Gọi hóa trị của sắt clorua là n

Ta có : \(FeCl_n+nAgNO_3\rightarrow Fe\left(NO_3\right)_n+nAgCl\)

Ta có: \(n_{AgCl}=\dfrac{2,65}{143,5}=\dfrac{53}{2870}\left(mol\right)\)

Ta có: \(n_{FeCl_n}=\dfrac{1}{n}n_{AgCl}=\dfrac{53}{2870n}\left(mol\right)\)

=> \(\dfrac{1}{56+35,5n}=\dfrac{53}{2870n}\)

=> n=3

Vậy CT muối: FeCl₃

Đáp án B.

Đặt công thức muối sắt clorua là Fe Cl n

Fe Cl n  + n AgNO 3  → nAgCl + Fe NO 3 n

Ta có phương trình : 6,5 x n(108 + 35,5) = 17,22 x (56 + 35,5n)

n = 3 → Fe Cl 3

Câu 3:

\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right);n_{HCl}=0,1.1=0,1\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,1}{1}>\dfrac{0,1}{2}\Rightarrow Fe.dư\\ n_{H_2}=\dfrac{n_{HCl}}{2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\)

Câu 1:

\(Đặt:FeCl_x\) (x: nguyên dương, x hoá trị của Fe)

\(FeCl_x+xAgNO_3\rightarrow xAgCl\downarrow+Fe\left(NO_3\right)_x\\ n_{AgCl}=\dfrac{8,61}{143,5}=0,06\left(mol\right)\\ n_{FeCl_x}=\dfrac{0,06}{x}\left(mol\right)\\ M_{FeCl_x}=\dfrac{3,25}{\dfrac{0,06}{x}}=\dfrac{3,25x}{0,06}\left(\dfrac{g}{mol}\right)\)

Xét x=1;x=2;x=3;x=4, ta thấy có lúc x=3 thì\(M_{FeCl_3}=162,5\left(\dfrac{g}{mol}\right)\) 

Vậy nhận x=3 => CTHH FeCl₃

Câu 2:

\(n_{CuSO_4}=\dfrac{20.10\%}{160}=0,0125\left(mol\right)\\ Zn+CuSO_4\rightarrow ZnSO_4+Cu\\ n_{Zn}=n_{Cu}=n_{ZnSO_4}=n_{CuSO_4}=0,0125\left(mol\right)\\ m_{Zn}=0,0125.65=0,8125\left(g\right)\\ m_{ddZnSO_4}=0,8125+20-0,0125.64=20,0125\left(g\right)\\ C\%_{ddZnSO_4}=\dfrac{0,0125.161}{20,0125}.100\%\approx10,056\%\)

\(m_{FeCl_x}=\dfrac{10.32,5}{100}=3,25\left(g\right)\)

PTHH: FeCl_x + 3AgNO₃ --> Fe(NO₃)₃ + xAgCl + (3-x)Ag

_______a------------------------------->ax--------->(3-x)a

=> 143,5ax + 108(3-x)a = 8,61

=> a(35,5x + 324) = 8,61

=> \(a=\dfrac{8,61}{35,5x+324}\)

=> \(M_{FeCl_x}=56+35,5x=\dfrac{3,25}{\dfrac{8,61}{35,5x+324}}\)

=> x = 3

=> CTHH: FeCl₃

Đặt hóa trị Fe là x(x>0)

\(FeCl_x+xAgNO_3\to xAgCl\downarrow+Fe(NO_3)_x\\ \Rightarrow n_{FeCl_x}=\dfrac{n_{AgCl}}{x}=\dfrac{\dfrac{8,61}{143,5}}{x}=\dfrac{0,06}{x}\\ \Rightarrow M_{FeCl_x}=\dfrac{3,25}{\dfrac{0,06}{x}}=\dfrac{325}{6}x\\ \Rightarrow 56+35,5x=\dfrac{325}{6}x\\ \Rightarrow 56=\dfrac{56}{3}x\\ \Rightarrow x=3\\ \Rightarrow CTHH:FeCl_3\)

B