1) \(\left\{{}\begin{matrix}n_{CO}+n_{CO_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\\\dfrac{28.n_{CO}+44.n_{CO_2}}{n_{CO}+n_{CO_2}}=16.2=32\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}n_{CO}=0,105\left(mol\right)\\n_{CO_2}=0,035\left(mol\right)\end{matrix}\right.\)

n_O = n_CO2 = 0,035 (mol)

=> a = 2,92 + 0,035.16 = 3,48(g)

\(n_{H_2SO_4}=\dfrac{100.5,39\%}{98}=0,055\left(mol\right)\)

n_H2O = n_O = 0,035 (mol)

Bảo toàn H: \(n_{H_2}=\dfrac{0,055.2-0,035.2}{2}=0,02\left(mol\right)\)

=> \(V=0,02.22,4=0,448\left(l\right)\)

2) Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Fe_3O_4}=b\left(mol\right)\\n_{CuO}=c\left(mol\right)\end{matrix}\right.\)

=> 56a + 232b + 80c = 3,48 (1)

Bảo toàn Fe: n_Fe = a + 3b (mol)

Bảo toàn Cu: n_Cu = c (mol)

PTHH: Fe + H₂SO₄ --> FeSO₄ + H₂

         0,02<-0,02<------0,02<---0,02

            Fe₃O₄ + 4H₂SO₄ --> Fe₂(SO₄)₃ + FeSO₄ + 4H₂O

                 b--->4b------------>b-------------->b

             CuO + H₂SO₄ --> CuSO₄ + H₂O

                c---->c------------>c

=> a = 0,02

=> 0,02 + 4b + c = 0,055 => 4b + c = 0,035 

(1) => 232b + 80c = 2,36

=> b = 0,005 (mol); c = 0,015 (mol)

B chứa \(\left\{{}\begin{matrix}FeSO_4:0,025\left(mol\right)\\Fe_2\left(SO_4\right)_3:0,005\left(mol\right)\\CuSO_4:0,015\left(mol\right)\end{matrix}\right.\)

m_{dd sau pư} = 3,48 + 100 - 0,02.2 = 103,44 (g)

=> \(\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{0,025.152}{103,44}.100\%=3,674\%\\C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,005.400}{103,44}.100\%=1,933\%\\C\%_{CuSO_4}=\dfrac{0,015.160}{103,44}.100\%=2,32\%\end{matrix}\right.\)

3)

Rắn khan chứa \(\left\{{}\begin{matrix}BaSO_4\\Fe\left(OH\right)_3\\Cu\left(OH\right)_2\end{matrix}\right.\)

Có: \(n_{BaSO_4}=n_{SO_4}=0,055\left(mol\right)\)

Bảo toàn Fe: \(n_{Fe\left(OH\right)_3}=n_{FeSO_4}+2.n_{Fe_2\left(SO_4\right)_3}=0,035\left(mol\right)\)

Bảo toàn Cu: \(n_{Cu\left(OH\right)_2}=0,015\left(mol\right)\)

=> b = 0,055.233 + 0,035.107 + 0,015.98 = 18,03 (g)

Đáp án C

Theo định luật bảo toàn khối lượng, ta có:

Chọn đáp án B

Ta có:

\(Đặt:n_{FeO}=a\left(mol\right),,n_{Fe_2O_3}=b\left(mol\right)\)

\(m_X=72a+160b=30.4\left(g\right)\left(1\right)\)

\(FeO+CÒ\underrightarrow{t^0}Fe+CO_2\)

\(Fe_2O_3+3CO\underrightarrow{t^0}2Fe+3CO_2\)

\(X:COdư,CO_2\)

\(m_X=m_{CO\left(dư\right)}+m_{CO_2}=\left(1-a-3b\right)\cdot28+\left(a+3b\right)\cdot44=36\left(g\right)\) 

\(\Leftrightarrow16a+48b=8\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.2,b=0.1\)

\(m_{Fe}=\left(0.2+0.1\cdot2\right)\cdot56=22.4\left(mol\right)\)

\(m_{FeO}=0.2\cdot72=14.4\left(g\right)\)

\(m_{Fe_2O_3}=0.1\cdot160=16\left(g\right)\)

Đáp án C

  = 

Đáp án A