a, \(n_{OH^-}=10^{-1}.V_A\left(mol\right)\)

\(n_{H^+}=10^{-2}.V_B\left(mol\right)\)

\(n_{OH^-dư}=10^{-2}.\left(V_A+V_B\right)\left(mol\right)\)

Ta có: \(n_{OH^-}-n_{OH^-dư}=n_{H^+}\)

\(\Leftrightarrow10^{-1}.V_A-10^{-2}.\left(V_A+V_B\right)=10^{-2}.V_B\)

\(\Leftrightarrow0,09V_A=0,02V_B\)

\(\Rightarrow\dfrac{V_A}{V_B}=\dfrac{2}{9}\)

b, Ta có: \(\left\{{}\begin{matrix}V_A+V_B=0,55\\\dfrac{V_A}{V_B}=\dfrac{2}{9}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}V_A=0,1\left(l\right)\\V_B=0,45\left(l\right)\end{matrix}\right.\)

\(n_{BaCl_2}=\dfrac{1}{2}n_{Cl^-}=\dfrac{1}{2}n_{H^+}=\dfrac{1}{2}.10^{-2}.0,1=0,0005\left(mol\right)\Rightarrow m_{BaCl_2}=0,104\left(g\right)\)

\(n_{Ba\left(OH\right)_2}=\dfrac{1}{2}n_{OH^-dư}=\dfrac{1}{2}.10^{-2}.0,55=0,00275\left(mol\right)\Rightarrow m_{Ba\left(OH\right)_2}=0,047025\left(g\right)\)

\(\Rightarrow\%m_{Ba\left(OH\right)_2}=\dfrac{0,047025}{0,047025+0,104}.100\%=31,14\%\)

\(\Rightarrow\%m_{BaCl_2}=62,86\%\)

Câu 1:

PT ion: \(H^++OH^-\rightarrow H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{OH^-}=0,6\cdot0,4+0,6\cdot0,3\cdot2=0,6\left(mol\right)\\n_{H^+}=0,2\cdot2,6=0,52\left(mol\right)\end{matrix}\right.\) 

\(\Rightarrow\) H⁺ hết, OH^- còn dư \(\Rightarrow n_{OH^-\left(dư\right)}=0,08\left(mol\right)\)

\(\Rightarrow\left[OH^-\right]=\dfrac{0,08}{0,6+0,2}=0,1\left(M\right)\) \(\Rightarrow pH=14+log\left(0,1\right)=13\)

Bài 2:

PT ion: \(H^++OH^-\rightarrow H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{OH^-}=0,3\cdot1,6=0,48\left(mol\right)\\n_{H^+}=0,2\cdot1\cdot2+0,2\cdot2=0,8\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\) OH^- hết, H⁺ còn dư \(\Rightarrow n_{H^+\left(dư\right)}=0,32\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,32}{0,2+0,3}=0,64\left(M\right)\) \(\Rightarrow pH=-log\left(0,64\right)\approx0,19\)

Đáp án B

Đáp án B

Đáp án B

Đáp án B

 Chọn đáp án C

Ta có: nBa(OH)2 = 0,1 mol ⇒ nOH– = 0,2 mol.

+ nHCl = 0,1 mol ⇒ nH+ = 0,1 mol.

+ Nhận thấy nOH– > nH+ ⇒ nOH– dư.

⇒ Dung dịch Z làm quỳ tím hóa xanh ⇒ Chọn C