----------->0,02

=> n_NaOH = 0,03 + 0,02 = 0,05 (mol)

m_{dd sau pư} = 1,31 + 18,72 - 0,015.2 = 20 (g)

=> \(C\%_{dd.NaOH}=\dfrac{0,05.40}{20}.100\%=10\%\)

\(V_{dd.NaOH}=\dfrac{20}{1,2}=\dfrac{50}{3}\left(ml\right)=\dfrac{1}{60}\left(l\right)\) 

\(C_{M\left(dd.NaOH\right)}=\dfrac{0,05}{\dfrac{1}{60}}=3M\)

\(a.n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\\ Na_2O+H_2O\rightarrow NaOH\\ m_{ddNaOH}=193,8+6,2=200\left(g\right)\\C\%_{ddX}=C\%_{ddNaOH}=\dfrac{0,1.2.40}{200}.100=4\%\\ b.2NaOH+CuSO_4\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\ a=m_{Cu\left(OH\right)_2}=\dfrac{0,2}{2}.98=9,8\left(g\right)\\ c.Cu\left(OH\right)_2\underrightarrow{to}CuO+H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{HCl}=2.n_{CuO}=2.n_{Cu\left(OH\right)_2}=2.0,1=0,2\left(mol\right)\\ V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(lít\right)=100\left(ml\right)\)

\(a)n_{Na}=\dfrac{9,2}{23}=0,4\left(mol\right)\\ PTHH:2Na+2H_2O\xrightarrow[]{}2NaOH+H_2\\ n_{H_2}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ b)n_{Na}=n_{NaOH}=0,4mol\\ m_{NaOH}=0,4.40=16\left(g\right)\\ m_{H_2}=0,2.2=0,4\left(g\right)\\ m_{ddNaOH}=9,2+191,2-0,4=200\left(g\right)\\ C_{\%NaOH}=\dfrac{16}{200}.100\%=8\%\)