\(n_{Al_2O_3}=\dfrac{10.2}{102}=0.1\left(mol\right)\)

\(n_{HCl}=0.35\cdot2=0.7\left(mol\right)\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

\(1.................6\)

\(0.1.............0.7\)

Lập tỉ lệ : \(\dfrac{0.1}{1}< \dfrac{0.7}{6}\Rightarrow HCldư\)

\(m_{AlCl_3}=0.1\cdot2\cdot133.5=26.7\left(g\right)\)

\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(0.1.....................0.1\)

\(m_{FeCl_2}=0.1\cdot127=12.7\left(g\right)\)

Bảo toàn nguyên tố Fe:

\(n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\)

\(\Rightarrow m_{FeCl_2}=12,7\left(g\right)\)

\(a.n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ a............3a.......a.........1,5a\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b.........2b........b.........b\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}27a+56b=5,5\\1,5a+b=0,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{27.0,1}{5,5}.100\approx49,091\%\\\%m_{Fe}=\dfrac{0,05.56}{5,5}.100\approx50,909\%\end{matrix}\right.\\ b.C_{MddHCl}=\dfrac{3a+2b}{0,5}=\dfrac{3.0,1+2.0,05}{0,5}=0,8\left(M\right)\)

PT: \(FeO+2HCl\rightarrow FeCl_2+H_2O\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

Ta có: 72n_FeO + 102n_Al2O3 = 45 (1)

\(n_{HCl}=1.2,2=2,2\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{FeO}+6n_{Al_2O_3}=2,2\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{FeO}=0,2\left(mol\right)\\n_{Al_2O_3}=0,3\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{FeO}=0,2.72=14,4\left(g\right)\\m_{Al_2O_3}=0,3.102=30,6\left(g\right)\end{matrix}\right.\)

Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{FeO}=0,2\left(mol\right)\\n_{AlCl_3}=2n_{Al_2O_3}=0,6\left(mol\right)\end{matrix}\right.\) 

⇒ m _muối = m_FeCl2 + m_AlCl3 = 0,2.127 + 0,6.133,5 = 105,5 (g)

\(n_{HCl}=1.2,2=2,2mol\\ FeO+2HCl\rightarrow FeCl_2+H_2O\\ Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\\ n_{FeO}=a;n_{Al_2O_3}=b\\ \Rightarrow\left\{{}\begin{matrix}72a+102b=45\\2a+6b=2,2\end{matrix}\right.\\ \Rightarrow a=0,2;b=0,3\\ m_{FeO}=0,2.72=14,4g\\ m_{Al_2O_3}=45-14,4=30,6g\\ n_{FeO}=n_{FeCl_2}=0,2mol\\ n_{Al_2O_3}=0,3.2=0,6mol\\ m_{muối}=0,2.127+0,6.133,5=105,5g\)

\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)

\(n_{HCl}=0.35\cdot1=0.35\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Lập tỉ lệ : 

\(0.1< \dfrac{0.35}{2}\Rightarrow HCldư\)

\(m_{FeCl_2}=0.1\cdot127=12.7\left(g\right)\)

Đáp án A

Chất rắn Y là Cu không phản ứng

n_HCl =  = 2.0,35 = 0,7

m_muối = m_KL + m_{gốc axit} = (9,14 – 2,54) + 0,7.35,5 = 31,45(g)

\(n_{Zn}=\dfrac{6,5}{65}=0,1(mol)\\ PTHH:Zn+H_2SO_4\to ZnSO_4+H_2\\ \Rightarrow n_{ZnSO_4}=n_{Zn}=0,1(mol)\\ \Rightarrow m_{ZnSO_4}=0,1.161=16,1(g)\)

Bảo toàn nguyên tố Zn:

\(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)

\(\Rightarrow m_{ZnSO_4}=16,1\left(g\right)\)

\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)

\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)