Chất rắn ko tan là Cu

Đặt \(n_{Mg}=x(mol);n_{Al}=y(mol)\Rightarrow 24x+27y=13-4=9(1)\)

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45(mol)\\ PTHH:Mg+2HCl\to MgCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow x+1,5y=0,45(2)\\ (1)(2)\Rightarrow x=0,15(mol);y=0,2(mol)\\ a,\%_{Cu}=\dfrac{4}{13}.100\%=30,77\%\\ \%_{Mg}=\dfrac{0,15.24}{13}.100\%=27,69\%\\ \%_{Al}=100\%-30,77\%-27,69\%=41,54\%\\ b,\Sigma n_{HCl}=2x+3y=0,9(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,9}{2}=0,45(l)\)

a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)

\(\Rightarrow m=m_{Cu}=12-5,6=6,4\left(g\right)\)

b, \(n_{FeSO_4}=n_{H_2SO_4\left(pư\right)}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,2.2-0,1=0,3\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl -->ZnCl₂ + H₂

____0,2<----------------------0,2

=> m_Zn = 0,2.65 = 13 (g)

m_Cu = m_{rắn không tan} = 19,5 (g)

\(\left\{{}\begin{matrix}\%Zn=\dfrac{13}{13+19,5}.100\%=40\%\\\%Cu=\dfrac{19,5}{13+19,5}.100\%=60\%\end{matrix}\right.\)

`n_(H_2)=4,48/22,4=0,2 (mol)`

Ta có PTHH: `Zn+2HCl --> ZnCl_2 +H_2`

Theo PT:       `1`--------------------------------`1`

Theo đề:       `0,2`------------------------------`0,2`

`m_(Zn)=0,2.65=13(g)`

Vì `Cu` không phản ứng với `HCl` nên `m_(chất rắn không tan)=m_(Cu)=19,5(gam)`

`%Zn=13/(13+19,5) .100%=40%`

`%Cu=100%-40%=60%`

\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{Fe}=0,15\left(mol\right)\\ \Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\\ ChấtrắnkhôngtanlàCu\\ Cu+Cl_2\text{ }\rightarrow CuCl_2\\ n_{Cu}=n_{Cl_2}=0,2\left(mol\right)\\ \Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\\ \%m_{Fe}=\dfrac{8,4}{8,4+12,8}.100=39,62\%\\ \%m_{Cu}=100-39,62=60,38\%\)

\(n_{Fe} = a(mol) ; n_{Mg} = b(mol)\\ \Rightarrow 56a + 24b = 16,8 - 6,4 = 10,4(1)\\ Fe + 2HCl \to FeCl_2 + H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + b = \dfrac{6,72}{22,4} = 0,3(2)\)

Từ (1)(2) suy ra: a = 0,1 ; b = 0,2

Vậy :

\(\%m_{Fe} = \dfrac{0,1.56}{16,8}.100\% = 33,33\%\\ \%m_{Mg} = \dfrac{0,2.24}{16,8}.100\% = 28,57\%\\ \%m_{Cu} = 100\% - 33,33\% - 28,57\% = 38,1\%\)