12,1 gam (Fe, Zn) + HCl (vừa đủ) →  muối  FeCl 2 ,   ZnCl 2   +   H 2

Đáp án là C

Chọn đáp án B

mMuối = 12,1 + 0,2.2.35,5 = 26,3 gam

a)

Gọi $n_{Zn} = a(mol) ; n_{Al} = b(mol) \Rightarrow 65a + 27b = 11,9(1)$

$Zn + 2HCl \to ZnCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : 

$n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$

Từ (1)(2) suy ra : a = 0,1; b = 0,2

$m_{Zn} = 0,1.65 = 6,5(gam)$

$m_{Al} = 0,2.27 = 5,4(gam)$

b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$C\%_{HCl} = \dfrac{0,8.36,5}{125}.100\% = 23,36\%$

a) Gọi số mol Zn, Fe là a, b (mol)

=> 65a + 56b = 8,56 (1)

\(n_{H_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

           a--->2a-------->a----->a

            Fe + 2HCl --> FeCl₂ + H₂

           b----->2b------->b------>b

=> a + b = 0,14 (2)

(1)(2) => a = 0,08; b = 0,06 

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,08.65}{8,56}.100\%=60,748\%\\\%m_{Fe}=\dfrac{0,06.56}{8,56}.100\%=39,252\%\end{matrix}\right.\)

b) 

n_KOH = 0,2.0,1 = 0,02 (mol)

PTHH: KOH + HCl --> KCl + H₂O

           0,02-->0,02

=> n_HCl = 0,02 + 2a + 2b = 0,3 (mol)

=> \(C_{M\left(HCl\right)}=xM=\dfrac{0,3}{0,15}=2M\)

c) m = 0,08.136 + 0,06.127 = 18,5(g)

\(m_{HCl}=\dfrac{124,1\cdot25}{100}=31,025g\)

\(\Rightarrow n_{HCl}=0,85mol\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

 x          3x

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

y            2y

\(\Rightarrow\left\{{}\begin{matrix}27x+65y=17,05\\3x+2y=0,85\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,15\\y=0,2\end{matrix}\right.\)

\(\%m_{Zn}=\dfrac{0,2\cdot65}{17,05}\cdot100\%=75,25\%\)

76,2% 

\(n_{O_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)

\(n_{H_2}=\dfrac{10.08}{22.4}=0.45\left(mol\right)\)

\(n_{Fe}=a\left(mol\right),n_{Al}=b\left(mol\right)\)

\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)

\(a.......\dfrac{2a}{3}\)

\(4Al+3O_2\underrightarrow{^{^{t^0}}}2Al_2O_3\)

\(b.......\dfrac{3b}{4}\)

\(n_{O_2}=\dfrac{2a}{3}+\dfrac{3b}{4}=0.25\left(mol\right)\left(1\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(n_{H_2}=a+1.5b=0.45\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.15,b=0.2\)

\(m_{Fe}=0.15\cdot56=8.4\left(g\right)\)

\(m_{Al}=0.2\cdot27=5.4\left(g\right)\)

\(\%m_{Fe}=\dfrac{8.4}{8.4+5.4}\cdot100\%=60.8\%\)

\(\%m_{Al}=100-60.8=39.2\%\)

a) Gọi số mol Mg, Fe là a, b (mol)

=> 24a + 56b = 11,84

\(n_{HCl}=\dfrac{146.14\%}{36,5}=0,56\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

            a--->2a--------->a----->a

           Fe + 2HCl --> FeCl₂ + H₂

            b-->2b-------->b------>b

=> 2a + 2b = 0,56

=> a = 0,12; b = 0,16

=> \(\left\{{}\begin{matrix}\%Mg=\dfrac{0,12.24}{11,84}.100\%=24,324\%\\\%Fe=\dfrac{0,16.56}{11,84}.100\%=75,676\%\end{matrix}\right.\)

b) \(n_{H_2}=a+b=0,28\left(mol\right)\)

=> \(V_{H_2}=0,28.22,4=6,272\left(l\right)\)

c) m_{dd sau pư} = 11,84 + 146 - 0,28.2 = 157,28 (g)

=> \(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,12.95}{157,28}.100\%=7,25\%\\C\%_{FeCl_2}=\dfrac{0,16.127}{157,28}.100\%=12,92\%\end{matrix}\right.\)

\(a)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=0,1mol\\ m_{Zn}=0,1.65=6,5g\\ m_{Cu}=9,7-6,5=3,2g\\ b)C_{\%ZnCl_2}=\dfrac{0,1.136}{6,5+120-0,1.2}\cdot100=10,77\%\)

Đáp án B

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1=n_{Zn}\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1mol\\ C\%=\dfrac{0,2\cdot136}{175,6+14,6-0,2}=14,32\%\)