Nồng độ mol của dung dịch  H 2 SO 4  :

n H 2 SO 4 = n SO 3  = 8/80 = 0,1 mol

Theo phương trình hoá học :

C Mdd   H 2 SO 4  = 1000x0,1/250 = 0,4M

\(n_{Al\left(OH\right)_3}=\dfrac{7,8}{78}=0,1mol\\ 2Al\left(OH\right)_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+6H_2O\\ 0,1................0,15.............0,05............0,3\\ C_{\%H_2SO_4}=\dfrac{0,15.98}{300}\cdot100\%=4,9\%\\ C_{\%Al_2\left(SO_4\right)_3}=\dfrac{0,05.342}{7,8+300}\cdot100\%=5,56\%\)

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

              a_______a_______a_____a    (mol)

            \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

                2b______3b__________b_____3b    (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27\cdot2b=11\\a+3b=0,2\cdot2=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{11}\cdot100\%\approx50,91\%\\\%m_{Al}=49,09\%\end{matrix}\right.\)

Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{FeSO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\) 

a) nH2SO4=0,4(mol)

Đặt: nFe=x(mol); nAl=y(mol) (x,y>0)

PTHH: Fe + H2SO4 -> FeSO4 + H2

x________x______x______x(mol)

2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2

y____1,5y_______0,5y_______1,5y(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=> mFe=0,1.56=5,6(g)

=>%mFe=(5,6/11).100=50,909%

=>%mAl= 49,091%

b) V(H2,đktc)=0,4.22,4=8,96(l)

c) nAl2(SO4)3= 0,5y=0,5.0,2=0,1(mol)

nFeSO4=x=0,1(mol)

Vddsau=VddH2SO4=0,2(l)

=>CMddAl2(SO4)3= 0,1/0,2=0,5(M)

CMddFeSO4=0,1/0,2=0,5(M)

\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)

Anh có làm rồi nha!

B

B

B

nCO2=0,25(mol)

Để sp thu được NaHCO3 => nNaOH \(\le\) 0,25(mol)

=> mNaOH \(\le\) 10(g)

=> C%ddNaOH \(\le\) \(\dfrac{10}{200}.100=5\%\)

=> CHỌN A

\(n_{MgO}=a\left(mol\right),n_{Fe_2O_3}=b\left(mol\right)\)

\(m=40a+160b=12\left(g\right)\left(1\right)\)

\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

\(m_{Muối}=120a+400y=32\left(g\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.1,b=0.05\)

\(\%MgO=\dfrac{0.1\cdot40}{12}\cdot100\%=33.33\%\)

\(\%Fe_2O_3=66.67\%\)

\(m_{dd}=12+200=212\left(g\right)\)

\(C\%_{MgSO_4}=\dfrac{0.1\cdot120}{212}\cdot100\%=5.66\%\)

\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0.05\cdot400}{212}\cdot100\%=9.42\%\)