\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

a) Theo Pt : \(n_{H2}=n_{Fe}=n_{FeCl2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\)

\(\%m_{Cu}=100\%-56\%=44\%\)

b) Theo Pt : \(n_{H2}=2n_{HCl}=2.0,1=0,2\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}.100\%=100\left(g\right)\)

c) \(m_{ddspu}=10+100-0,1.2=109,8\left(g\right)\)

\(C\%_{FeCl2}=\dfrac{0,1.127}{109,8}.100\%=11,57\%\)

\(n_{Fe} = a(mol) ; n_{Mg} = b(mol)\\ \Rightarrow 56a + 24b = 16,8 - 6,4 = 10,4(1)\\ Fe + 2HCl \to FeCl_2 + H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + b = \dfrac{6,72}{22,4} = 0,3(2)\)

Từ (1)(2) suy ra: a = 0,1 ; b = 0,2

Vậy :

\(\%m_{Fe} = \dfrac{0,1.56}{16,8}.100\% = 33,33\%\\ \%m_{Mg} = \dfrac{0,2.24}{16,8}.100\% = 28,57\%\\ \%m_{Cu} = 100\% - 33,33\% - 28,57\% = 38,1\%\)

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: Fe + H₂SO₄ → FeSO₄ + H₂

Mol:     0,4                                         0,4

\(m_{Fe}=0,4.56=22,4\left(g\right)\)

\(m_{hh}=22,4+5=27,4\left(g\right)\)

\(\%m_{Fe}=\dfrac{22,4.100\%}{27,4}=81,75\%;\%m_{Cu}=100-81,75=18,25\%\)

2Al+6Hcl->2AlCl₃+3H₂

x-----------------x--------3\2x

Fe+2HCl->FeCl₂+H₂

y-----------------y------y 

Ta có :

\(\left\{{}\begin{matrix}27x+56y=9,65\\\dfrac{3}{2}x+y=0,325\end{matrix}\right.\)

=>x=0,15 mol, y=0,1 mol

=>m Al=0,15.27=4,05g

=>m Fe=56.0,1=5,6g

b)

=>m AlCl3=0,15.133,5=20,025g

=>m FeCl2=0,1.127=12,7g

\(\left\{{}\begin{matrix}Al\\Fe\end{matrix}\right.+HCl->\left\{{}\begin{matrix}AlCl3\\FeCl2\end{matrix}\right.+7,28lH2\)

a, 

Ta có :

\(\left\{{}\begin{matrix}27x+56y=9,65\\3x+2y=0,65\left(bt-e\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}x=0,15\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}mAl=0,15.27=4,05\left(g\right)\\mFe=0,1.56=5,6\left(g\right)\end{matrix}\right.\)

b,

Bảo toàn nguyên tố :

nAl = nAlCl3 = 0,15 ( mol )

nFe = nFeCl2 = 0,1 ( mol )

Khối lượng chất tan A :

m = 0,15 . 133,5 + 0,1 . 127 = 32,725(g)

Bài 1:

a+b) PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)=n_{Fe}\)

\(\Rightarrow m_{Fe}=0,2\cdot56=11,2\left(g\right)\) \(\Rightarrow m_{Cu}=6,4\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{11,2}{17,6}\cdot100\%\approx63,64\%\\\%m_{Cu}=36,36\%\end{matrix}\right.\)

c) Ta có: \(n_{Cu}=\dfrac{6,4}{64}=0,1\left(mol\right)\)

Bảo toàn nguyên tố: \(n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Fe}=0,1\left(mol\right)=n_{CuSO_4}\)

\(\Rightarrow m_{muối}=0,1\cdot400+0,1\cdot160=56\left(g\right)\)

Bài 2:

Quy đổi hh gồm Fe (a mol) và O (b mol)

\(\Rightarrow56a+16b=27,6\)  (1)

Ta có: \(n_{SO_2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)

Bảo toàn electron: \(3n_{Fe}=2n_O+2n_{SO_2}\) \(\Rightarrow3a-2b=0,45\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,39\\b=0,36\end{matrix}\right.\)

Bảo toàn nguyên tố: \(n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Fe}=0,195\left(mol\right)\) \(\Rightarrow m_{Fe_2\left(SO_4\right)_3}=0,195\cdot400=78\left(g\right)\)

\(n_{H_2}=\dfrac{7,84}{22,4}=0,35mol\)

Gọi \(\left\{{}\begin{matrix}n_{Fe}=x\\n_{Zn}=y\end{matrix}\right.\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

 x                                     x ( mol )

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

 y                                     y      ( mol )

Ta có:

\(\left\{{}\begin{matrix}56x+65y=21,4\\x+y=0,35\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,15\\y=0,2\end{matrix}\right.\)

\(\Rightarrow m_{Fe}=0,15.56=8,4g\)

\(\Rightarrow m_{Zn}=0,2.65=13g\)

\(\%m_{Fe}=\dfrac{8,4}{21,4}.100=39,25\%\)

\(\%m_{Zn}=100\%-39,25\%=60,75\%\)

\(m_{FeCl_2}=0,15.127=19,05g\)

\(m_{ZnCl_2}=0,2.136=27,2g\)

Do HNO3 nóng dư nên Fe, Cu pứ hết --> Fe3+ & Cu2+
M(B) = 36 --> nNO : nNO2 = 5:3
Khi cho đ sau pứ tác dụng vs NH3 dư thì --> Fe(OH)3 ko tan, Cu(NH3)4(OH)2 tan
--> Chất rắn sau nung: Fe2O3: n = 0,05 --> nFe = 0,1 -->mFe = 5,6, mCu = 6,4g
Từ nFe, nCu, bảo toàn electron --> nNO, nNO2 --> V
c, Dung dịch kiềm> Vì trong dd D có NH4NHO3, nên cho kiềm vào sẽ sinh ra NH3.

PTHH:

\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)

0,15                                                     0,15 

\(CaO+2HCl\rightarrow CaCl_2+H_2O\)

Ta có: \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(\Rightarrow m_{CaCO_3}=0,15\cdot100=15\left(g\right)\)

\(\Rightarrow m_{CaO}=20,6-15=5,6\left(g\right)\)

\(\Rightarrow\%m_{CaCO_3}=\dfrac{15\cdot100}{20,6}\approx73\%\)

\(\Rightarrow\%m_{CaO}=100\%-73\%=27\%\)