check lại giúp mình câu b) nhé

C₂H₂ + Br₂ ra 1,2-đibrometen(tỉ lệ 1:1) hoặc 1,1,2,2-tetrabrometan(tỉ lệ 1:2) chứ không ra đibrometan nhé :v

a) m_tăng = m_C2H4 = 7 (g)

=> \(n_{C_2H_4}=\dfrac{7}{28}=0,25\left(mol\right)\)

\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,25.24,79}{9,916}.100\%=62,5\%\\\%V_{CH_4}=100\%-62,5\%=37,5\%\end{matrix}\right.\)

b) 

PTHH: C₂H₄ + Br₂ ---> C₂H₄Br₂

           0,25-->0,25

=> \(C_{M\left(dd.Br_2\right)}=\dfrac{0,25}{0,25}=1M\)

c)

\(n_{CH_4}=\dfrac{9,916}{24,79}-0,25=0,15\left(mol\right)\)

PTHH: CH₄ + 2O₂ --t^o--> CO₂ + 2H₂O

            0,15-->0,3

            C₂H₄ + 3O₂ --t^o--> 2CO₂ + 2H₂O

            0,25-->0,75

=> V_O2(đkc) = (0,3 + 0,75).24,79 = 26,0295 (l)

A tác dụng với nước

\(n_{H_2}=\dfrac{3,7185}{24,79}=0,15mol\\ Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)

\(a----------\rightarrow a\)

\(Ba\left(OH\right)_2+2Al+2H_2O\rightarrow Ba\left(AlO_2\right)_2+3H_2\)

\(a----------------\rightarrow3a\)

\(\Rightarrow a+3a=0,15\\ \Rightarrow a=0,0375mol\)

A tác dụng với NaOH

\(n_{H_2}=\dfrac{7,347}{24,79}=0,3mol\)

\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)

\(a----------\rightarrow a\)

\(2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2\)

\(b---------------\rightarrow1,5b\)

\(\Rightarrow a+1,5b=0,3\\ \Rightarrow0,0375+1,5b=0,3\\ \Rightarrow b=0,175mol\)

A tác dụng với HCl

\(n_{H_2}=\dfrac{9,916}{24,79}=0,4mol\)

\(Ba+2HCl\rightarrow BaCl_2+H_2\)

\(a---------\rightarrow a\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(b---------\rightarrow1,5b\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(c---------\rightarrow c\)

\(\Rightarrow a+1,5b+c=0,4\\ \Rightarrow0,0375+1,5.0,175+c=0,4\\ \Rightarrow c=0,1mol\)

\(m_A=0,0375.137+0,175.27+0,1.24=12,2625g\\ \%m_{Ba}=\dfrac{0,0375.137}{12,2625}\cdot100=41,9\%\\ \%m_{Al}=\dfrac{0,175.27}{12,2625}\cdot100=38,53\%\\ \%m_{Mg}=100-41,9-38,53=19,57\%\)

\(a)C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ C_3H_4+2Br_2\rightarrow C_3H_4Br_4\\ b)n_{hh}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{Br_2}=0,4.1=0,4\left(mol\right)\\ Đặt:x=n_{C_2H_4};y=n_{C_3H_4}\\ Tacó:\left\{{}\begin{matrix}x+y=0,25\\x+2y=0,4\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,15\end{matrix}\right.\\ \%V_{C_2H_4}=\%n_{C_2H_4}=\dfrac{0,1}{0,25}.100=40\%;\%V_{C_3H_4}=60\%\\ c)X+AgNO_3/NH_3chỉcóC_3H_4pứ\\ C_3H_4+AgNO_3+NH_3\rightarrow C_3H_3Ag+2NH_4NO_3\\ n_{C_3H_2Ag_2}=n_{C_3H_4}=0,15\left(mol\right)\\ \Rightarrow m=0,15.147=22,05\left(g\right)\)

a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, - Khí thoát ra là CH₄.

⇒ V_CH4 = 4,48 (l)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{4,48}{11,2}.100\%=40\%\\\%V_{C_2H_4}=100-40=60\%\end{matrix}\right.\)

- Do dung dịch brom dư, nên khí thoát ra là metan.

- Chọn đáp án A.

Đáp án A

Hướng dẫn

Chất khí thoát ra là CH₄ => thể tích CH₄ là 2,24 lít

=> % V C H 4 = 2 , 24 8 , 96 .100% = 25%

Đáp án A

a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{6,4}{160}=0,04\left(mol\right);n_{hh}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

             0,04<--0,04

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04}{0,6}.100\%=6,67\%\\\%V_{CH_4}=100\%-6,67\%=93,33\%\end{matrix}\right.\)

b) \(n_{CH_4}=0,6-0,04=0,56\left(mol\right)\)

PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)

              0,56----------->0,56

            \(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)

              0,04----------->0,08

\(\Rightarrow V_{CO_2}=\left(0,08+0,56\right).22,4=14,336\left(l\right)\)