a) 

PTHH: C₂H₂ + 2Br₂ --> C₂H₂Br₄

Khí thoát ra là CH₄

\(n_{CH_4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(n_{C_2H_2}=\dfrac{6,72}{22,4}-0,2=0,1\left(mol\right)\)

\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,2.16}{0,2.16+0,1.26}.100\%=55,17\%\\\%m_{C_2H_2}=\dfrac{0,1.26}{0,2.16+0,1.26}.100\%=44,83\%\end{matrix}\right.\)

b) 

PTHH: C₂H₂ + 2Br₂ --> C₂H₂Br₄

              0,1--->0,2

=> m_Br2 = 0,2.160 = 32 (g)

ta có :

nBr2=\(\dfrac{16}{160}=0,1mol\)

C2H4+Br2->C2H4Br2

0,1------0,1

=>VC2H4=0,1.22,4=2,24l

=>VCH4=3,36l->n CH4=0,15 mol

->%VC2H4=\(\dfrac{2,24}{5,6}.100\)=40%

=>%VCH4=60%

c)

CH4+2O2-to>CO2+2H2O

0,15---------------0,15

C2H4+3O2--to>2CO2+2H2O

0,1--------------------0,2
=>m CaCO3=0,35.100=35g

a, C₂H₄ đã pư với dd Brom.

b, Ta có: \(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,05\left(mol\right)\Rightarrow m_{C_2H_4}=0,05.28=1,4\left(g\right)\)

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

a) Ta có: \(n_{C_2H_4}=\dfrac{9,1}{28}=0,325\left(mol\right)=n_{Br_2}\) \(\Rightarrow V_{Br_2}=\dfrac{0,325}{2}=0,1625\left(l\right)=162,5\left(ml\right)\)

b) Ta có: \(\left\{{}\begin{matrix}n_{C_2H_4}=0,325\left(mol\right)\\n_{CH_4}=\dfrac{13,44}{22,4}-0,325=0,275\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{hh}=9,1+0,275\cdot16=13,5\left(g\right)\)

c) PTHH: \(CH_4+2O_2 \underrightarrow{t^o} CO_2+2H_2O\)

                \(C_2H_4+3O_2 \underrightarrow{t^o} 2CO_2+ 2H_2O\)

Theo các PTHH: \(\Sigma n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=1,525\left(mol\right)\)

\(\Rightarrow V_{O_2}=1,525\cdot22,4=34,16\left(l\right)\)

\(a,n_{hh\left(CH_4,C_2H_4,C_2H_2\right)}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ n_{hh\left(C_2H_4,C_2H_2\right)}=0,4-0,1=0,3\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}a+b=0,3\\28a+26b=8,1\end{matrix}\right.\Leftrightarrow a=b=0,15\left(mol\right)\)

PTHH:

\(CH\equiv CH+2Br-Br\rightarrow CHBr_2-CHBr_2\)

\(CH_2=CH_2+Br-Br\rightarrow CH_2Br-CH_2Br\)

\(b,\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,4}.100\%=25\%\\\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,15}{0,4}.100\%=37,5\%\end{matrix}\right.\)

c, PTHH:

\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^o}2CO_2+H_2O\\ C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Ba\left(OH\right)_2+CO_2\rightarrow BaCO_3\downarrow+H_2O\\ \rightarrow n_{BaCO_3}=n_{CO_2}=0,1+0,15.0,15.2=0,7\left(mol\right)\\ m_{BaCO_3}=0,7.197=137,9\left(g\right)\)